The kinetics of metal soap crystallization in oil polymers
The crystallization of metal soaps in oil paint is an important chemical phenomenon that affects the appearance and structural stability of many works of art. A deep understanding of the structural transitions that occur during crystallization and their kinetics will help to support conservation dec...
Uloženo v:
| Vydáno v: | Physical chemistry chemical physics : PCCP Ročník 23; číslo 39; s. 22589 |
|---|---|
| Hlavní autoři: | , , , , |
| Médium: | Journal Article |
| Jazyk: | angličtina |
| Vydáno: |
13.10.2021
|
| ISSN: | 1463-9084, 1463-9084 |
| On-line přístup: | Zjistit podrobnosti o přístupu |
| Tagy: |
Přidat tag
Žádné tagy, Buďte první, kdo vytvoří štítek k tomuto záznamu!
|
| Abstract | The crystallization of metal soaps in oil paint is an important chemical phenomenon that affects the appearance and structural stability of many works of art. A deep understanding of the structural transitions that occur during crystallization and their kinetics will help to support conservation decisions that minimize future detrimental change to paintings. We have used a method based on attenuated total reflection Fourier transform infrared spectroscopy and detailed spectrum analysis to quantitatively monitor all relevant metal soap structures during crystallization in a linseed oil matrix with varying degrees of polymerization. It was found that zinc soap crystallization behaviour is strongly influenced by the properties of the oil matrix, slowing down drastically with increasing polymerization, forming crystalline polymorphs in varying ratios, and demonstrating two-stage kinetics. In contrast, lead soap crystallization was invariably fast, but the degree of disorder in the crystallized phases was increasing with matrix polymerization. Besides fundamental insight into the mechanisms of metal soap crystallization, the results lay foundations for improved risk assessment during conservation treatment of oil paintings.The crystallization of metal soaps in oil paint is an important chemical phenomenon that affects the appearance and structural stability of many works of art. A deep understanding of the structural transitions that occur during crystallization and their kinetics will help to support conservation decisions that minimize future detrimental change to paintings. We have used a method based on attenuated total reflection Fourier transform infrared spectroscopy and detailed spectrum analysis to quantitatively monitor all relevant metal soap structures during crystallization in a linseed oil matrix with varying degrees of polymerization. It was found that zinc soap crystallization behaviour is strongly influenced by the properties of the oil matrix, slowing down drastically with increasing polymerization, forming crystalline polymorphs in varying ratios, and demonstrating two-stage kinetics. In contrast, lead soap crystallization was invariably fast, but the degree of disorder in the crystallized phases was increasing with matrix polymerization. Besides fundamental insight into the mechanisms of metal soap crystallization, the results lay foundations for improved risk assessment during conservation treatment of oil paintings. |
|---|---|
