An iridium( iii / iv / v ) redox series featuring a terminal imido complex with triplet ground state

The iridium( iii / iv / v ) imido redox series [Ir(N t Bu){N(CHCHP t Bu 2 ) 2 }] 0/+/2+ was synthesized and examined spectroscopically, magnetically, crystallographically and computationally. The monocationic iridium( iv ) imide exhibits an electronic doublet ground state with considerable ‘imidyl’...

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