Synthesis of Cyclophenacene‐ and Chiral‐Type Cyclophenylene‐Naphthylene Belts

We report the synthesis of a [20]cyclophenacene‐type cyclophenylene‐naphthylene (CPN) belt and the enantioselective synthesis of chiral‐type CPN belts (up to >99 % ee) by the cationic rhodium(I)‐catalyzed intramolecular [2+2+2] cycloaddition of naphthalene‐embedded cyclic polyynes. The synthesis...

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Bibliographic Details
Published in:	Angewandte Chemie International Edition Vol. 61; no. 15; pp. e202200800 - n/a
Main Authors:	Nogami, Juntaro, Nagashima, Yuki, Sugiyama, Haruki, Miyamoto, Kazunori, Tanaka, Yusuke, Uekusa, Hidehiro, Muranaka, Atsuya, Uchiyama, Masanobu, Tanaka, Ken
Format:	Journal Article
Language:	English
Published:	WEINHEIM Wiley 04.04.2022 Wiley Subscription Services, Inc
Edition:	International ed. in English
Subjects:	[2+2+2] Cycloaddition Anisotropy Belts Chemistry Chemistry, Multidisciplinary Circular dichroism Circular polarization Crystallography Cycloaddition Cyclophenylene-Naphthylene Belts DFT Calculations Dichroism Enantiomers Naphthalene Physical Sciences Planar Chirality Rhodium Science & Technology Synthesis Cyclophenylene-Naphthylene Belts DESIGN CARBON [2+2+2] Cycloaddition CATALYZED 2+2+2 CYCLOADDITION MOLECULES Rhodium CYCLOPARAPHENYLENES GROWTH SYSTEMS DFT Calculations Planar Chirality CHEMICAL-SYNTHESIS CYCLOTRIMERIZATION
ISSN:	1433-7851, 1521-3773, 1521-3773
Online Access:	Get full text
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