Effect of zinc stearate on the rheology of ionic elastomer based on carboxylated nitrile rubber
Monsanto rheometry, melt viscometry, differential scanning calorimetry, and dynamic mechanical spectroscopy have been used to study the effects of zinc stearate on the rheological behavior of ionomer based on carboxylated nitrile rubber (XNBR) ‐ zinc oxide (ZnO) system. At temperatures below its mel...
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| Vydané v: | Polymer engineering and science Ročník 36; číslo 2; s. 283 - 287 |
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| Médium: | Journal Article |
| Jazyk: | English |
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01.01.1996
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| Abstract | Monsanto rheometry, melt viscometry, differential scanning calorimetry, and dynamic mechanical spectroscopy have been used to study the effects of zinc stearate on the rheological behavior of ionomer based on carboxylated nitrile rubber (XNBR) ‐ zinc oxide (ZnO) system. At temperatures below its melting point, zinc stearate functions as a reinforcing agent for ionomer formation. Above its melting point, it acts as a plasticizer for the ionic domains, thereby facilitating easy processing of the ionomer. |
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| AbstractList | Monsanto rheometry, melt viscometry, differential scanning calorimetry, and dynamic mechanical spectroscopy have been used to study the effects of zinc stearate on the rheological behavior of ionomer based on carboxylated nitrile rubber (XNBR) ‐ zinc oxide (ZnO) system. At temperatures below its melting point, zinc stearate functions as a reinforcing agent for ionomer formation. Above its melting point, it acts as a plasticizer for the ionic domains, thereby facilitating easy processing of the ionomer. |
| Author | Mandal, U. K. De, S. K. Tripathy, D. K. |
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| Cites_doi | 10.1021/ba-1980-0187.ch005 10.1021/ma00220a012 10.1021/ba-1980-0187.ch003 10.5254/1.3536023 10.1002/app.1995.070550805 10.1021/i300002a010 10.1021/ma60078a057 10.1002/app.1992.070440918 10.5254/1.3539642 10.1002/pol.1981.230160102 10.1016/0032-3861(83)90159-3 10.1016/0032-3861(93)90507-7 10.1002/pen.760220808 |
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| Keywords | Additive Nitrile rubber Transition metal Compounds Apparent viscosity Elastomer Rheological properties |
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| References | U. K. Mandal, D. K. Tripathy, and S. K. De, J. Appl. Polym. Sci. 55, 1185 (1995). S. K. Chakraborty and S. K. De, Polymer, 24, 1055 (1983). A. I. Medalia, Rubber Chem. Technol., 51, 4379 (1978). A. R. Payne, in Reinforcement of Elastomers G. Kraus, ed., Interscience, New York (1965). R. D. Lundberg, H. S. Makowski, and L. Wasterman, Am. Chem. Soc., Adv. Chem. Ser., 187, 67 (1980). N. K. Dutta and D. K. Tripathy, J. Appl. Polym. Sci., 44, 1635 (1992). A. Eisenberg and M. King, Ion Containing Polymers, pp. 25-55, Academic Press, New York (1977). H. P. Brown, Rubber Chem. Technol., 36, 931 (1963). W. J. MacKnight and T. R. Earnest, Jr., J. Polym. Sci., Macromol. Rev., 16, 41 (1981). H. S. Makowski and R. D. Lundberg, Am. Chem. Soc., Adv. Chem. Ser., 187, 37 (1980). T. Duvdevani, P. K. Agarwal, and R. D. Lundberg, Polym. Eng. Sci., 22, 499 (1982). H. S. Makowski and R. D. Lundberg, Paper No. 3 in Ion in Polymers, A. Eisenberg, ed., Advances in Chemistry Series No. 187, American Chemical Society, Washington, D.C. (1980). U. K. Mandal, D. K. Tripathy, and S. K. De, Polymer, 34, 3832 (1993). A. Eisenberg, B. Hird, and R. B. Moore, Macromolecules, 23, 4098 (1990). L. Holliday, Ed., Ionic Polymers, pp. 93-104, Applied Science Publishers, London (1975). P. K. Agarwal, H. S. Makowski, and R. D. Lundberg, Macromolecules, 13, 1679 (1980). C. G. Bazuin and A. Eisenberg, Ind. Eng. Chem. Prod. Res. Dev., 20, 271 (1981). W. J. MacKnight and R. D. Lundberg, Rubber Chem. Technol., 57, 652 (1984). 1963; 36 1993; 34 1990; 23 1980; 13 1978; 51 1995; 55 1984; 57 1982; 22 1965 1975 1981; 16 1980 1992; 44 1980; 187 1983; 24 1981; 20 1977 Medalia A. I. (e_1_2_1_17_2) 1978; 51 Eisenberg A. (e_1_2_1_3_2) 1977 Makowski H. S. (e_1_2_1_10_2) 1980 Payne A. R. (e_1_2_1_16_2) 1965 Holliday L. (e_1_2_1_2_2) 1975 e_1_2_1_6_2 e_1_2_1_7_2 e_1_2_1_4_2 e_1_2_1_5_2 e_1_2_1_11_2 e_1_2_1_12_2 e_1_2_1_15_2 e_1_2_1_13_2 e_1_2_1_14_2 e_1_2_1_19_2 e_1_2_1_8_2 e_1_2_1_9_2 e_1_2_1_18_2 |
