A Cationic Oligomer as an Organic Template for Direct Synthesis of Aluminosilicate ITH Zeolite

There are a large number of zeolites, such as ITH, that cannot be prepared in the aluminosilicate form. Now, the successful synthesis of aluminosilicate ITH zeolite using a simple cationic oligomer as an organic template is presented. Key to the success is that the cationic oligomer has a strong com...

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Published in:	Angewandte Chemie International Edition Vol. 59; no. 36; pp. 15649 - 15655
Main Authors:	Lei, Chi, Dong, Zhuoya, Martínez, Cristina, Martínez‐Triguero, Joaquín, Chen, Wei, Wu, Qinming, Meng, Xiangju, Parvulescu, Andrei‐Nicolae, De Baerdemaeker, Trees, Müller, Ulrich, Zheng, Anmin, Ma, Yanhang, Zhang, Weiping, Yokoi, Toshiyuki, Marler, Bernd, De Vos, Dirk E., Kolb, Ute, Corma, Avelino, Xiao, Feng‐Shou
Format:	Journal Article
Language:	English
Published:	Germany Wiley Subscription Services, Inc 01.09.2020
Edition:	International ed. in English
Subjects:	aluminosilicate ITH Aluminosilicates Aluminum Aluminum silicates cationic oligomers Cations Crystal morphology direct synthesis MTP reaction Propylene Selectivity Synthesis Zeolites zeolite aluminosilicate ITH cationic oligomer direct synthesis MTP reaction
ISSN:	1433-7851, 1521-3773, 1521-3773
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Abstract	There are a large number of zeolites, such as ITH, that cannot be prepared in the aluminosilicate form. Now, the successful synthesis of aluminosilicate ITH zeolite using a simple cationic oligomer as an organic template is presented. Key to the success is that the cationic oligomer has a strong complexation ability with aluminum species combined with a structural directing ability for the ITH structure similar to that of the conventional organic template. The aluminosilicate ITH zeolite has very high crystallinity, nanosheet‐like crystal morphology, large surface area, fully four‐coordinated Al species, and abundant acidic sites. Methanol‐to‐propylene (MTP) tests reveal that the Al‐ITH zeolite shows much higher selectivity for propylene and longer lifetime than commercial ZSM‐5. FCC tests show that Al‐ITH zeolite is a good candidate as a shape‐selective FCC additive for enhancing propylene and butylene selectivity. Oligomers to the aid of ITH: A way to directly synthesize aluminosilicate ITH (Al‐ITH) zeolite using a cationic oligomer as an organic template is presented: The strong complexation ability with aluminum species is a key factor for the successful preparation.
AbstractList	There are a large number of zeolites, such as ITH, that cannot be prepared in the aluminosilicate form. Now, the successful synthesis of aluminosilicate ITH zeolite using a simple cationic oligomer as an organic template is presented. Key to the success is that the cationic oligomer has a strong complexation ability with aluminum species combined with a structural directing ability for the ITH structure similar to that of the conventional organic template. The aluminosilicate ITH zeolite has very high crystallinity, nanosheet‐like crystal morphology, large surface area, fully four‐coordinated Al species, and abundant acidic sites. Methanol‐to‐propylene (MTP) tests reveal that the Al‐ITH zeolite shows much higher selectivity for propylene and longer lifetime than commercial ZSM‐5. FCC tests show that Al‐ITH zeolite is a good candidate as a shape‐selective FCC additive for enhancing propylene and butylene selectivity. There are a large number of zeolites, such as ITH, that cannot be prepared in the aluminosilicate form. Now, the successful synthesis of aluminosilicate ITH zeolite using a simple cationic oligomer as an organic template is presented. Key to the success is that the cationic oligomer has a strong complexation ability with aluminum species combined with a structural directing ability for the ITH structure similar to that of the conventional organic template. The aluminosilicate ITH zeolite has very high crystallinity, nanosheet‐like crystal morphology, large surface area, fully four‐coordinated Al species, and abundant acidic sites. Methanol‐to‐propylene (MTP) tests reveal that the Al‐ITH zeolite shows much higher selectivity for propylene and longer lifetime than commercial ZSM‐5. FCC tests show that Al‐ITH zeolite is a good candidate as a shape‐selective FCC additive for enhancing propylene and