Improved MOF nanoparticle recovery and purification using crosslinked PVDF membranes

Crosslinked PVDF-membranes are demonstrated to offer a viable alternative for centrifugation in the preparation of MOF-particles, thus realising new opportunities at lab-scale and continuous production at large-scale. The membranes combine extreme-pH with solvent stability, thus enabling application...

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Veröffentlicht in:Chemical communications (Cambridge, England) Jg. 54; H. 53; S. 7370
Hauptverfasser: Van Goethem, Cédric, Mertens, Matthias, Cirujano, Francisco G, Seo, Jin W, De Vos, Dirk, Vankelecom, Ivo F J
Format: Journal Article
Sprache:Englisch
Veröffentlicht: England 28.06.2018
ISSN:1364-548X, 1364-548X
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Abstract Crosslinked PVDF-membranes are demonstrated to offer a viable alternative for centrifugation in the preparation of MOF-particles, thus realising new opportunities at lab-scale and continuous production at large-scale. The membranes combine extreme-pH with solvent stability, thus enabling application in any MOF synthesis, demonstrated here for ZIF-8, ZIF-67, HKUST-1, UiO-66 and MIL-53(Al).
AbstractList Crosslinked PVDF-membranes are demonstrated to offer a viable alternative for centrifugation in the preparation of MOF-particles, thus realising new opportunities at lab-scale and continuous production at large-scale. The membranes combine extreme-pH with solvent stability, thus enabling application in any MOF synthesis, demonstrated here for ZIF-8, ZIF-67, HKUST-1, UiO-66 and MIL-53(Al).Crosslinked PVDF-membranes are demonstrated to offer a viable alternative for centrifugation in the preparation of MOF-particles, thus realising new opportunities at lab-scale and continuous production at large-scale. The membranes combine extreme-pH with solvent stability, thus enabling application in any MOF synthesis, demonstrated here for ZIF-8, ZIF-67, HKUST-1, UiO-66 and MIL-53(Al).
Crosslinked PVDF-membranes are demonstrated to offer a viable alternative for centrifugation in the preparation of MOF-particles, thus realising new opportunities at lab-scale and continuous production at large-scale. The membranes combine extreme-pH with solvent stability, thus enabling application in any MOF synthesis, demonstrated here for ZIF-8, ZIF-67, HKUST-1, UiO-66 and MIL-53(Al).
Author De Vos, Dirk
Cirujano, Francisco G
Seo, Jin W
Vankelecom, Ivo F J
Mertens, Matthias
Van Goethem, Cédric
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  surname: Van Goethem
  fullname: Van Goethem, Cédric
  email: ivo.vankelecom@kuleuven.be
  organization: Center for Surface Chemistry and Catalysis, KU Leuven, Celestijnenlaan 200F box 2461, 3001 Leuven, Belgium. ivo.vankelecom@kuleuven.be
– sequence: 2
  givenname: Matthias
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  fullname: Mertens, Matthias
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  givenname: Francisco G
  surname: Cirujano
  fullname: Cirujano, Francisco G
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  givenname: Jin W
  surname: Seo
  fullname: Seo, Jin W
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  surname: De Vos
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  fullname: Vankelecom, Ivo F J
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Title Improved MOF nanoparticle recovery and purification using crosslinked PVDF membranes
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