Functionalization of MWCNTs with atomic nitrogen

In this study of the changes induced by exposing MWCNTs to a nitrogen plasma, it was found by HRTEM that the atomic nitrogen exposure does not significantly etch the surface of the carbon nanotube (CNT). Nevertheless, the atomic nitrogen generated by a microwave plasma effectively grafts amine, nitr...

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Veröffentlicht in:Micron (Oxford, England : 1993) Jg. 40; H. 1; S. 85 - 88
Hauptverfasser: Ruelle, Benoit, Felten, Alexandre, Ghijsen, Jacques, Drube, Wolfgang, Johnson, Robert L., Liang, Duoduo, Erni, Rolf, Van Tendeloo, Gustaaf, Sophie, Peeterbroeck, Dubois, Philippe, Godfroid, Thomas, Hecq, Michel, Bittencourt, Carla
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Sprache:Englisch
Veröffentlicht: England Elsevier Ltd 2009
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ISSN:0968-4328, 1878-4291
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Abstract In this study of the changes induced by exposing MWCNTs to a nitrogen plasma, it was found by HRTEM that the atomic nitrogen exposure does not significantly etch the surface of the carbon nanotube (CNT). Nevertheless, the atomic nitrogen generated by a microwave plasma effectively grafts amine, nitrile, amide, and oxime groups onto the CNT surface, as observed by XPS, altering the density of valence electronic states, as seen in UPS.
AbstractList In this study of the changes induced by exposing MWCNTs to a nitrogen plasma, it was found by HRTEM that the atomic nitrogen exposure does not significantly etch the surface of the carbon nanotube (CNT). Nevertheless, the atomic nitrogen generated by a microwave plasma effectively grafts amine, nitrile, amide, and oxime groups onto the CNT surface, as observed by XPS, altering the density of valence electronic states, as seen in UPS.
In this study of the changes induced by exposing MWCNTs to a nitrogen plasma, it was found by HRTEM that the atomic nitrogen exposure does not significantly etch the surface of the carbon nanotube (CNT). Nevertheless, the atomic nitrogen generated by a microwave plasma effectively grafts amine, nitrile, amide, and oxime groups onto the CNT surface, as observed by XPS, altering the density of valence electronic states, as seen in UPS.In this study of the changes induced by exposing MWCNTs to a nitrogen plasma, it was found by HRTEM that the atomic nitrogen exposure does not significantly etch the surface of the carbon nanotube (CNT). Nevertheless, the atomic nitrogen generated by a microwave plasma effectively grafts amine, nitrile, amide, and oxime groups onto the CNT surface, as observed by XPS, altering the density of valence electronic states, as seen in UPS.
Author Johnson, Robert L.
Erni, Rolf
Hecq, Michel
Drube, Wolfgang
Dubois, Philippe
Van Tendeloo, Gustaaf
Bittencourt, Carla
Ruelle, Benoit
Godfroid, Thomas
Ghijsen, Jacques
Liang, Duoduo
Sophie, Peeterbroeck
Felten, Alexandre
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  organization: Laboratory Electron Spectroscopy (LISE), FUNDP, B-5000 Namur, Belgium
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  givenname: Jacques
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  givenname: Wolfgang
  surname: Drube
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  organization: DESY, Hasylab, D-22603 Hamburg, Germany
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  surname: Johnson
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  fullname: Liang, Duoduo
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  surname: Erni
  fullname: Erni, Rolf
  organization: EMAT, University of Antwerp, B-2020 Antwerp, Belgium
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  surname: Van Tendeloo
  fullname: Van Tendeloo, Gustaaf
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  surname: Dubois
  fullname: Dubois, Philippe
  organization: SMPC, University of Mons-Hainaut, B-7000, Belgium
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  givenname: Carla
  surname: Bittencourt
  fullname: Bittencourt, Carla
  email: carla.bittencourt@materianova.be
  organization: LCIA, University of Mons-Hainaut, Avenue Nicolas Copernic 1, B-7000 Mons, Belgium
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Issue 1
Keywords Plasma
CNTs
High-resolution microscopy
Photoelectron spectroscopy
Chemical functionalization
Surface treatment
Synchrotron radiation
Language English
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Snippet In this study of the changes induced by exposing MWCNTs to a nitrogen plasma, it was found by HRTEM that the atomic nitrogen exposure does not significantly...
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SubjectTerms Chemical functionalization
CNTs
High-resolution microscopy
Photoelectron spectroscopy
Plasma
Surface treatment
Synchrotron radiation
Title Functionalization of MWCNTs with atomic nitrogen
URI https://dx.doi.org/10.1016/j.micron.2008.01.003
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