Communication: X-ray scattering from ionic liquids with pyrrolidinium cations
We report the structure functions obtained from x-ray scattering experiments on a series of four homologous ionic liquids. The ionic liquids are 1-alkyl-1-methylpyrrolidinium cations paired with the bis(trifluoromethylsulfonyl)amide anion, with alkyl chain lengths of n = 4, 6, 8, and 10. The structu...
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| Vydáno v: | The Journal of chemical physics Ročník 134; číslo 12; s. 121101 |
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| Hlavní autoři: | , , , |
| Médium: | Journal Article |
| Jazyk: | angličtina |
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United States
28.03.2011
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| ISSN: | 1089-7690, 1089-7690 |
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| Abstract | We report the structure functions obtained from x-ray scattering experiments on a series of four homologous ionic liquids. The ionic liquids are 1-alkyl-1-methylpyrrolidinium cations paired with the bis(trifluoromethylsulfonyl)amide anion, with alkyl chain lengths of n = 4, 6, 8, and 10. The structure functions display two intense diffraction peaks for values of the scattering vector q in the range from 0.6 to 1.5 Å(-1) for all samples. Both diffraction peaks shift to lower values of q for increasing temperature. First sharp diffraction peaks are observed in the structure functions for q < 0.5 Å(-1) for liquids with n = 6, 8, and 10. |
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| AbstractList | We report the structure functions obtained from x-ray scattering experiments on a series of four homologous ionic liquids. The ionic liquids are 1-alkyl-1-methylpyrrolidinium cations paired with the bis(trifluoromethylsulfonyl)amide anion, with alkyl chain lengths of n = 4, 6, 8, and 10. The structure functions display two intense diffraction peaks for values of the scattering vector q in the range from 0.6 to 1.5 Å(-1) for all samples. Both diffraction peaks shift to lower values of q for increasing temperature. First sharp diffraction peaks are observed in the structure functions for q < 0.5 Å(-1) for liquids with n = 6, 8, and 10. We report the structure functions obtained from x-ray scattering experiments on a series of four homologous ionic liquids. The ionic liquids are 1-alkyl-1-methylpyrrolidinium cations paired with the bis(trifluoromethylsulfonyl)amide anion, with alkyl chain lengths of n = 4, 6, 8, and 10. The structure functions display two intense diffraction peaks for values of the scattering vector q in the range from 0.6 to 1.5 Å(-1) for all samples. Both diffraction peaks shift to lower values of q for increasing temperature. First sharp diffraction peaks are observed in the structure functions for q < 0.5 Å(-1) for liquids with n = 6, 8, and 10.We report the structure functions obtained from x-ray scattering experiments on a series of four homologous ionic liquids. The ionic liquids are 1-alkyl-1-methylpyrrolidinium cations paired with the bis(trifluoromethylsulfonyl)amide anion, with alkyl chain lengths of n = 4, 6, 8, and 10. The structure functions display two intense diffraction peaks for values of the scattering vector q in the range from 0.6 to 1.5 Å(-1) for all samples. Both diffraction peaks shift to lower values of q for increasing temperature. First sharp diffraction peaks are observed in the structure functions for q < 0.5 Å(-1) for liquids with n = 6, 8, and 10. |
| Author | Santos, Cherry S Murthy, N Sanjeeva Castner, Jr, Edward W Baker, Gary A |
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| SubjectTerms | Cations - chemistry Ionic Liquids - chemistry Pyrrolidines - chemistry Scattering, Radiation Temperature X-Ray Diffraction X-Rays |
| Title | Communication: X-ray scattering from ionic liquids with pyrrolidinium cations |
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