Insights into the remediation characterization of modified bentonite in minimizing organosulphur compounds from diesel fuel
•ORS uptake was marginally affected with the particle size.•ORS mainly uptakes on the external surface area of the adsorbents.•Acid activation process enhanced the adsorptive efficiency of AB.•Acid activation process did increase the AB's surface area and pore volumes.•ORS that was adsorbed by...
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| Published in: | Journal of industrial and engineering chemistry (Seoul, Korea) Vol. 28; pp. 282 - 293 |
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| Main Authors: | , , , |
| Format: | Journal Article |
| Language: | English |
| Published: |
Elsevier B.V
25.08.2015
한국공업화학회 |
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| ISSN: | 1226-086X, 1876-794X |
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| Abstract | •ORS uptake was marginally affected with the particle size.•ORS mainly uptakes on the external surface area of the adsorbents.•Acid activation process enhanced the adsorptive efficiency of AB.•Acid activation process did increase the AB's surface area and pore volumes.•ORS that was adsorbed by AB (4.7920mg S/g) is more than that adsorbed by TB.
In this work, physical and chemical characteristics of the raw, treated, and acid activated bentonite were investigated using XRD, FTIR, scanning electron microscopy (SEM), and differential thermal analysis (DTA)/thermogravimetry (TG) analysis and surface area and porosity determination techniques. The organosulphur compounds (ORS) uptake was slightly affected by the particle size indicating that the removal of ORS mainly occurred on the external surface of the modified bentonite samples. The acid activation process enhanced the adsorptive efficiency of the bentonite sample through increasing both the surface area and the pore volume, in addition to the release of a considerable amount of interlayer cations of the clay. |
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| AbstractList | In this work, physical and chemical characteristics of the raw, treated, and acid activated bentonite wereinvestigated using XRD, FTIR, scanning electron microscopy (SEM), and differential thermal analysis(DTA)/thermogravimetry (TG) analysis and surface area and porosity determination techniques. Theorganosulphur compounds (ORS) uptake was slightly affected by the particle size indicating that theremoval of ORS mainly occurred on the external surface of the modified bentonite samples. The acidactivation process enhanced the adsorptive efficiency of the bentonite sample through increasing boththe surface area and the pore volume, in addition to the release of a considerable amount of interlayercations of the clay. KCI Citation Count: 6 •ORS uptake was marginally affected with the particle size.•ORS mainly uptakes on the external surface area of the adsorbents.•Acid activation process enhanced the adsorptive efficiency of AB.•Acid activation process did increase the AB's surface area and pore volumes.•ORS that was adsorbed by AB (4.7920mg S/g) is more than that adsorbed by TB. In this work, physical and chemical characteristics of the raw, treated, and acid activated bentonite were investigated using XRD, FTIR, scanning electron microscopy (SEM), and differential thermal analysis (DTA)/thermogravimetry (TG) analysis and surface area and porosity determination techniques. The organosulphur compounds (ORS) uptake was slightly affected by the particle size indicating that the removal of ORS mainly occurred on the external surface of the modified bentonite samples. The acid activation process enhanced the adsorptive efficiency of the bentonite sample through increasing both the surface area and the pore volume, in addition to the release of a considerable amount of interlayer cations of the clay. |
| Author | Sultan, Mohammed Robl, Christian Khalili, Fawwaz I. Al-Ghouti, Mohammad A. |
| Author_xml | – sequence: 1 givenname: Fawwaz I. surname: Khalili fullname: Khalili, Fawwaz I. organization: Department of Chemistry, The University of Jordan, Amman 11942, Jordan – sequence: 2 givenname: Mohammed surname: Sultan fullname: Sultan, Mohammed organization: Institut für Anorganische und Analytische Chemie, Friedrich-Schiller-Universität Jena, 07743 Jena, Germany – sequence: 3 givenname: Christian surname: Robl fullname: Robl, Christian organization: Institut für Anorganische und Analytische Chemie, Friedrich-Schiller-Universität Jena, 07743 Jena, Germany – sequence: 4 givenname: Mohammad A. surname: Al-Ghouti fullname: Al-Ghouti, Mohammad A. email: mohammad.alghouti@qu.edu.qa organization: Department of Biological and Environmental Sciences, Qatar University, P.O. Box 2713, Qatar |
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| CitedBy_id | crossref_primary_10_1016_j_clay_2016_05_001 crossref_primary_10_1039_D1RA01819A crossref_primary_10_1002_ente_201500475 crossref_primary_10_1002_ep_12539 |
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| Keywords | Bentonite Remediation Organosulphur compounds Diesel fuel Characteristics |
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| Snippet | •ORS uptake was marginally affected with the particle size.•ORS mainly uptakes on the external surface area of the adsorbents.•Acid activation process enhanced... In this work, physical and chemical characteristics of the raw, treated, and acid activated bentonite wereinvestigated using XRD, FTIR, scanning electron... |
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| SubjectTerms | Bentonite Characteristics Diesel fuel Organosulphur compounds Remediation 화학공학 |
| Title | Insights into the remediation characterization of modified bentonite in minimizing organosulphur compounds from diesel fuel |
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