| AbstractList | The crystallization of metal soaps in oil paint is an important chemical phenomenon that affects the appearance and structural stability of many works of art. A deep understanding of the structural transitions that occur during crystallization and their kinetics will help to support conservation decisions that minimize future detrimental change to paintings. We have used a method based on attenuated total reflection Fourier transform infrared spectroscopy and detailed spectrum analysis to quantitatively monitor all relevant metal soap structures during crystallization in a linseed oil matrix with varying degrees of polymerization. It was found that zinc soap crystallization behaviour is strongly influenced by the properties of the oil matrix, slowing down drastically with increasing polymerization, forming crystalline polymorphs in varying ratios, and demonstrating two-stage kinetics. In contrast, lead soap crystallization was invariably fast, but the degree of disorder in the crystallized phases was increasing with matrix polymerization. Besides fundamental insight into the mechanisms of metal soap crystallization, the results lay foundations for improved risk assessment during conservation treatment of oil paintings.The crystallization of metal soaps in oil paint is an important chemical phenomenon that affects the appearance and structural stability of many works of art. A deep understanding of the structural transitions that occur during crystallization and their kinetics will help to support conservation decisions that minimize future detrimental change to paintings. We have used a method based on attenuated total reflection Fourier transform infrared spectroscopy and detailed spectrum analysis to quantitatively monitor all relevant metal soap structures during crystallization in a linseed oil matrix with varying degrees of polymerization. It was found that zinc soap crystallization behaviour is strongly influenced by the properties of the oil matrix, slowing down drastically with increasing polymerization, forming crystalline polymorphs in varying ratios, and demonstrating two-stage kinetics. In contrast, lead soap crystallization was invariably fast, but the degree of disorder in the crystallized phases was increasing with matrix polymerization. Besides fundamental insight into the mechanisms of metal soap crystallization, the results lay foundations for improved risk assessment during conservation treatment of oil paintings. |
| Author | Iedema, Piet Hermans, Joen Zuidgeest, Lonneke Keune, Katrien Woutersen, Sander |
| Author_xml | – sequence: 1 givenname: Joen surname: Hermans fullname: Hermans, Joen – sequence: 2 givenname: Lonneke surname: Zuidgeest fullname: Zuidgeest, Lonneke – sequence: 3 givenname: Piet surname: Iedema fullname: Iedema, Piet – sequence: 4 givenname: Sander surname: Woutersen fullname: Woutersen, Sander – sequence: 5 givenname: Katrien surname: Keune fullname: Keune, Katrien |
| BookMark | eNpNjLtOAzEURC0UJJJAwxe4pFm4fq1tOhTxkiLRhDryOtfCxGsv8aYIX89KUFDNHGnOLMgsl4yEXDO4ZSDs3Y75AYTUdn9G5ky2orFg5OxfvyCLWj8BgCkm5uR-84F0HzOO0VdaAu1xdInW4gbqD6c6QYrfbowl05hpiYkOJZ16PNRLch5cqnj1l0vy_vS4Wb0067fn19XDuvES1Ngg8ybYrvNKMVC8C8JxptEqZ3UwohNBquCMC1zitPB2N2ktamhBmy5IviQ3v7_DoXwdsY7bPlaPKbmM5Vi3XGnDlGxB8B_NnExx |
| CitedBy_id | crossref_primary_10_1007_s10118_024_3213_6 crossref_primary_10_1186_s40494_023_00988_3 crossref_primary_10_1016_j_culher_2023_05_031 crossref_primary_10_1126_sciadv_adt0897 crossref_primary_10_1186_s40494_023_01023_1 crossref_primary_10_1016_j_ijheatmasstransfer_2022_123682 crossref_primary_10_1016_j_microc_2025_113476 crossref_primary_10_1515_tsd_2024_2599 crossref_primary_10_1186_s40494_024_01309_y crossref_primary_10_1016_j_cej_2023_145264 |
| ContentType | Journal Article |
| DBID | 7X8 |
| DOI | 10.1039/d1cp03479k |
| DatabaseName | MEDLINE - Academic |
| DatabaseTitle | MEDLINE - Academic |
| DatabaseTitleList | MEDLINE - Academic |
| Database_xml | – sequence: 1 dbid: 7X8 name: MEDLINE - Academic url: https://search.proquest.com/medline sourceTypes: Aggregation Database |
| DeliveryMethod | no_fulltext_linktorsrc |
| Discipline | Chemistry |
| EISSN | 1463-9084 |