| References_xml | – reference: U. K. Mandal, D. K. Tripathy, and S. K. De, Polymer, 34, 3832 (1993). – reference: H. S. Makowski and R. D. Lundberg, Am. Chem. Soc., Adv. Chem. Ser., 187, 37 (1980). – reference: A. Eisenberg, B. Hird, and R. B. Moore, Macromolecules, 23, 4098 (1990). – reference: W. J. MacKnight and R. D. Lundberg, Rubber Chem. Technol., 57, 652 (1984). – reference: A. R. Payne, in Reinforcement of Elastomers G. Kraus, ed., Interscience, New York (1965). – reference: R. D. Lundberg, H. S. Makowski, and L. Wasterman, Am. Chem. Soc., Adv. Chem. Ser., 187, 67 (1980). – reference: S. K. Chakraborty and S. K. De, Polymer, 24, 1055 (1983). – reference: U. K. Mandal, D. K. Tripathy, and S. K. De, J. Appl. Polym. Sci. 55, 1185 (1995). – reference: A. Eisenberg and M. King, Ion Containing Polymers, pp. 25-55, Academic Press, New York (1977). – reference: P. K. Agarwal, H. S. Makowski, and R. D. Lundberg, Macromolecules, 13, 1679 (1980). – reference: T. Duvdevani, P. K. Agarwal, and R. D. Lundberg, Polym. Eng. Sci., 22, 499 (1982). – reference: H. P. Brown, Rubber Chem. Technol., 36, 931 (1963). – reference: C. G. Bazuin and A. Eisenberg, Ind. Eng. Chem. Prod. Res. Dev., 20, 271 (1981). – reference: A. I. Medalia, Rubber Chem. Technol., 51, 4379 (1978). – reference: W. J. MacKnight and T. R. Earnest, Jr., J. Polym. Sci., Macromol. Rev., 16, 41 (1981). – reference: H. S. Makowski and R. D. Lundberg, Paper No. 3 in Ion in Polymers, A. Eisenberg, ed., Advances in Chemistry Series No. 187, American Chemical Society, Washington, D.C. (1980). – reference: N. K. Dutta and D. K. Tripathy, J. Appl. Polym. Sci., 44, 1635 (1992). – reference: L. Holliday, Ed., Ionic Polymers, pp. 93-104, Applied Science Publishers, London (1975). – volume: 22 start-page: 499 year: 1982 publication-title: Polym. Eng. Sci. – volume: 44 start-page: 1635 year: 1992 publication-title: J. Appl. Polym. Sci. – volume: 187 start-page: 37 year: 1980 publication-title: Am. Chem. Soc., Adv. Chem. Ser. – volume: 16 start-page: 41 year: 1981 publication-title: J. Polym. Sci., Macromol. Rev. – volume: 20 start-page: 271 year: 1981 publication-title: Ind. Eng. Chem. Prod. Res. Dev. – volume: 51 start-page: 4379 year: 1978 publication-title: Rubber Chem. Technol. – year: 1980 – start-page: 25 year: 1977 end-page: 55 – volume: 57 start-page: 652 year: 1984 publication-title: Rubber Chem. Technol. – year: 1965 – volume: 24 start-page: 1055 year: 1983 publication-title: Polymer – volume: 55 start-page: 1185 year: 1995 publication-title: J. Appl. Polym. Sci. – volume: 187 start-page: 67 year: 1980 publication-title: Am. Chem. Soc., Adv. Chem. Ser. – volume: 13 start-page: 1679 year: 1980 publication-title: Macromolecules – start-page: 93 year: 1975 end-page: 104 – volume: 34 start-page: 3832 year: 1993 publication-title: Polymer – volume: 23 start-page: 4098 year: 1990 publication-title: Macromolecules – volume: 36 start-page: 931 year: 1963 publication-title: Rubber Chem. Technol. – ident: e_1_2_1_7_2 doi: 10.1021/ba-1980-0187.ch005 – ident: e_1_2_1_19_2 doi: 10.1021/ma00220a012 – volume: 51 start-page: 4379 year: 1978 ident: e_1_2_1_17_2 publication-title: Rubber Chem. Technol. – ident: e_1_2_1_8_2 doi: 10.1021/ba-1980-0187.ch003 – start-page: 93 volume-title: Ionic Polymers year: 1975 ident: e_1_2_1_2_2 – start-page: 25 volume-title: Ion Containing Polymers year: 1977 ident: e_1_2_1_3_2 – ident: e_1_2_1_6_2 doi: 10.5254/1.3536023 – volume-title: Reinforcement of Elastomers year: 1965 ident: e_1_2_1_16_2 – ident: e_1_2_1_15_2 doi: 10.1002/app.1995.070550805 – ident: e_1_2_1_5_2 doi: 10.1021/i300002a010 – ident: e_1_2_1_9_2 doi: 10.1021/ma60078a057 – ident: e_1_2_1_18_2 doi: 10.1002/app.1992.070440918 – ident: e_1_2_1_12_2 doi: 10.5254/1.3539642 – ident: e_1_2_1_4_2 doi: 10.1002/pol.1981.230160102 – ident: e_1_2_1_13_2 doi: 10.1016/0032-3861(83)90159-3 – ident: e_1_2_1_14_2 doi: 10.1016/0032-3861(93)90507-7 – ident: e_1_2_1_11_2 doi: 10.1002/pen.760220808 – volume-title: Ion in Polymers year: 1980 ident: e_1_2_1_10_2 |
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| SubjectTerms | Applied sciences Exact sciences and technology Physical properties Polymer industry, paints, wood Properties and testing Rheological properties Technology of polymers |
| Title | Effect of zinc stearate on the rheology of ionic elastomer based on carboxylated nitrile rubber |
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