Improved MOF nanoparticle recovery and purification using crosslinked PVDF membranes

Crosslinked PVDF-membranes are demonstrated to offer a viable alternative for centrifugation in the preparation of MOF-particles, thus realising new opportunities at lab-scale and continuous production at large-scale. The membranes combine extreme-pH with solvent stability, thus enabling application...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) Vol. 54; no. 53; p. 7370
Main Authors: Van Goethem, Cédric, Mertens, Matthias, Cirujano, Francisco G, Seo, Jin W, De Vos, Dirk, Vankelecom, Ivo F J
Format: Journal Article
Language:English
Published: England 28.06.2018
ISSN:1364-548X, 1364-548X
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Summary:Crosslinked PVDF-membranes are demonstrated to offer a viable alternative for centrifugation in the preparation of MOF-particles, thus realising new opportunities at lab-scale and continuous production at large-scale. The membranes combine extreme-pH with solvent stability, thus enabling application in any MOF synthesis, demonstrated here for ZIF-8, ZIF-67, HKUST-1, UiO-66 and MIL-53(Al).
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ISSN:1364-548X
1364-548X
DOI:10.1039/c8cc04326d