Determination of pre-exponential factor and reaction mechanism in a model-free way

The effective activation energy (Eα) dependency is used to compute the dependence of the pre-exponential factor (Aα) and of the mathematical function that describe the reaction mechanism f(α) in a model-free way. The effective rate constant kα(T) depends on both temperature (T) and extent of convers...

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Veröffentlicht in:	Thermochimica acta Jg. 691; S. 178707
1. Verfasser:	Sbirrazzuoli, Nicolas
Format:	Journal Article
Sprache:	Englisch
Veröffentlicht:	Elsevier B.V 01.09.2020 Elsevier
Schlagworte:	activation energy Chemical Sciences Isoconversional kinetic analysis Model-free kinetics Nonisothermal kinetics Pre-exponential factor Reaction mechanism reaction mechanisms temperature Isoconversional kinetic analysis Reaction mechanism Pre-exponential factor Nonisothermal kinetics Model-free kinetics
ISSN:	0040-6031, 1872-762X
Online-Zugang:	Volltext
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