A zirconium squarate metal-organic framework with modulator-dependent molecular sieving properties

We report the first zirconium metal-organic framework based on squaric acid, representing the member with the smallest unit cell in the isoreticular UiO-66 family. Its molecular sieving properties are strongly influenced by the monocarboxylic acid modulator incorporated during synthesis.

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Vydáno v:Chemical communications (Cambridge, England) Ročník 50; číslo 70; s. 10055
Hlavní autoři: Bueken, Bart, Reinsch, Helge, Reimer, Nele, Stassen, Ivo, Vermoortele, Frederik, Ameloot, Rob, Stock, Norbert, Kirschhock, Christine E A, De Vos, Dirk
Médium: Journal Article
Jazyk:angličtina
Vydáno: England 11.09.2014
ISSN:1364-548X, 1364-548X
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Shrnutí:We report the first zirconium metal-organic framework based on squaric acid, representing the member with the smallest unit cell in the isoreticular UiO-66 family. Its molecular sieving properties are strongly influenced by the monocarboxylic acid modulator incorporated during synthesis.
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ISSN:1364-548X
1364-548X
DOI:10.1039/c4cc03764b