Thermally-induced hysteretic valence tautomeric conversions in the solid state via two-step labile electron transfers in manganese-nitronyl nitroxide 2D-frameworks

Near room temperature hysteretic thermo-induced valence tautomerism was discovered in a layered 2D-coordination polymer of manganese(ii) with nitronyl nitroxide radicals separated by ClO4- anions (1). This opens a novel approach towards switchable materials with hysteresis and under ambient conditio...

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Bibliographic Details

Published in:	Dalton transactions : an international journal of inorganic chemistry Vol. 49; no. 44; p. 15646
Main Authors:	Lecourt, Constance, Izumi, Yuuta, Khrouz, Lhoussain, Toche, François, Chiriac, Rodica, Bélanger-Desmarais, Nicolas, Reber, Christian, Fabelo, Oscar, Inoue, Katsuya, Desroches, Cédric, Luneau, Dominique
Format:	Journal Article
Language:	English
Published:	01.01.2020
ISSN:	1477-9234, 1477-9234
Online Access:	Get more information
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