Short time dynamics in the isotropic phase of liquid crystals: the aspect ratio and the power law decay
Optical heterodyne detected optical Kerr effect (OHD-OKE) experiments are used to study the orientational dynamics of the liquid crystal 4 ′-octyl-4-biphenylcarbonitrile (8CB) in the isotropic phase near the isotropic to nematic phase transition. The results are compared to those for three other liq...
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| Published in: | Chemical physics letters Vol. 366; no. 1; pp. 82 - 87 |
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| Language: | English |
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Elsevier B.V
25.11.2002
Elsevier Science |
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| ISSN: | 0009-2614, 1873-4448 |
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| Abstract | Optical heterodyne detected optical Kerr effect (OHD-OKE) experiments are used to study the orientational dynamics of the liquid crystal 4
′-octyl-4-biphenylcarbonitrile (8CB) in the isotropic phase near the isotropic to nematic phase transition. The results are compared to those for three other liquid crystals. The 8CB data display a short time scale temperature independent power law decay and a long time scale exponential decay with a temperature dependence described by Landau–de Gennes theory. The power law exponent is −0.56. Combining this result with previous results for three other liquid crystals [J. Chem. Phys. 116 (2002) 6339; J. Chem. Phys. 116 (2002) 360], it is found that the power law exponent depends linearly on the aspect ratio of the liquid crystal. |
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| AbstractList | Optical heterodyne detected optical Kerr effect (OHD-OKE) experiments are used to study the orientational dynamics of the liquid crystal 4
′-octyl-4-biphenylcarbonitrile (8CB) in the isotropic phase near the isotropic to nematic phase transition. The results are compared to those for three other liquid crystals. The 8CB data display a short time scale temperature independent power law decay and a long time scale exponential decay with a temperature dependence described by Landau–de Gennes theory. The power law exponent is −0.56. Combining this result with previous results for three other liquid crystals [J. Chem. Phys. 116 (2002) 6339; J. Chem. Phys. 116 (2002) 360], it is found that the power law exponent depends linearly on the aspect ratio of the liquid crystal. |
| Author | Cang, Hu Fayer, M.D Li, Jie |
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| Cites_doi | 10.1016/B978-0-12-025006-6.50008-5 10.1063/1.458832 10.1021/j100178a029 10.1016/0167-7322(95)00888-9 10.1063/1.1287595 10.1103/PhysRevLett.30.895 10.1063/1.456264 10.1063/1.1423948 10.1063/1.1659051 10.1016/0375-9601(78)90123-8 10.1063/1.453733 10.1063/1.447441 10.1063/1.477340 10.1021/jp002949d 10.1063/1.453454 10.1063/1.1462039 10.1103/PhysRevA.14.1281 10.1103/PhysRevLett.25.503 10.1021/j100139a036 10.1021/je000219t 10.1063/1.1682297 10.1109/3.144 10.1016/0009-2614(92)85537-K |
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| Keywords | Exponential distribution Molecular dynamics Liquid phase Experimental study Aspect ratio Liquid crystals Relaxation time Molecular orientation Optical Kerr effect Temperature effects Saturated aliphatic compound Heterodyne detection Benzenic compound Nitriles Molecular reorientation Power law Organic compounds Liquid nematic transformation |
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| SubjectTerms | Condensed matter: structure, mechanical and thermal properties Exact sciences and technology Liquid crystals Orientational order of liquid crystals; electric and magnetic field effects on order Physics Structure of solids and liquids; crystallography |
| Title | Short time dynamics in the isotropic phase of liquid crystals: the aspect ratio and the power law decay |
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