Mixed occupancy: the crystal structure of scheelite-type LiLu[MoO 4 ] 2
Coarse colorless single crystals of lithium lutetium bis[orthomolybdate(VI)], LiLu[MoO 4 ] 2 , were obtained as a by-product from a reaction aimed at lithium derivatives of lutetium molybdate. The title compound crystallizes in the scheelite structure type (tetragonal, space group I 4 1 / a ) with t...
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| Published in: | Acta crystallographica. Section E, Crystallographic communications Vol. 80; no. 6; pp. 607 - 609 |
|---|---|
| Main Authors: | , |
| Format: | Journal Article |
| Language: | English |
| Published: |
England
International Union of Crystallography
01.06.2024
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| Subjects: | |
| ISSN: | 2056-9890, 2056-9890 |
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| Abstract | Coarse colorless single crystals of lithium lutetium bis[orthomolybdate(VI)], LiLu[MoO
4
]
2
, were obtained as a by-product from a reaction aimed at lithium derivatives of lutetium molybdate. The title compound crystallizes in the scheelite structure type (tetragonal, space group
I
4
1
/
a
) with two formula units per unit cell. The Wyckoff position 4
b
(site symmetry \overline{4}) comprises a mixed occupancy of Li
+
and Lu
3+
cations in a 1:1 ratio. In comparison with a previous powder X-ray study [Cheng
et al.
(2015).
Dalton Trans.
44
, 18078–18089.] all atoms were refined with anisotropic displacement parameters. |
|---|---|
| AbstractList | The crystal structure of LiLu[MoO4]2, which emerged as a by-product of the synthesis to obtain lithium derivatives of lutetium molybdate, adopts the scheelite type. Coarse colorless single crystals of lithium lutetium bis[orthomolybdate(VI)], LiLu[MoO4]2, were obtained as a by-product from a reaction aimed at lithium derivatives of lutetium molybdate. The title compound crystallizes in the scheelite structure type (tetragonal, space group I41/a) with two formula units per unit cell. The Wyckoff position 4b (site symmetry
) comprises a mixed occupancy of Li+ and Lu3+ cations in a 1:1 ratio. In comparison with a previous powder X-ray study [Cheng et al. (2015 ▸). Dalton Trans.
44, 18078–18089.] all atoms were refined with anisotropic displacement parameters. Coarse colorless single crystals of lithium lutetium bis[orthomolybdate(VI)], LiLu[MoO4]2, were obtained as a by-product from a reaction aimed at lithium derivatives of lutetium molybdate. The title compound crystallizes in the scheelite structure type (tetragonal, space group I41/a) with two formula units per unit cell. The Wyckoff position 4b (site symmetry \overline{4}) comprises a mixed occupancy of Li+ and Lu3+ cations in a 1:1 ratio. In comparison with a previous powder X-ray study [Cheng et al. (2015). Dalton Trans. 44, 18078–18089.] all atoms were refined with anisotropic displacement parameters. Coarse colorless single crystals of lithium lutetium bis[orthomolybdate(VI)], LiLu[MoO 4 ] 2 , were obtained as a by-product from a reaction aimed at lithium derivatives of lutetium molybdate. The title compound crystallizes in the scheelite structure type (tetragonal, space group I 4 1 / a ) with two formula units per unit cell. The Wyckoff position 4 b (site symmetry \overline{4}) comprises a mixed occupancy of Li + and Lu 3+ cations in a 1:1 ratio. In comparison with a previous powder X-ray study [Cheng et al. (2015). Dalton Trans. 44 , 18078–18089.] all atoms were refined with anisotropic displacement parameters. Coarse colorless single crystals of lithium lutetium bis-[orthomolybdate(VI)], LiLu[MoO ] , were obtained as a by-product from a reaction aimed at lithium derivatives of lutetium molybdate. The title compound crystallizes in the scheelite structure type (tetra-gonal, space group 4 / ) with two formula units per unit cell. The Wyckoff position 4 (site symmetry ) comprises a mixed occupancy of Li and Lu cations in a 1:1 ratio. In comparison with a previous powder X-ray study [Cheng (2015 ▸). , 18078-18089.] all atoms were refined with anisotropic displacement parameters. |
