Selective Adsorption and Separation of Xylene Isomers and Ethylbenzene with the Microporous Vanadium(IV) Terephthalate MIL-47

A breakthrough result: The microporous metal–organic framework MIL‐47 is an excellent adsorbent for the separation of C8 alkylaromatic compounds, such as ethylbenzene, meta‐xylene, and para‐xylene. The potential of MIL‐47, with its high uptake capacity and its hydrophobic nature, for real separation...

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Vydáno v:Angewandte Chemie International Edition Ročník 46; číslo 23; s. 4293 - 4297
Hlavní autoři: Alaerts, Luc, Kirschhock, Christine E. A., Maes, Michael, van der Veen, Monique A., Finsy, Vincent, Depla, Anouschka, Martens, Johan A., Baron, Gino V., Jacobs, Pierre A., Denayer, Joeri F. M., De Vos, Dirk E.
Médium: Journal Article
Jazyk:angličtina
Vydáno: Weinheim WILEY-VCH Verlag 01.01.2007
WILEY‐VCH Verlag
Témata:
Adsorption
Benzene Derivatives - chemistry
host-guest systems
Isomerism
liquid chromatography
metal-organic frameworks
microporous materials
Organometallic Compounds - chemistry
Porosity
Surface Properties
Xylenes - chemistry
ISSN:1433-7851, 1521-3773
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Shrnutí:A breakthrough result: The microporous metal–organic framework MIL‐47 is an excellent adsorbent for the separation of C8 alkylaromatic compounds, such as ethylbenzene, meta‐xylene, and para‐xylene. The potential of MIL‐47, with its high uptake capacity and its hydrophobic nature, for real separations of the C8 alkylaromatic compounds was demonstrated by breakthrough and chromatographic experiments (see picture).
Bibliografie:istex:74902D24FAC9F9CC07AFE0EB563E5FDFCAC6B16C
ark:/67375/WNG-ZZFFFJNC-T
L.A. and J.D. are grateful to F.W.O.-Vlaanderen (Research Foundation-Flanders) for positions as a research assistant and post-doctoral researcher, respectively. This work was performed in the frame of the IAP Functional Supramolecular Systems of the Belgian Federal Government.
Belgian Federal Government
ArticleID:ANIE200700056
L.A. and J.D. are grateful to F.W.O.‐Vlaanderen (Research Foundation—Flanders) for positions as a research assistant and post‐doctoral researcher, respectively. This work was performed in the frame of the IAP Functional Supramolecular Systems of the Belgian Federal Government.
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ISSN:1433-7851
1521-3773
DOI:10.1002/anie.200700056