Rheological behavior of high methoxyl pectin from the pulp of tamarillo fruit (Solanum betaceum)

•Rheological behavior of a high methoxyl pectin from tamarillo pulp was studied.•STW-A dispersed in water (3–8% w/w) showed liquid-like behavior.•STW-A (2–3%), at pH 3 and with 50% sucrose showed shear-thinning flow and gel-like behaviors.•STW-A in the presence of sucrose did not follow the Cox and...

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Published in:Carbohydrate polymers Vol. 139; pp. 125 - 130
Main Authors: Nascimento, Georgia Erdmann do, Simas-Tosin, Fernanda F., Iacomini, Marcello, Gorin, Philip Albert James, Cordeiro, Lucimara M.C.
Format: Journal Article
Language:English
Published: England Elsevier Ltd 30.03.2016
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ISSN:0144-8617, 1879-1344
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Abstract •Rheological behavior of a high methoxyl pectin from tamarillo pulp was studied.•STW-A dispersed in water (3–8% w/w) showed liquid-like behavior.•STW-A (2–3%), at pH 3 and with 50% sucrose showed shear-thinning flow and gel-like behaviors.•STW-A in the presence of sucrose did not follow the Cox and Merz rule.•STW-A (at 2 and 3%) with sucrose formed thermostable gels (at 5–80°C and 80–5°C). Rheological behavior of a high methyl-esterified pectic fraction (STW-A) from tamarillo was evaluated at different concentrations in water and with sucrose (50% w/w, pH 3). STW-A dispersions at 3, 5, and 8% (w/w) showed low apparent viscosities, shear-thinning and liquid-like behaviors. They were well fitted using the Ostwald–de Waele model and obey the Cox–Merz rule. The viscosity and the viscoelastic behavior were greatly modified by the presence of sucrose. STW-A at 1% (+ sucrose) showed shear-thinning and concentrated solution behavior. Pronounced shear-thinning and gel-like behaviors were obtained with STW-A at 2 and 3% (+ sucrose). Their flow curves profiles were better fitted using the Hershel–Bulkley model and not followed the Cox and Merz rule. Temperature sweeps (5–80°C) showed that STW-A formed thermostable gels. Altogether, our results suggested tamarillo can be a new source of pectin with potential applications as thickeners/gelling agents depending on solvent or applied processes.
AbstractList Rheological behavior of a high methyl-esterified pectic fraction (STW-A) from tamarillo was evaluated at different concentrations in water and with sucrose (50% w/w, pH 3). STW-A dispersions at 3, 5, and 8% (w/w) showed low apparent viscosities, shear-thinning and liquid-like behaviors. They were well fitted using the Ostwald-de Waele model and obey the Cox-Merz rule. The viscosity and the viscoelastic behavior were greatly modified by the presence of sucrose. STW-A at 1% (+ sucrose) showed shear-thinning and concentrated solution behavior. Pronounced shear-thinning and gel-like behaviors were obtained with STW-A at 2 and 3% (+ sucrose). Their flow curves profiles were better fitted using the Hershel-Bulkley model and not followed the Cox and Merz rule. Temperature sweeps (5-80°C) showed that STW-A formed thermostable gels. Altogether, our results suggested tamarillo can be a new source of pectin with potential applications as thickeners/gelling agents depending on solvent or applied processes.
•Rheological behavior of a high methoxyl pectin from tamarillo pulp was studied.•STW-A dispersed in water (3–8% w/w) showed liquid-like behavior.•STW-A (2–3%), at pH 3 and with 50% sucrose showed shear-thinning flow and gel-like behaviors.•STW-A in the presence of sucrose did not follow the Cox and Merz rule.•STW-A (at 2 and 3%) with sucrose formed thermostable gels (at 5–80°C and 80–5°C). Rheological behavior of a high methyl-esterified pectic fraction (STW-A) from tamarillo was evaluated at different concentrations in water and with sucrose (50% w/w, pH 3). STW-A dispersions at 3, 5, and 8% (w/w) showed low apparent viscosities, shear-thinning and liquid-like behaviors. They were well fitted using the Ostwald–de Waele model and obey the Cox–Merz rule. The viscosity and the viscoelastic behavior were greatly modified by the presence of sucrose. STW-A at 1% (+ sucrose) showed shear-thinning and concentrated solution behavior. Pronounced shear-thinning and gel-like behaviors were obtained with STW-A at 2 and 3% (+ sucrose). Their flow curves profiles were better fitted using the Hershel–Bulkley model and not followed the Cox and Merz rule. Temperature sweeps (5–80°C) showed that STW-A formed thermostable gels. Altogether, our results suggested tamarillo can be a new source of pectin with potential applications as thickeners/gelling agents depending on solvent or applied processes.
Author Nascimento, Georgia Erdmann do
Cordeiro, Lucimara M.C.
Simas-Tosin, Fernanda F.
Gorin, Philip Albert James
Iacomini, Marcello
Author_xml – sequence: 1
  givenname: Georgia Erdmann do
  surname: Nascimento
  fullname: Nascimento, Georgia Erdmann do
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  givenname: Fernanda F.
  surname: Simas-Tosin
  fullname: Simas-Tosin, Fernanda F.
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  givenname: Marcello
  surname: Iacomini
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  givenname: Philip Albert James
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  fullname: Gorin, Philip Albert James
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  givenname: Lucimara M.C.
  surname: Cordeiro
  fullname: Cordeiro, Lucimara M.C.
  email: lucimaramcc@ufpr.br
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Keywords Pectin
Tamarillo
Rheology
Solanum betaceum
Gel
Language English
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Snippet •Rheological behavior of a high methoxyl pectin from tamarillo pulp was studied.•STW-A dispersed in water (3–8% w/w) showed liquid-like behavior.•STW-A (2–3%),...
Rheological behavior of a high methyl-esterified pectic fraction (STW-A) from tamarillo was evaluated at different concentrations in water and with sucrose...
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elsevier
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StartPage 125
SubjectTerms dispersions
Elasticity
Fruit - chemistry
Gel
gelling agents
gels
Models, Theoretical
Pectin
pectins
Pectins - chemistry
pulp
Rheology
Solanum
Solanum betaceum
solvents
sucrose
Sucrose - chemistry
Tamarillo
temperature
thermal stability
thickeners
viscoelasticity
Viscosity
Title Rheological behavior of high methoxyl pectin from the pulp of tamarillo fruit (Solanum betaceum)
URI https://dx.doi.org/10.1016/j.carbpol.2015.11.067
https://www.ncbi.nlm.nih.gov/pubmed/26794955
https://www.proquest.com/docview/1760921772
https://www.proquest.com/docview/2000238989
Volume 139
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