Stability of xenon oxides at high pressures

Xenon, which is quite inert under ambient conditions, may become reactive under pressure. The possibility of the formation of stable xenon oxides and silicates in the interior of the Earth could explain the atmospheric missing xenon paradox. Using an ab initio evolutionary algorithm, we predict the...

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Vydáno v:	Nature chemistry Ročník 5; číslo 1; s. 61 - 65
Hlavní autoři:	Zhu, Qiang, Jung, Daniel Y., Oganov, Artem R., Glass, Colin W., Gatti, Carlo, Lyakhov, Andriy O.
Médium:	Journal Article
Jazyk:	angličtina
Vydáno:	London Nature Publishing Group UK 01.01.2013 Nature Publishing Group
Témata:	639/638/263 639/638/563 Algorithms Analytical Chemistry Biochemistry Chemical bonds Chemistry Chemistry/Food Science Crystallography, X-Ray Earth mantle Genetic algorithms High pressure Inorganic Chemistry Lower mantle Organic Chemistry Oxidation Oxides Oxides - chemistry Physical Chemistry Pressure Quantum Theory Silicates Temperature Xenon Xenon - chemistry
ISSN:	1755-4330, 1755-4349, 1755-4349
On-line přístup:	Získat plný text
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Shrnutí:	Xenon, which is quite inert under ambient conditions, may become reactive under pressure. The possibility of the formation of stable xenon oxides and silicates in the interior of the Earth could explain the atmospheric missing xenon paradox. Using an ab initio evolutionary algorithm, we predict the existence of thermodynamically stable Xe–O compounds at high pressures (XeO, XeO 2 and XeO 3 become stable at pressures above 83, 102 and 114 GPa, respectively). Our calculations indicate large charge transfer in these oxides, suggesting that large electronegativity difference and high pressure are the key factors favouring the formation of xenon compounds. However, xenon compounds cannot exist in the Earth's mantle: xenon oxides are unstable in equilibrium with the metallic iron occurring in the lower mantle, and xenon silicates are predicted to decompose spontaneously at all mantle pressures (<136 GPa). However, it is possible that xenon atoms may be retained at defects in mantle silicates and oxides. Xenon is an inert element at ambient conditions but may become reactive under pressure. It has now been predicted that pressure stabilizes increasing oxidation states of Xe atoms (from Xe 0 to Xe 2+ to Xe 4+ to Xe 6+ ), and thus a series of compounds — XeO, XeO 2 and XeO 3 — become thermodynamically stable at megabar pressures.
Bibliografie:	ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14 content type line 23
ISSN:	1755-4330 1755-4349 1755-4349
DOI:	10.1038/nchem.1497