| Author | Hertweck, Robin F. Hartenbach, Ingo |
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| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/38845709$$D View this record in MEDLINE/PubMed |
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| Cites_doi | 10.1515/acs-2016-0023 10.1039/C5DT02760H 10.1016/j.jallcom.2021.159147 10.1002/zaac.201700305 10.1021/cm049095k 10.1107/S2053273314026370 10.1016/j.jallcom.2021.161074 10.1107/S0021889810022120 10.1021/ja01446a012 10.1107/S2053229614024218 10.1524/zkri.216.8.449.20358 |
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| Issue | 6 |
| Keywords | crystal structure lutetium lithium mixed occupancy scheelite molybdates |
| Language | English |
| License | Hartenbach and Hertweck 2024. This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
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| References_xml | – volume: 9 start-page: 136 year: 2016 ident: wm5719_bb10 publication-title: Acta Chim. Slovaca doi: 10.1515/acs-2016-0023 – volume: 44 start-page: 18078 year: 2015 ident: wm5719_bb3 publication-title: Dalton Trans. doi: 10.1039/C5DT02760H – volume: 868 start-page: 159147 year: 2021 ident: wm5719_bb6 publication-title: J. Alloys Compd. doi: 10.1016/j.jallcom.2021.159147 – volume: 643 start-page: 2050 year: 2017 ident: wm5719_bb7 publication-title: Z. Anorg. Allg. Chem. doi: 10.1002/zaac.201700305 – volume: 17 start-page: 291 year: 2005 ident: wm5719_bb14 publication-title: Chem. Mater. doi: 10.1021/cm049095k – volume: 71 start-page: 3 year: 2015 ident: wm5719_bb11 publication-title: Acta Cryst. A doi: 10.1107/S2053273314026370 – volume: 884 start-page: 161074 year: 2021 ident: wm5719_bb1 publication-title: J. Alloys Compd. doi: 10.1016/j.jallcom.2021.161074 – volume: 43 start-page: 920 year: 2010 ident: wm5719_bb15 publication-title: J. Appl. Cryst. doi: 10.1107/S0021889810022120 – volume: 42 start-page: 85 year: 1920 ident: wm5719_bb5 publication-title: J. Am. Chem. Soc. doi: 10.1021/ja01446a012 – volume: 71 start-page: 3 year: 2015 ident: wm5719_bb12 publication-title: Acta Cryst. C doi: 10.1107/S2053229614024218 – ident: wm5719_bb4 – ident: wm5719_bb2 – volume: 18 start-page: 2036 year: 1982 ident: wm5719_bb8 publication-title: Neorg. Mater. – volume: 216 start-page: 449 year: 2001 ident: wm5719_bb9 publication-title: Z. Kristallogr. Cryst. Mater. doi: 10.1524/zkri.216.8.449.20358 – ident: wm5719_bb13 |
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| Snippet | Coarse colorless single crystals of lithium lutetium bis[orthomolybdate(VI)], LiLu[MoO
4
]
2
, were obtained as a by-product from a reaction aimed at lithium... Coarse colorless single crystals of lithium lutetium bis-[orthomolybdate(VI)], LiLu[MoO ] , were obtained as a by-product from a reaction aimed at lithium... The crystal structure of LiLu[MoO4]2, which emerged as a by-product of the synthesis to obtain lithium derivatives of lutetium molybdate, adopts the scheelite... Coarse colorless single crystals of lithium lutetium bis[orthomolybdate(VI)], LiLu[MoO4]2, were obtained as a by-product from a reaction aimed at lithium... |
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| SubjectTerms | crystal structure lithium lutetium mixed occupancy molybdates Research Communications scheelite |
| Title | Mixed occupancy: the crystal structure of scheelite-type LiLu[MoO 4 ] 2 |
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