Fishing for Catalysts: Mechanism-Based Probes for Active Species in Solution
A combination of derivatization with charged substrates and electrospray‐ionization mass spectrometry is used to fish out the active species in a catalytic reaction. The observed species in the mass spectrometer corresponds to the resting state of the catalyst. Data for the ring‐opening metathesis p...
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| Vydáno v: | Helvetica chimica acta Ročník 83; číslo 9; s. 2192 - 2196 |
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| Hlavní autoři: | , |
| Médium: | Journal Article |
| Jazyk: | angličtina |
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Basel
Verlag Helvetica Chimica Acta
06.09.2000
Wiley |
| Témata: | |
| ISSN: | 0018-019X, 1522-2675 |
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| Abstract | A combination of derivatization with charged substrates and electrospray‐ionization mass spectrometry is used to fish out the active species in a catalytic reaction. The observed species in the mass spectrometer corresponds to the resting state of the catalyst. Data for the ring‐opening metathesis polymerization (ROMP) of norbornene by (Cy3P)2Cl2Ru=CHPh (Cy=cyclohexyl) are used to illustrate the method. |
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| AbstractList | A combination of derivatization with charged substrates and electrospray-ionization mass spectrometry is used to fish out the active species in a catalytic reaction. The observed species in the mass spectrometer corresponds to the resting state of the catalyst. Data for the ring-opening metathesis polymerization (ROMP) of norbornene by (Cy3P)2Cl2Ru=CHPh (Cy=cyclohexyl) are used to illustrate the method. A combination of derivatization with charged substrates and electrospray-ionization mass spectrometry is used to fish out the active species in a catalytic reaction. The observed species in the mass spectrometer corresponds to the resting state of the catalyst. Data for the ring-opening metathesis polymerization (ROMP) of norbornene by (Cy3P)(3)Cl2Ru = CHPh (Cy = cyclohexyl) are used to illustrate the method. |
| Author | Adlhart, Christian Chen, Peter |
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| Keywords | OLEFIN METATHESIS CATALYSTS |
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| References | Lynn, DM (WOS:000072246500043) 1998; 120 HINDERLING C (WOS:000089843100008.6) 1998; 110 Hinderling, C (WOS:A1997YE66100026) 1997; 119 Ulman, M (WOS:000074172700018) 1998; 17 Dias, EL (WOS:000074448800015) 1998; 17 FEICHTINGER D (WOS:000089843100008.4) 1997; 109 HINDERLING C (WOS:000089843100008.8) 1997; 109 Kim, YM (WOS:000079857900077) 1999; 185 COLE RD (WOS:000089843100008.1) 1997 HALPERN, J (WOS:A1982NY36400006) 1982; 217 Schwab, P (WOS:A1996TQ16100014) 1996; 118 Dias, EL (WOS:A1997WW93800005) 1997; 119 |
| References_xml | – volume: 109 start-page: 272 year: 1997 ident: WOS:000089843100008.8 publication-title: ANGEW CHEM – volume: 17 start-page: 2758 year: 1998 ident: WOS:000074448800015 article-title: Synthesis and investigation of homo- and heterobimetallic ruthenium olefin metathesis catalysts exhibiting increased activities publication-title: ORGANOMETALLICS – volume: 118 start-page: 100 year: 1996 ident: WOS:A1996TQ16100014 article-title: Synthesis and applications of RuCl2(=CHR')(PR(3))(2): The influence of the alkylidene moiety on metathesis activity publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY – volume: 185 start-page: 871 year: 1999 ident: WOS:000079857900077 article-title: Reactions of electrosprayed rhodium phosphine complexes in the gas phase: modeling homogeneous catalytic hydrogenation publication-title: INTERNATIONAL JOURNAL OF MASS SPECTROMETRY – year: 1997 ident: WOS:000089843100008.1 publication-title: ELECTROSPRAY IONIZAT – volume: 110 start-page: 2831 year: 1998 ident: WOS:000089843100008.6 publication-title: ANGEW CHEM – volume: 120 start-page: 1627 year: 1998 ident: WOS:000072246500043 article-title: Living ring-opening metathesis polymerization in water publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY – volume: 17 start-page: 2484 year: 1998 ident: WOS:000074172700018 article-title: Relative reaction rates of olefin substrates with ruthenium(II) carbene metathesis initiators publication-title: ORGANOMETALLICS – volume: 217 start-page: 401 year: 1982 ident: WOS:A1982NY36400006 article-title: MECHANISM AND STEREOSELECTIVITY OF ASYMMETRIC HYDROGENATION publication-title: SCIENCE – volume: 119 start-page: 3887 year: 1997 ident: WOS:A1997WW93800005 article-title: Well-defined ruthenium olefin metathesis catalysts: Mechanism and activity publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY – volume: 119 start-page: 10793 year: 1997 ident: WOS:A1997YE66100026 article-title: A combined gas-phase, solution-phase, and computational study of C-H activation by cationic iridium(III) complexes publication-title: JOURNAL OF THE AMERICAN CHEMICAL SOCIETY – volume: 109 start-page: 1796 year: 1997 ident: WOS:000089843100008.4 publication-title: ANGEW CHEM |
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| Title | Fishing for Catalysts: Mechanism-Based Probes for Active Species in Solution |
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