Photomediated controlled radical polymerization
Photomediated controlled radical polymerization is a versatile method to prepare, under mild conditions, various well-defined polymers with complex architecture, such as block and graft copolymers, sequence-controlled polymers, or hybrid materials via surface-initiated polymerization. It also provid...
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| Vydáno v: | Progress in polymer science Ročník 62; s. 73 - 125 |
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| Hlavní autoři: | , , , , , |
| Médium: | Journal Article |
| Jazyk: | angličtina |
| Vydáno: |
Elsevier Ltd
01.11.2016
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| Témata: | |
| ISSN: | 0079-6700, 1873-1619 |
| On-line přístup: | Získat plný text |
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| Abstract | Photomediated controlled radical polymerization is a versatile method to prepare, under mild conditions, various well-defined polymers with complex architecture, such as block and graft copolymers, sequence-controlled polymers, or hybrid materials via surface-initiated polymerization. It also provides opportunity to manipulate the reaction through spatiotemporal control. This review presents a comprehensive account of the fundamentals and applications of various photomediated CRP techniques, including atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT), nitroxide mediated polymerization (NMP) and other procedures. In addition, mechanistic aspects of other photomediated methods are discussed. |
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| AbstractList | Photomediated controlled radical polymerization is a versatile method to prepare, under mild conditions, various well-defined polymers with complex architecture, such as block and graft copolymers, sequence-controlled polymers, or hybrid materials via surface-initiated polymerization. It also provides opportunity to manipulate the reaction through spatiotemporal control. This review presents a comprehensive account of the fundamentals and applications of various photomediated CRP techniques, including atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT), nitroxide mediated polymerization (NMP) and other procedures. In addition, mechanistic aspects of other photomediated methods are discussed. |
| Author | Matyjaszewski, Krzysztof Junkers, Tanja Pan, Xiangcheng Laun, Joachim Yagci, Yusuf Tasdelen, Mehmet Atilla |
| Author_xml | – sequence: 1 givenname: Xiangcheng surname: Pan fullname: Pan, Xiangcheng organization: Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213, United States – sequence: 2 givenname: Mehmet Atilla surname: Tasdelen fullname: Tasdelen, Mehmet Atilla organization: Department of Polymer Engineering, Faculty of Engineering, Yalova University, 77100 Yalova, Turkey – sequence: 3 givenname: Joachim surname: Laun fullname: Laun, Joachim organization: Polymer Reaction Design Group, Institute for Materials Research (IMO), Universiteit Hasselt, Martelarenlaan 42, 3500 Hasselt, Belgium – sequence: 4 givenname: Tanja surname: Junkers fullname: Junkers, Tanja email: junkers@polymatter.net organization: Polymer Reaction Design Group, Institute for Materials Research (IMO), Universiteit Hasselt, Martelarenlaan 42, 3500 Hasselt, Belgium – sequence: 5 givenname: Yusuf surname: Yagci fullname: Yagci, Yusuf email: yusuf@itu.edu.tr organization: Department of Chemistry, Istanbul Technical University, 34469 Maslak, Istanbul, Turkey – sequence: 6 givenname: Krzysztof surname: Matyjaszewski fullname: Matyjaszewski, Krzysztof email: km3b@andrew.cmu.edu organization: Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213, United States |
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