Direct Electrochemical Preparation of Cobalt, Tungsten, and Tungsten Carbide from Cemented Carbide Scrap

A novel process of preparing cobalt, tungsten, and tungsten carbide powders from cemented carbide scrap by molten salt electrolysis has been investigated in this paper. In this experiment, WC-6Co and NaCl–KCl salt were used as sacrificial anode and electrolyte, respectively. The dissolution potentia...

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Veröffentlicht in:	Metallurgical and materials transactions. B, Process metallurgy and materials processing science Jg. 48; H. 1; S. 692 - 700
Hauptverfasser:	Xiao, Xiangjun, Xi, Xiaoli, Nie, Zuoren, Zhang, Liwen, Ma, Liwen
Format:	Journal Article
Sprache:	Englisch
Veröffentlicht:	New York Springer US 01.02.2017 Springer Nature B.V
Schlagworte:	Carbides Cermets Characterization and Evaluation of Materials Chemistry and Materials Science Cobalt Cobalt powders Electrolysis Extraction processes Heavy metals Materials Science Metal scrap Metallic Materials Nanotechnology Scrap Structural Materials Surfaces and Interfaces Thin Films Tungsten Tungsten carbide Tungsten carbides Voltammetry Tungsten Powder Tungsten Carbide Cobalt Tungsten Electrolysis Time
ISSN:	1073-5615, 1543-1916
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Abstract	A novel process of preparing cobalt, tungsten, and tungsten carbide powders from cemented carbide scrap by molten salt electrolysis has been investigated in this paper. In this experiment, WC-6Co and NaCl–KCl salt were used as sacrificial anode and electrolyte, respectively. The dissolution potential of cobalt and WC was determined by linear sweep voltammetry to be 0 and 0.6 V ( vs Ag/AgCl), respectively. Furthermore, the electrochemical behavior of cobalt and tungsten ions was investigated by a variety of electrochemical techniques. Results of cyclic voltammetry (CV) and square-wave voltammetry show that the cobalt and tungsten ions existed as Co 2+ and W 2+ on melts, respectively. The effect of applied voltage, electrolysis current, and electrolysis times on the composition of the product was studied. Results showed that pure cobalt powder can be obtained when the electrolysis potential is lower than 0.6 V or during low current and short times. Double-cathode and two-stage electrolysis was utilized for the preparation of cobalt, tungsten carbide, and tungsten powders. Additionally, X-ray diffraction results confirm that the product collected at cathodes 1 and 2 is pure Co and WC, respectively. Pure tungsten powder was obtained after electrolysis of the second part. Scanning electron microscope results show that the diameters of tungsten, tungsten carbide, and cobalt powder are smaller than 100, 200, and 200 nm, respectively.
AbstractList	A novel process of preparing cobalt, tungsten, and tungsten carbide powders from cemented carbide scrap by molten salt electrolysis has been investigated in this paper. In this experiment, WC-6Co and NaCl-KCl salt were used as sacrificial anode and electrolyte, respectively. The dissolution potential of cobalt and WC was determined by linear sweep voltammetry to be 0 and 0.6 V (vs Ag/AgCl), respectively. Furthermore, the electrochemical behavior of cobalt and tungsten ions was investigated by a variety of electrochemical techniques. Results of cyclic voltammetry (CV) and square-wave voltammetry show that the cobalt and tungsten ions existed as Co2+ and W2+ on melts, respectively. The effect of applied voltage, electrolysis current, and electrolysis times on the composition of the product was studied. Results showed that pure cobalt powder can be obtained when the electrolysis potential is lower than 0.6 V or during low current and short times. Double-cathode and two-stage electrolysis was utilized for the preparation of cobalt, tungsten carbide, and tungsten powders. Additionally, X-ray diffraction results confirm that the product collected at cathodes 1 and 2 is pure Co and WC, respectively. Pure tungsten powder was obtained after electrolysis of the second part. Scanning electron microscope results show that the diameters of tungsten, tungsten carbide, and cobalt powder are smaller than 100, 200, and 200 nm, respectively. A novel process of preparing cobalt, tungsten, and tungsten carbide powders from cemented carbide scrap by molten salt electrolysis has been investigated in this paper. In this experiment, WC-6Co and NaCl-KCl salt were used