Rhodium‐Catalyzed Synthesis of Chiral Monohydrosilanes by Intramolecular C−H Functionalization of Dihydrosilanes

The preparation of chiral monohydrosilanes remains a rarely achieved goal. To this end a Rh‐catalyzed desymmetrization of dihydrosilanes by way of intramolecular C(sp2)−H functionalization under simple and mild conditions has now been developed. This method provides easy access to a broad range of c...

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Bibliographic Details
Published in:	Angewandte Chemie International Edition Vol. 60; no. 8; pp. 4245 - 4251
Main Authors:	Ma, Wenpeng, Liu, Li‐Chuan, An, Kun, He, Tao, He, Wei
Format:	Journal Article
Language:	English
Published:	WEINHEIM Wiley 19.02.2021 Wiley Subscription Services, Inc
Edition:	International ed. in English
Subjects:	Chemical synthesis Chemistry Chemistry, Multidisciplinary desymmetrization dihydrosilanes enantioselectivity monohydrosilane Physical Sciences Rhodium Science & Technology Silicon Silicon compounds Stereochemistry enantioselectivity desymmetrization ASYMMETRIC-SYNTHESIS ENANTIOSELECTIVE SYNTHESIS HYDROSILYLATION dihydrosilanes SILICON-STEREOGENIC SILANES KETONES SILACYCLOBUTANES DEHYDROGENATIVE SILYLATION CONSTRUCTION monohydrosilane BOND ACTIVATION rhodium
ISSN:	1433-7851, 1521-3773, 1521-3773
Online Access:	Get full text
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