Intermolecular Hybridization Governs Molecular Electrical Doping

Current models for molecular electrical doping of organic semiconductors are found to be at odds with other well-established concepts in that field, like polaron formation. Addressing these inconsistencies for prototypical systems, we present experimental and theoretical evidence for intermolecular...

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Vydáno v:Physical review letters Ročník 108; číslo 3; s. 035502
Hlavní autoři: Salzmann, Ingo, Heimel, Georg, Duhm, Steffen, Oehzelt, Martin, Pingel, Patrick, George, Benjamin M., Schnegg, Alexander, Lips, Klaus, Blum, Ralf-Peter, Vollmer, Antje, Koch, Norbert
Médium: Journal Article
Jazyk:angličtina
Vydáno: United States 18.01.2012
ISSN:0031-9007, 1079-7114, 1079-7114
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Abstract Current models for molecular electrical doping of organic semiconductors are found to be at odds with other well-established concepts in that field, like polaron formation. Addressing these inconsistencies for prototypical systems, we present experimental and theoretical evidence for intermolecular hybridization of organic semiconductor and dopant frontier molecular orbitals. Common doping-related observations are attributed to this phenomenon, and controlling the degree of hybridization emerges as a strategy for overcoming the present limitations in the yield of doping-induced charge carriers.
AbstractList Current models for molecular electrical doping of organic semiconductors are found to be at odds with other well-established concepts in that field, like polaron formation. Addressing these inconsistencies for prototypical systems, we present experimental and theoretical evidence for intermolecular hybridization of organic semiconductor and dopant frontier molecular orbitals. Common doping-related observations are attributed to this phenomenon, and controlling the degree of hybridization emerges as a strategy for overcoming the present limitations in the yield of doping-induced charge carriers.
Current models for molecular electrical doping of organic semiconductors are found to be at odds with other well-established concepts in that field, like polaron formation. Addressing these inconsistencies for prototypical systems, we present experimental and theoretical evidence for intermolecular hybridization of organic semiconductor and dopant frontier molecular orbitals. Common doping-related observations are attributed to this phenomenon, and controlling the degree of hybridization emerges as a strategy for overcoming the present limitations in the yield of doping-induced charge carriers.Current models for molecular electrical doping of organic semiconductors are found to be at odds with other well-established concepts in that field, like polaron formation. Addressing these inconsistencies for prototypical systems, we present experimental and theoretical evidence for intermolecular hybridization of organic semiconductor and dopant frontier molecular orbitals. Common doping-related observations are attributed to this phenomenon, and controlling the degree of hybridization emerges as a strategy for overcoming the present limitations in the yield of doping-induced charge carriers.
ArticleNumber 035502
Author Vollmer, Antje
Koch, Norbert
George, Benjamin M.
Lips, Klaus
Salzmann, Ingo
Duhm, Steffen
Schnegg, Alexander
Oehzelt, Martin
Pingel, Patrick
Heimel, Georg
Blum, Ralf-Peter
Author_xml – sequence: 1
  givenname: Ingo
  surname: Salzmann
  fullname: Salzmann, Ingo
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  givenname: Georg
  surname: Heimel
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– sequence: 3
  givenname: Steffen
  surname: Duhm
  fullname: Duhm, Steffen
– sequence: 4
  givenname: Martin
  surname: Oehzelt
  fullname: Oehzelt, Martin
– sequence: 5
  givenname: Patrick
  surname: Pingel
  fullname: Pingel, Patrick
– sequence: 6
  givenname: Benjamin M.
  surname: George
  fullname: George, Benjamin M.
– sequence: 7
  givenname: Alexander
  surname: Schnegg
  fullname: Schnegg, Alexander
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  givenname: Klaus
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  surname: Vollmer
  fullname: Vollmer, Antje
– sequence: 11
  givenname: Norbert
  surname: Koch
  fullname: Koch, Norbert
BackLink https://www.ncbi.nlm.nih.gov/pubmed/22400758$$D View this record in MEDLINE/PubMed
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