A zirconium methacrylate oxocluster as precursor for the low-temperature synthesis of porous zirconium(IV) dicarboxylates

The exchange of the monocarboxylate ligand of the zirconium methacrylate oxocluster Zr(6)O(4)(OH)(4)(OMc)(12) (OMc = CH(2)=CH(CH(3))COO) with dicarboxylic acids (trans,trans muconic acid and terephthalic acid) leads to porous zirconium dicarboxylates exhibiting the UiO-66 architecture; the mild reac...

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Bibliographic Details
Published in:Chemical communications (Cambridge, England) Vol. 46; no. 5; p. 767
Main Authors: Guillerm, Vincent, Gross, Silvia, Serre, Christian, Devic, Thomas, Bauer, Matthias, Férey, Gérard
Format: Journal Article
Language:English
Published: England 01.01.2010
Subjects:
Hydrocarbons, Chlorinated - chemistry
Particle Size
Porosity
Surface Properties
Temperature
Zirconium - chemistry
ISSN:1364-548X, 1364-548X
Online Access:Get more information
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Summary:The exchange of the monocarboxylate ligand of the zirconium methacrylate oxocluster Zr(6)O(4)(OH)(4)(OMc)(12) (OMc = CH(2)=CH(CH(3))COO) with dicarboxylic acids (trans,trans muconic acid and terephthalic acid) leads to porous zirconium dicarboxylates exhibiting the UiO-66 architecture; the mild reaction conditions allow the control of their particle size.
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ISSN:1364-548X
1364-548X
DOI:10.1039/b914919h