Low‐Spin and High‐Spin Perferryl Intermediates in Non‐Heme Iron Catalyzed Oxidations of Aliphatic C−H Groups

The selectivity patterns of iron catalysts of the Fe(PDP) family in aliphatic C−H oxidation with H2O2 have been studied (PDP=N,N′‐bis(pyridine‐2‐ylmethyl)‐2,2′‐bipyrrolidine). Cyclohexane, adamantane, 1‐bromo‐3,7‐dimethyloctane, 3,7‐dimethyloctyl acetate, (−)‐acetoxy‐p‐menthane, and cis‐1,2‐dimethyl...

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Bibliographic Details
Published in:	Chemistry : a European journal Vol. 27; no. 28; pp. 7781 - 7788
Main Authors:	Zima, Alexandra M., Lyakin, Oleg Y., Bryliakov, Konstantin P., Talsi, Evgenii P.
Format:	Journal Article
Language:	English
Published:	Germany Wiley Subscription Services, Inc 17.05.2021
Subjects:	Acetic acid Aliphatic compounds biomimetic chemistry Catalysts Chemistry Congeners Cyclohexane Decay rate Enantiomers Epoxidation Heme Hydrogen peroxide Intermediates Iron mechanism Oxidation Pyridines Rate constants Regioselectivity Selectivity Substrates selectivity oxidation iron biomimetic chemistry intermediates mechanism
ISSN:	0947-6539, 1521-3765, 1521-3765
Online Access:	Get full text
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