Heterogeneous Raney Nickel and Cobalt Catalysts for Racemization and Dynamic Kinetic Resolution of Amines

Raney metals were studied as heterogeneous catalysts for racemization and dynamic kinetic resolution (DKR) of chiral amines, as an alternative to metals like palladium or ruthenium. Both Raney nickel and cobalt were able to selectively racemize various chiral amines with high selectivity. In the rac...

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Vydáno v:	Advanced synthesis & catalysis Ročník 350; číslo 1; s. 113 - 121
Hlavní autoři:	Parvulescu, Andrei N., Jacobs, Pierre A., De Vos, Dirk E.
Médium:	Journal Article
Jazyk:	angličtina
Vydáno:	Weinheim WILEY-VCH Verlag 04.01.2008 WILEY‐VCH Verlag Wiley
Témata:	Chemistry Chemistry, Applied Chemistry, Organic chiral amides chiral amines dynamic kinetic resolution kinetic resolution Physical Sciences Raney cobalt Raney nickel Science & Technology PALLADIUM chiral amines ACYLATION Raney nickel RUTHENIUM Raney cobalt COMBINATION resolution ASYMMETRIC TRANSFORMATIONS SECONDARY ALCOHOLS TEMPERATURE chiral amides kinetic resolution LIPASE EFFICIENT dynamic kinetic
ISSN:	1615-4150, 1615-4169
On-line přístup:	Získat plný text
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