Mapping Dithiobenzoate-Mediated RAFT Polymerization Products via Online Microreactor/Mass Spectrometry Monitoring
2-cyano-2-propyl dithiobenzoates (CPDB)-mediated reversible addition-fragmentation chain transfer (RAFT) polymerization was monitored by online flow microreactor/mass spectrometry. This enabled the reactions to be followed in a time-resolved manner, closely resolving product patterns in the reaction...
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| Vydáno v: | Polymers Ročník 10; číslo 11; s. 1228 |
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06.11.2018
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| Abstract | 2-cyano-2-propyl dithiobenzoates (CPDB)-mediated reversible addition-fragmentation chain transfer (RAFT) polymerization was monitored by online flow microreactor/mass spectrometry. This enabled the reactions to be followed in a time-resolved manner, closely resolving product patterns in the reaction mixtures at any point in time. RAFT polymerization was investigated for low RAFT to monomer ratios, enabling the monitoring of the early stages of a typical RAFT polymerization. The expected transition from pre- to the RAFT main equilibrium is observed. However, very high abundancies for cross-termination products were also identified, both in the pre- and main equilibrium stage. This is a somewhat surprising result as such products have always been expected, but to date have not been observed in the majority of studies. Product isolation and NMR analysis revealed that cross-termination occurs in the para position of the benzoate ring and becomes fully irreversible via re-aromatization of the ring in a H-shift reaction. The present data suggest a pronounced chain-length dependence of the cross-termination reaction, which would explain why the products are seen here, but not in other studies. |
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| AbstractList | 2-cyano-2-propyl dithiobenzoates (CPDB)-mediated reversible addition-fragmentation chain transfer (RAFT) polymerization was monitored by online flow microreactor/mass spectrometry. This enabled the reactions to be followed in a time-resolved manner, closely resolving product patterns in the reaction mixtures at any point in time. RAFT polymerization was investigated for low RAFT to monomer ratios, enabling the monitoring of the early stages of a typical RAFT polymerization. The expected transition from pre- to the RAFT main equilibrium is observed. However, very high abundancies for cross-termination products were also identified, both in the pre- and main equilibrium stage. This is a somewhat surprising result as such products have always been expected, but to date have not been observed in the majority of studies. Product isolation and NMR analysis revealed that cross-termination occurs in the para position of the benzoate ring and becomes fully irreversible via re-aromatization of the ring in a H-shift reaction. The present data suggest a pronounced chain-length dependence of the cross-termination reaction, which would explain why the products are seen here, but not in other studies. 2-cyano-2-propyl dithiobenzoates (CPDB)-mediated reversible addition-fragmentation chain transfer (RAFT) polymerization was monitored by online flow microreactor/mass spectrometry. This enabled the reactions to be followed in a time-resolved manner, closely resolving product patterns in the reaction mixtures at any point in time. RAFT polymerization was investigated for low RAFT to monomer ratios, enabling the monitoring of the early stages of a typical RAFT polymerization. The expected transition from pre- to the RAFT main equilibrium is observed. However, very high abundancies for cross-termination products were also identified, both in the pre- and main equilibrium stage. This is a somewhat surprising result as such products have always been expected, but to date have not been observed in the majority of studies. Product isolation and NMR analysis revealed that cross-termination occurs in the para position of the benzoate ring and becomes fully irreversible via re-aromatization of the ring in a H-shift reaction. The present data suggest a pronounced chain-length dependence of the cross-termination reaction, which would explain why the products are seen here, but not in other studies.2-cyano-2-propyl dithiobenzoates (CPDB)-mediated reversible addition-fragmentation chain transfer (RAFT) polymerization was monitored by online flow microreactor/mass spectrometry. This enabled the reactions to be followed in a time-resolved manner, closely resolving product patterns in the reaction mixtures at any point in time. RAFT polymerization was investigated for low RAFT to monomer ratios, enabling the monitoring of the early stages of a typical RAFT polymerization. The expected transition from pre- to the RAFT main equilibrium is observed. However, very high abundancies for cross-termination products were also identified, both in the pre- and main equilibrium stage. This is a somewhat surprising result as such products have always been expected, but to date have not been observed in the majority of studies. Product isolation and NMR analysis revealed that cross-termination occurs in the para position of the benzoate ring and becomes fully irreversible via re-aromatization of the ring in a H-shift reaction. The present data suggest a pronounced chain-length dependence of the cross-termination reaction, which would explain why the products are seen here, but not in other studies. |
