On the interplay between charge, spin and structural dynamics in transition metal complexes

This perspective presents some recent results concerning ultrafast intramolecular relaxation processes in metal-based molecular complexes. Ultrafast electronic/vibrational relaxation at sub-vibrational time scales, ultrafast intersystem crossing processes and ultrafast structure changes are discusse...

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Veröffentlicht in:Dalton transactions : an international journal of inorganic chemistry Jg. 41; H. 42; S. 13022
1. Verfasser: Chergui, Majed
Format: Journal Article
Sprache:Englisch
Veröffentlicht: England 14.11.2012
ISSN:1477-9234, 1477-9234
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Zusammenfassung:This perspective presents some recent results concerning ultrafast intramolecular relaxation processes in metal-based molecular complexes. Ultrafast electronic/vibrational relaxation at sub-vibrational time scales, ultrafast intersystem crossing processes and ultrafast structure changes are discussed, stressing the questions that still need to be solved in order to arrive at a rationale that describes these processes. We will also discuss some new techniques, based on core-level spectroscopies that can provide new insights into the ultrafast intramolecular relaxation in these systems.
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ISSN:1477-9234
1477-9234
DOI:10.1039/c2dt30764b