| GroupedDBID | --- -DZ -~X 0-7 0R~ 123 29O 2WC 4.4 53G 705 70~ 7X8 7~J 87K AAEMU AAFBY AAIWI AAJAE AAMEH AANOJ AAWGC AAXHV AAXPP ABASK ABDVN ABEMK ABJNI ABPDG ABRYZ ABXOH ACGFO ACGFS ACIWK ACLDK ACNCT ADMRA ADSRN AEFDR AENEX AENGV AESAV AETIL AFLYV AFOGI AFRDS AFRZK AFVBQ AGEGJ AGKEF AGMRB AGRSR AHGCF AKMSF ALMA_UNASSIGNED_HOLDINGS ALUYA ANUXI APEMP ASKNT AUDPV AZFZN BLAPV BSQNT C6K CS3 D0L DU5 EBS ECGLT EE0 EF- F5P GGIMP GNO H13 HZ~ H~N IDZ J3G J3I M4U N9A NHB O9- P2P R56 R7B R7C RAOCF RCNCU RNS RPMJG RRA RRC RSCEA SKA SKF SLH TN5 TWZ UHB VH6 WH7 YNT |
| ID | FETCH-LOGICAL-c405t-e1c8f9bbc551052bf3a217e95a97f83b3f45fa8af24e510c9d4056e706078bf42 |
| IEDL.DBID | 7X8 |
| ISICitedReferencesCount | 17 |
| ISICitedReferencesURI | http://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestLinkType=CitingArticles&DestApp=WOS_CPL&KeyUT=000701992300001&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| ISSN | 1463-9084 |
| IngestDate | Sun Nov 09 14:34:52 EST 2025 |
| IsDoiOpenAccess | false |
| IsOpenAccess | true |
| IsPeerReviewed | true |
| IsScholarly | true |
| Issue | 39 |
| Language | English |
| LinkModel | DirectLink |
| MergedId | FETCHMERGED-LOGICAL-c405t-e1c8f9bbc551052bf3a217e95a97f83b3f45fa8af24e510c9d4056e706078bf42 |
| Notes | ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 |
| OpenAccessLink | https://pubs.rsc.org/en/content/articlepdf/2021/cp/d1cp03479k |
| PQID | 2578154603 |
| PQPubID | 23479 |
| ParticipantIDs | proquest_miscellaneous_2578154603 |
| PublicationCentury | 2000 |
| PublicationDate | 2021-10-13 |
| PublicationDateYYYYMMDD | 2021-10-13 |
| PublicationDate_xml | – month: 10 year: 2021 text: 2021-10-13 day: 13 |
| PublicationDecade | 2020 |
| PublicationTitle | Physical chemistry chemical physics : PCCP |
| PublicationYear | 2021 |
| SSID | ssj0001513 |
| Score | 2.4784715 |
| Snippet | The crystallization of metal soaps in oil paint is an important chemical phenomenon that affects the appearance and structural stability of many works of art.... |
| SourceID | proquest |
| SourceType | Aggregation Database |
| StartPage | 22589 |
| Title | The kinetics of metal soap crystallization in oil polymers |
| URI | https://www.proquest.com/docview/2578154603 |
| Volume | 23 |
| WOSCitedRecordID | wos000701992300001&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D |
| hasFullText | |
| inHoldings | 1 |
| isFullTextHit | |
| isPrint | |
| link | http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV1LSwMxEA5qBb34Ft9E8Bq6m0eTeBEpFk_Fg0JvJclOoLjurt0q9N-bbHfpwYvgPYFkMpn5MpmZD6E744S0WZYSIweOcGaBWA8pEYJqp6X1KnUN2YQcj9Vkol_agFvdplV2NrEx1FnpYoy8H1UruPtBwh6qTxJZo-LvakuhsYl6LECZmNIlJ-tu4cGbsVV1ESM6UbxrT8p0P0tdlcQqyvdfRrjxLKP9_67pAO21mBI_rpTgEG1AcYR2hh2V2zG6D8qA3wOejD2ZcenxBwTMjevSVNjNlwEg5nlbj4lnBS5nOa7KfBlD2ifobfT0OnwmLWkCcQF7LQikTnltrRMROlHrmQmvDtDCaOkVs8xz4Y0ynnIII5zOwrQBxCY6UlnP6SnaKsoCzhAGSIB6EBqc5ZxTk2nQTHPlhAVl9Dm67cQyDRuKPw2mgPKrnq4Fc_GHMZdol8ZMkZgnwq5Qz4eLB9do230vZvX8pjnTH-PWrVw |
| linkProvider | ProQuest |
| openUrl | ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=The+kinetics+of+metal+soap+crystallization+in+oil+polymers&rft.jtitle=Physical+chemistry+chemical+physics+%3A+PCCP&rft.au=Hermans%2C+Joen&rft.au=Zuidgeest%2C+Lonneke&rft.au=Iedema%2C+Piet&rft.au=Woutersen%2C+Sander&rft.date=2021-10-13&rft.issn=1463-9084&rft.eissn=1463-9084&rft.volume=23&rft.issue=39&rft.spage=22589&rft_id=info:doi/10.1039%2Fd1cp03479k&rft.externalDBID=NO_FULL_TEXT |
| thumbnail_l | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=1463-9084&client=summon |
| thumbnail_m | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=1463-9084&client=summon |
| thumbnail_s | http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=1463-9084&client=summon |