| Author | Junkers, Tanja Haven, Joris J. |
| AuthorAffiliation | 1 Polymer Reaction Design Group, School of Chemistry, Monash University, 19 Rainforest Walk, Clayton, VIC 3800, Australia; joris.haven@monash.edu 2 Institute for Materials Research, Hasselt University, Martelarenlaan 42, 3500 Hasselt, Belgium |
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| Cites_doi | 10.1002/mats.201600048 10.1002/marc.200900907 10.1002/pola.23385 10.1002/masy.200750217 10.1039/C4SC02908A 10.3390/polym10030318 10.1021/cr990119u 10.1002/pola.24857 10.1002/1521-3919(20021101)11:8<823::AID-MATS823>3.0.CO;2-R 10.1021/ma990316v 10.1021/cr940534g 10.1002/1097-0126(200009)49:9<993::AID-PI506>3.0.CO;2-6 10.1002/macp.201200668 10.1039/C7PY00360A 10.1002/marc.201400518 10.1002/ejoc.201700851 10.1021/ma001484m 10.1039/c0py00245c 10.1002/macp.201700381 10.1002/mren.201700016 10.1039/C4CC10426A 10.1016/j.ces.2017.11.043 10.1021/ma0628634 10.1021/ma800388c 10.1021/ma9804951 10.1002/marc.200600317 10.1002/pola.21589 10.1002/marc.201500357 10.1002/pola.10854 10.1002/marc.200500832 |
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| References | Hawker (ref_3) 2001; 101 Moad (ref_7) 2000; 49 Pahnke (ref_29) 2015; 6 Meiser (ref_30) 2013; 214 Reyniers (ref_4) 2018; 177 Coote (ref_10) 2003; 41 Coote (ref_12) 2006; 27 Junkers (ref_18) 2011; 49 Geelen (ref_11) 2007; 40 Chiefari (ref_1) 1998; 31 ref_17 Buback (ref_13) 2007; 248 Konkolewicz (ref_14) 2008; 41 Buback (ref_16) 2006; 27 Matyjaszewski (ref_2) 2001; 101 Haven (ref_26) 2017; 11 Konkolewicz (ref_15) 2009; 47 Reyniers (ref_20) 2017; 26 Haven (ref_23) 2015; 51 Haven (ref_24) 2017; 2017 Chernikova (ref_27) 2010; 1 ref_21 Haven (ref_25) 2017; 8 Derboven (ref_22) 2015; 36 Vana (ref_9) 2002; 11 Hawthorne (ref_5) 1999; 32 Buback (ref_6) 2006; 44 Klumperman (ref_19) 2010; 31 Ranieri (ref_28) 2014; 35 Monteiro (ref_8) 2001; 34 |
| References_xml | – volume: 26 start-page: 1600048 year: 2017 ident: ref_20 article-title: An Update on the Pivotal Role of Kinetic Modeling for the Mechanistic Understanding and Design of Bulk and Solution RAFT Polymerization publication-title: Macromol. Theory Simul. doi: 10.1002/mats.201600048 – volume: 31 start-page: 1846 year: 2010 ident: ref_19 article-title: RAFT-Mediated Polymerization—A Story of Incompatible Data? publication-title: Macromol. Rapid Commun. doi: 10.1002/marc.200900907 – volume: 47 start-page: 3455 year: 2009 ident: ref_15 article-title: RAFT polymerization kinetics: How long are the cross-terminating oligomers? publication-title: J. Polym. Sci. Polym. Chem. doi: 10.1002/pola.23385 – volume: 248 start-page: 158 year: 2007 ident: ref_13 article-title: A Missing Reaction Step in Dithiobenzoate-Mediated RAFT Polymerization publication-title: Macromol. Symp. doi: 10.1002/masy.200750217 – volume: 6 start-page: 1061 year: 2015 ident: ref_29 article-title: Entropy driven chain effects on ligation chemistry publication-title: Chem. Sci. doi: 10.1039/C4SC02908A – ident: ref_21 doi: 10.3390/polym10030318 – volume: 101 start-page: 3661 year: 2001 ident: ref_3 article-title: New Polymer Synthesis by Nitroxide Mediated Living Radical Polymerizations publication-title: Chem. Rev. doi: 10.1021/cr990119u – volume: 49 start-page: 4154 year: 2011 ident: ref_18 article-title: RAFT kinetics revisited: Revival of the RAFT debate publication-title: J. Polym. Sci. Polym. Chem. doi: 10.1002/pola.24857 – volume: 11 start-page: 823 year: 2002 ident: ref_9 article-title: Kinetic Analysis of Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerizations: Conditions for Inhibition, Retardation, and Optimum Living Polymerization publication-title: Macromol. Theory Simul. doi: 10.1002/1521-3919(20021101)11:8<823::AID-MATS823>3.0.CO;2-R – volume: 32 start-page: 5457 year: 1999 ident: ref_5 article-title: Living Radical Polymerization with Reversible Addition–Fragmentation Chain Transfer (RAFT): Direct ESR Observation of Intermediate Radicals publication-title: Macromolecules doi: 10.1021/ma990316v – volume: 101 start-page: 2921 year: 2001 ident: ref_2 article-title: Atom Transfer Radical Polymerization publication-title: Chem. Rev. doi: 10.1021/cr940534g – volume: 49 start-page: 993 year: 2000 ident: ref_7 article-title: