Halogen bonding between metal centers and halocarbons

Metal-involving halogen bonding was detected in a series of associates of CHI3 with trans-[PtX2(NCNAlk2)2] (X = Cl, Br). The HI2C-Iη(1)(Pt) halogen bonding and the bifurcated HI2C-Iη(2)(Pt-Cl) halogen bonding - the latter undergoes the thermally induced reversible HI2C-I∙∙∙η(2)(Pt-Cl) ⇄ HI2C-I∙∙∙η(1...

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Bibliographic Details
Published in:	Chemical communications (Cambridge, England) Vol. 52; no. 32; pp. 5565 - 5568
Main Authors:	Ivanov, Daniil M, Novikov, Alexander S, Ananyev, Ivan V, Kirina, Yulia V, Kukushkin, Vadim Yu
Format:	Journal Article
Language:	English
Published:	England 25.04.2016
ISSN:	1364-548X
Online Access:	Get more information
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Summary:	Metal-involving halogen bonding was detected in a series of associates of CHI3 with trans-[PtX2(NCNAlk2)2] (X = Cl, Br). The HI2C-Iη(1)(Pt) halogen bonding and the bifurcated HI2C-Iη(2)(Pt-Cl) halogen bonding - the latter undergoes the thermally induced reversible HI2C-I∙∙∙η(2)(Pt-Cl) ⇄ HI2C-I∙∙∙η(1)(Pt) transformation - were observed and confirmed theoretically.
Bibliography:	ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23
ISSN:	1364-548X
DOI:	10.1039/c6cc01107a