Syntheses and Crystal Structures of Two Cadmium Methanetetrabenzoates Featured by Open Framework and Infinite Layers

Colorless single crystals of Cd2[μ8‐MTB]·3H2O·DMF (1) were prepared in DMF/H2O solution [1: space group C2/c (no. 15) with a = 1821.30(6), b = 2175.08(6), c = 1269.87(4) pm, β = 129.684(1)°]. The connection between the methane‐p‐benzoate tetraanions (MTB4–) and the Cd2+ cations leads to a three‐dime...

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Bibliographic Details
Published in:	Zeitschrift für anorganische und allgemeine Chemie (1950) Vol. 645; no. 14; pp. 912 - 918
Main Authors:	Harms, Sven, Köferstein, Roberto, Görls, Helmar, Robl, Christian
Format:	Journal Article
Language:	English
Published:	Weinheim Wiley Subscription Services, Inc 31.07.2019 Wiley-VCH Verlag
Subjects:	Benzoates Cadmium Chemical Sciences Coordination chemistry Coordination polymer Crystal structure Hydrogen bonds Inorganic chemistry Metal‐organic framework (MOF) Methanetetra‐p‐benzoic acid Single crystals Water chemistry metal organic framework methanetetra-p-benzoates single crystal cadmium porous benzoate building blocks Coordination compounds voids coordination polymer
ISSN:	0044-2313, 1521-3749
Online Access:	Get full text
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