as sacrificial anode and electrolyte, respectively. The dissolution potential of cobalt and WC was determined by linear sweep voltammetry to be 0 and 0.6 V (vs Ag/AgCl), respectively. Furthermore, the electrochemical behavior of cobalt and tungsten ions was investigated by a variety of electrochemical techniques. Results of cyclic voltammetry (CV) and square-wave voltammetry show that the cobalt and tungsten ions existed as Co super(2+) and W super(2+) on melts, respectively. The effect of applied voltage, electrolysis current, and electrolysis times on the composition of the product was studied. Results showed that pure cobalt powder can be obtained when the electrolysis potential is lower than 0.6 V or during low current and short times. Double-cathode and two-stage electrolysis was utilized for the preparation of cobalt, tungsten carbide, and tungsten powders. Additionally, X-ray diffraction results confirm that the product collected at cathodes 1 and 2 is pure Co and WC, respectively. Pure tungsten powder was obtained after electrolysis of the second part. Scanning electron microscope results show that the diameters of tungsten, tungsten carbide, and cobalt powder are smaller than 100, 200, and 200 nm, respectively. A novel process of preparing cobalt, tungsten, and tungsten carbide powders from cemented carbide scrap by molten salt electrolysis has been investigated in this paper. In this experiment, WC-6Co and NaCl–KCl salt were used as sacrificial anode and electrolyte, respectively. The dissolution potential of cobalt and WC was determined by linear sweep voltammetry to be 0 and 0.6 V ( vs Ag/AgCl), respectively. Furthermore, the electrochemical behavior of cobalt and tungsten ions was investigated by a variety of electrochemical techniques. Results of cyclic voltammetry (CV) and square-wave voltammetry show that the cobalt and tungsten ions existed as Co 2+ and W 2+ on melts, respectively. The effect of applied voltage, electrolysis current, and electrolysis times on the composition of the product was studied. Results showed that pure cobalt powder can be obtained when the electrolysis potential is lower than 0.6 V or during low current and short times. Double-cathode and two-stage electrolysis was utilized for the preparation of cobalt, tungsten carbide, and tungsten powders. Additionally, X-ray diffraction results confirm that the product collected at cathodes 1 and 2 is pure Co and WC, respectively. Pure tungsten powder was obtained after electrolysis of the second part. Scanning electron microscope results show that the diameters of tungsten, tungsten carbide, and cobalt powder are smaller than 100, 200, and 200 nm, respectively.
Author	Xi, Xiaoli Nie, Zuoren Zhang, Liwen Xiao, Xiangjun Ma, Liwen
Author_xml	– sequence: 1 givenname: Xiangjun surname: Xiao fullname: Xiao, Xiangjun organization: College of Material Science and Engineering, Beijing University of Technology – sequence: 2 givenname: Xiaoli surname: Xi fullname: Xi, Xiaoli email: xixiaoli@bjut.edu.cn organization: College of Material Science and Engineering, Beijing University of Technology – sequence: 3 givenname: Zuoren surname: Nie fullname: Nie, Zuoren organization: College of Material Science and Engineering, Beijing University of Technology – sequence: 4 givenname: Liwen surname: Zhang fullname: Zhang, Liwen organization: College of Material Science and Engineering, Beijing University of Technology – sequence: 5 givenname: Liwen surname: Ma fullname: Ma, Liwen organization: College of Material Science and Engineering, Beijing University of Technology
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Snippet	A novel process of preparing cobalt, tungsten, and tungsten carbide powders from cemented carbide scrap by molten salt electrolysis has been investigated in...
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SubjectTerms	Carbides Cermets Characterization and Evaluation of Materials Chemistry and Materials Science Cobalt Cobalt powders Electrolysis Extraction processes Heavy metals Materials Science Metal scrap Metallic Materials Nanotechnology Scrap Structural Materials Surfaces and Interfaces Thin Films Tungsten Tungsten carbide Tungsten carbides Voltammetry
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Title	Direct Electrochemical Preparation of Cobalt, Tungsten, and Tungsten Carbide from Cemented Carbide Scrap
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