Living free radical polymerization with reversible addition–Fragmentation chain transfer (the life of RAFT) publication-title: Polym. Int. doi: 10.1002/1097-0126(200009)49:9<993::AID-PI506>3.0.CO;2-6 – volume: 214 start-page: 924 year: 2013 ident: ref_30 article-title: EPR Study into Cross-Termination and Fragmentation with the Phenylethyl–Phenylethyl Dithiobenzoate RAFT Model System publication-title: Macromol. Chem. Phys. doi: 10.1002/macp.201200668 – volume: 8 start-page: 2972 year: 2017 ident: ref_25 article-title: High-throughput polymer screening in microreactors: Boosting the Passerini three component reaction publication-title: Polym. Chem. doi: 10.1039/C7PY00360A – volume: 35 start-page: 2023 year: 2014 ident: ref_28 article-title: Direct Access to Dithiobenzoate RAFT Agent Fragmentation Rate Coefficients by ESR Spin-Trapping publication-title: Macromol. Rapid Commun. doi: 10.1002/marc.201400518 – volume: 2017 start-page: 6474 year: 2017 ident: ref_24 article-title: Online Monitoring of Polymerizations: Current Status publication-title: Eur. J. Org. Chem. doi: 10.1002/ejoc.201700851 – volume: 34 start-page: 349 year: 2001 ident: ref_8 article-title: Intermediate Radical Termination as the Mechanism for Retardation in Reversible Addition–Fragmentation Chain Transfer Polymerization publication-title: Macromolecules doi: 10.1021/ma001484m – volume: 1 start-page: 1437 year: 2010 ident: ref_27 article-title: Use of spin traps to measure the addition and fragmentation rate coefficients of small molecule RAFT-adduct radicals publication-title: Polym. Chem. doi: 10.1039/c0py00245c – ident: ref_17 doi: 10.1002/macp.201700381 – volume: 11 start-page: 1700016 year: 2017 ident: ref_26 article-title: The Kinetics of n-Butyl Acrylate Radical Polymerization Revealed in a Single Experiment by Real Time On-line Mass Spectrometry Monitoring publication-title: Macromol. React. Eng. doi: 10.1002/mren.201700016 – volume: 51 start-page: 4611 year: 2015 ident: ref_23 article-title: Watching polymers grow: Real time monitoring of polymerizations via an on-line ESI-MS/microreactor coupling publication-title: Chem. Commun. doi: 10.1039/C4CC10426A – volume: 177 start-page: 163 year: 2018 ident: ref_4 article-title: How chain length dependencies interfere with the bulk RAFT polymerization rate and microstructural control publication-title: Chem. Eng. Sci. doi: 10.1016/j.ces.2017.11.043 – volume: 40 start-page: 3914 year: 2007 ident: ref_11 article-title: Intermediate Radical Termination in Reversible Addition-Fragmentation Chain Transfer-Mediated Polymerization: Identification of Termination Products publication-title: Macromolecules doi: 10.1021/ma0628634 – volume: 41 start-page: 6400 year: 2008 ident: ref_14 article-title: RAFT Polymerization Kinetics: Combination of Apparently Conflicting Models publication-title: Macromolecules doi: 10.1021/ma800388c – volume: 31 start-page: 5559 year: 1998 ident: ref_1 article-title: Living Free-Radical Polymerization by Reversible Addition−Fragmentation Chain Transfer: The RAFT Process publication-title: Macromolecules doi: 10.1021/ma9804951 – volume: 27 start-page: 1299 year: 2006 ident: ref_16 article-title: Mechanism of Dithiobenzoate-Mediated RAFT Polymerization: A Missing Reaction Step publication-title: Macromol. Rapid Commun. doi: 10.1002/marc.200600317 – volume: 44 start-page: 5809 year: 2006 ident: ref_6 article-title: Mechanism and kinetics of dithiobenzoate-mediated RAFT polymerization. I. The current situation publication-title: J. Polym. Sci. Polym. Chem. doi: 10.1002/pola.21589 – volume: 36 start-page: 2149 year: 2015 ident: ref_22 article-title: Improved Livingness and Control over Branching in RAFT Polymerization of Acrylates: Could Microflow Synthesis Make the Difference? publication-title: Macromol. Rapid Commun. doi: 10.1002/marc.201500357 – volume: 41 start-page: 2828 year: 2003 ident: ref_10 article-title: The reversible addition-fragmentation chain transfer process and the strength and limitations of modeling: Comment on “the magnitude of the fragmentation rate coefficient” publication-title: J. Polym. Sci. Polym. Chem. doi: 10.1002/pola.10854 – volume: 27 start-page: 473 year: 2006 ident: ref_12 article-title: Computational Studies of RAFT Polymerization–Mechanistic Insights and Practical Applications publication-title: Macromol. Rapid Commun. doi: 10.1002/marc.200500832 |
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| SubjectTerms | Addition polymerization Benzoates Chain transfer Equilibrium Free radicals Mass spectrometry Microreactors Molecular weight Monitoring NMR Nuclear magnetic resonance Polymerization Scientific imaging Shift reaction Software Solvents Spectroscopy |
| Title | Mapping Dithiobenzoate-Mediated RAFT Polymerization Products via Online Microreactor/Mass Spectrometry Monitoring |
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