Targeted Synthesis of a Highly Stable Aluminium Phosphonate Metal–Organic Framework Showing Reversible HCl Adsorption

A concept for obtaining isoreticular compounds with tri‐ instead of tetravalent metal cations using highly acidic reaction conditions was developed and successfully applied in a high throughput study using N,N′‐piperazinebis(methylenephosphonic acid) (H4PMP), that resulted in the discovery of a new...

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Bibliographic Details
Published in:	Angewandte Chemie International Edition Vol. 62; no. 26; pp. e202303561 - n/a
Main Authors:	Reichenau, Timm M., Steinke, Felix, Wharmby, Michael T., Näther, Christian, Engesser, Tobias A., Stock, Norbert
Format:	Journal Article
Language:	English
Published:	Germany Wiley Subscription Services, Inc 26.06.2023
Edition:	International ed. in English
Subjects:	Adsorption Aluminium Phosphonate Aluminum Aqueous solutions Cations Desorption Framework Stability HCl Adsorption High-Throughput Infrared spectroscopy Metal ions Metal-organic frameworks Metal–Organic Framework Phosphonates Vapor phases HCl Adsorption High-Throughput Metal-Organic Framework Aluminium Phosphonate Framework Stability
ISSN:	1433-7851, 1521-3773, 1521-3773
Online Access:	Get full text
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