butylene selectivity. Oligomers to the aid of ITH: A way to directly synthesize aluminosilicate ITH (Al‐ITH) zeolite using a cationic oligomer as an organic template is presented: The strong complexation ability with aluminum species is a key factor for the successful preparation. Despite great progress in the synthesis of aluminosilicate zeolites, there are still a large number of zeolites that could not be prepared in the aluminosilicate form. One of typical examples is ITH zeolite, where direct synthesis of aluminosilicate ITH is currently still challenging. Herein, for the first time we demonstrate the successful synthesis of aluminosilicate ITH zeolite using a simple cationic oligomer as an organic template. The key to this success is that the cationic oligomer has a strong complexation ability with aluminum species combined with a structural directing ability for the ITH structure similar to that of the conventional organic template. Physicochemical analysis shows that the aluminosilicate ITH zeolite has very high crystallinity, nanosheet-like crystal morphology, large surface area, fully four-coordinated Al species, and abundant acidic sites. More importantly, methanol-to-propylene (MTP) tests reveal that the Al-ITH zeolite shows much higher selectivity for propylene and longer lifetime than commercial ZSM-5. FCC tests show that Al-ITH zeolite is a good candidate as a shape selective FCC additive for enhancing propylene and butylene selectivity. There are a large number of zeolites, such as ITH, that cannot be prepared in the aluminosilicate form. Now, the successful synthesis of aluminosilicate ITH zeolite using a simple cationic oligomer as an organic template is presented. Key to the success is that the cationic oligomer has a strong complexation ability with aluminum species combined with a structural directing ability for the ITH structure similar to that of the conventional organic template. The aluminosilicate ITH zeolite has very high crystallinity, nanosheet-like crystal morphology, large surface area, fully four-coordinated Al species, and abundant acidic sites. Methanol-to-propylene (MTP) tests reveal that the Al-ITH zeolite shows much higher selectivity for propylene and longer lifetime than commercial ZSM-5. FCC tests show that Al-ITH zeolite is a good candidate as a shape-selective FCC additive for enhancing propylene and butylene selectivity.There are a large number of zeolites, such as ITH, that cannot be prepared in the aluminosilicate form. Now, the successful synthesis of aluminosilicate ITH zeolite using a simple cationic oligomer as an organic template is presented. Key to the success is that the cationic oligomer has a strong complexation ability with aluminum species combined with a structural directing ability for the ITH structure similar to that of the conventional organic template. The aluminosilicate ITH zeolite has very high crystallinity, nanosheet-like crystal morphology, large surface area, fully four-coordinated Al species, and abundant acidic sites. Methanol-to-propylene (MTP) tests reveal that the Al-ITH zeolite shows much higher selectivity for propylene and longer lifetime than commercial ZSM-5. FCC tests show that Al-ITH zeolite is a good candidate as a shape-selective FCC additive for enhancing propylene and butylene selectivity.
Author	Wu, Qinming Yokoi, Toshiyuki Xiao, Feng‐Shou De Baerdemaeker, Trees Ma, Yanhang Marler, Bernd Corma, Avelino Martínez‐Triguero, Joaquín Martínez, Cristina Zheng, Anmin De Vos, Dirk E. Chen, Wei Parvulescu, Andrei‐Nicolae Lei, Chi Dong, Zhuoya Meng, Xiangju Müller, Ulrich Zhang, Weiping Kolb, Ute
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Snippet	There are a large number of zeolites, such as ITH, that cannot be prepared in the aluminosilicate form. Now, the successful synthesis of aluminosilicate ITH... Despite great progress in the synthesis of aluminosilicate zeolites, there are still a large number of zeolites that could not be prepared in the...
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StartPage	15649
SubjectTerms	aluminosilicate ITH Aluminosilicates Aluminum Aluminum silicates cationic oligomers Cations Crystal morphology direct synthesis MTP reaction Propylene Selectivity Synthesis Zeolites
Title	A Cationic Oligomer as an Organic Template for Direct Synthesis of Aluminosilicate ITH Zeolite
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