Molecular hybridization yields triazole bronchodilators for the treatment of COPD

[Display omitted] A 1,2,4-triazole motif was employed as a bioisostere for the ester commonly used in muscarinic antagonists, and subsequent integrative conjugation to a β2 agonist quinolinone furnished a new class of bifunctional MABAs for the treatment of COPD. Medicinal chemistry optimization usi...

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Veröffentlicht in:Bioorganic & medicinal chemistry letters Jg. 25; H. 22; S. 5121 - 5126
Hauptverfasser: Jones, Lyn H., Burrows, Jane, Feeder, Neil, Glossop, Paul, James, Kim, Jones, Rhys M., Kenyon, Amy S., Patel, Sheena, Roberts, Dannielle F., Selby, Matthew D., Strang, Ross S., Stuart, Emilio F., Trevethick, Michael A., Watson, Jessica, Wright, Karen N., Clarke, Nick
Format: Journal Article
Sprache:Englisch
Veröffentlicht: England Elsevier Ltd 15.11.2015
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ISSN:0960-894X, 1464-3405, 1464-3405
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Abstract [Display omitted] A 1,2,4-triazole motif was employed as a bioisostere for the ester commonly used in muscarinic antagonists, and subsequent integrative conjugation to a β2 agonist quinolinone furnished a new class of bifunctional MABAs for the treatment of COPD. Medicinal chemistry optimization using the principles of ‘inhalation by design’ furnished a clinical candidate with desirable pharmacological, pharmacokinetic and biopharmaceutical properties.
AbstractList A 1,2,4-triazole motif was employed as a bioisostere for the ester commonly used in muscarinic antagonists, and subsequent integrative conjugation to a β2 agonist quinolinone furnished a new class of bifunctional MABAs for the treatment of COPD. Medicinal chemistry optimization using the principles of 'inhalation by design' furnished a clinical candidate with desirable pharmacological, pharmacokinetic and biopharmaceutical properties.
A 1,2,4-triazole motif was employed as a bioisostere for the ester commonly used in muscarinic antagonists, and subsequent integrative conjugation to a β2 agonist quinolinone furnished a new class of bifunctional MABAs for the treatment of COPD. Medicinal chemistry optimization using the principles of 'inhalation by design' furnished a clinical candidate with desirable pharmacological, pharmacokinetic and biopharmaceutical properties.A 1,2,4-triazole motif was employed as a bioisostere for the ester commonly used in muscarinic antagonists, and subsequent integrative conjugation to a β2 agonist quinolinone furnished a new class of bifunctional MABAs for the treatment of COPD. Medicinal chemistry optimization using the principles of 'inhalation by design' furnished a clinical candidate with desirable pharmacological, pharmacokinetic and biopharmaceutical properties.
[Display omitted] A 1,2,4-triazole motif was employed as a bioisostere for the ester commonly used in muscarinic antagonists, and subsequent integrative conjugation to a β2 agonist quinolinone furnished a new class of bifunctional MABAs for the treatment of COPD. Medicinal chemistry optimization using the principles of ‘inhalation by design’ furnished a clinical candidate with desirable pharmacological, pharmacokinetic and biopharmaceutical properties.
Author James, Kim
Stuart, Emilio F.
Feeder, Neil
Patel, Sheena
Watson, Jessica
Roberts, Dannielle F.
Selby, Matthew D.
Glossop, Paul
Kenyon, Amy S.
Jones, Rhys M.
Strang, Ross S.
Jones, Lyn H.
Wright, Karen N.
Clarke, Nick
Trevethick, Michael A.
Burrows, Jane
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Keywords MABA
Bifunctional
Inhalation by design
Bronchodilator
COPD
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Snippet [Display omitted] A 1,2,4-triazole motif was employed as a bioisostere for the ester commonly used in muscarinic antagonists, and subsequent integrative...
A 1,2,4-triazole motif was employed as a bioisostere for the ester commonly used in muscarinic antagonists, and subsequent integrative conjugation to a β2...
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SubjectTerms Adrenergic beta-2 Receptor Agonists - chemical synthesis
Adrenergic beta-2 Receptor Agonists - pharmacokinetics
Adrenergic beta-2 Receptor Agonists - pharmacology
Animals
Bifunctional
Biological Availability
Bronchoconstriction - drug effects
Bronchodilator
Bronchodilator Agents - chemical synthesis
Bronchodilator Agents - pharmacokinetics
Bronchodilator Agents - pharmacology
CHO Cells
COPD
Cricetulus
Dogs
Humans
Inhalation by design
Ipratropium - pharmacology
MABA
Muscarinic Antagonists - chemical synthesis
Muscarinic Antagonists - pharmacokinetics
Muscarinic Antagonists - pharmacology
Pulmonary Disease, Chronic Obstructive - drug therapy
Rats
Receptor, Muscarinic M3 - antagonists & inhibitors
Salmeterol Xinafoate - pharmacology
Tiotropium Bromide - pharmacology
Triazoles - chemical synthesis
Triazoles - pharmacokinetics
Triazoles - pharmacology
Title Molecular hybridization yields triazole bronchodilators for the treatment of COPD
URI https://dx.doi.org/10.1016/j.bmcl.2015.10.008
https://www.ncbi.nlm.nih.gov/pubmed/26471092
https://www.proquest.com/docview/1728667839
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