Photomediated controlled radical polymerization

Photomediated controlled radical polymerization is a versatile method to prepare, under mild conditions, various well-defined polymers with complex architecture, such as block and graft copolymers, sequence-controlled polymers, or hybrid materials via surface-initiated polymerization. It also provid...

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Vydané v:Progress in polymer science Ročník 62; s. 73 - 125
Hlavní autori: Pan, Xiangcheng, Tasdelen, Mehmet Atilla, Laun, Joachim, Junkers, Tanja, Yagci, Yusuf, Matyjaszewski, Krzysztof
Médium: Journal Article
Jazyk:English
Vydavateľské údaje: Elsevier Ltd 01.11.2016
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ISSN:0079-6700, 1873-1619
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Abstract Photomediated controlled radical polymerization is a versatile method to prepare, under mild conditions, various well-defined polymers with complex architecture, such as block and graft copolymers, sequence-controlled polymers, or hybrid materials via surface-initiated polymerization. It also provides opportunity to manipulate the reaction through spatiotemporal control. This review presents a comprehensive account of the fundamentals and applications of various photomediated CRP techniques, including atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT), nitroxide mediated polymerization (NMP) and other procedures. In addition, mechanistic aspects of other photomediated methods are discussed.
AbstractList Photomediated controlled radical polymerization is a versatile method to prepare, under mild conditions, various well-defined polymers with complex architecture, such as block and graft copolymers, sequence-controlled polymers, or hybrid materials via surface-initiated polymerization. It also provides opportunity to manipulate the reaction through spatiotemporal control. This review presents a comprehensive account of the fundamentals and applications of various photomediated CRP techniques, including atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT), nitroxide mediated polymerization (NMP) and other procedures. In addition, mechanistic aspects of other photomediated methods are discussed.
Author Matyjaszewski, Krzysztof
Junkers, Tanja
Pan, Xiangcheng
Laun, Joachim
Yagci, Yusuf
Tasdelen, Mehmet Atilla
Author_xml – sequence: 1
  givenname: Xiangcheng
  surname: Pan
  fullname: Pan, Xiangcheng
  organization: Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213, United States
– sequence: 2
  givenname: Mehmet Atilla
  surname: Tasdelen
  fullname: Tasdelen, Mehmet Atilla
  organization: Department of Polymer Engineering, Faculty of Engineering, Yalova University, 77100 Yalova, Turkey
– sequence: 3
  givenname: Joachim
  surname: Laun
  fullname: Laun, Joachim
  organization: Polymer Reaction Design Group, Institute for Materials Research (IMO), Universiteit Hasselt, Martelarenlaan 42, 3500 Hasselt, Belgium
– sequence: 4
  givenname: Tanja
  surname: Junkers
  fullname: Junkers, Tanja
  email: junkers@polymatter.net
  organization: Polymer Reaction Design Group, Institute for Materials Research (IMO), Universiteit Hasselt, Martelarenlaan 42, 3500 Hasselt, Belgium
– sequence: 5
  givenname: Yusuf
  surname: Yagci
  fullname: Yagci, Yusuf
  email: yusuf@itu.edu.tr
  organization: Department of Chemistry, Istanbul Technical University, 34469 Maslak, Istanbul, Turkey
– sequence: 6
  givenname: Krzysztof
  surname: Matyjaszewski
  fullname: Matyjaszewski, Krzysztof
  email: km3b@andrew.cmu.edu
  organization: Department of Chemistry, Carnegie Mellon University, Pittsburgh, PA 15213, United States
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Radical polymerization
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Snippet Photomediated controlled radical polymerization is a versatile method to prepare, under mild conditions, various well-defined polymers with complex...
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StartPage 73
SubjectTerms ATRP
NMP
Photopolymerization
Radical polymerization
RAFT
Title Photomediated controlled radical polymerization
URI https://dx.doi.org/10.1016/j.progpolymsci.2016.06.005
Volume 62
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