Unprecedented ROMP Activity of Low-Valent Rhenium-Nitrosyl Complexes: Mechanistic Evaluation of an Electrophilic Olefin Metathesis System

The reaction of [Re(H)(NO)2(PR3)2] complexes (1 a: R = PCy3; 1 b: R = PiPr3) with [H(OEt2)2][BArF4] ([BArF4] = tetrakis{3,5‐bis(trifluoromethyl)phenyl}borate) in benzene at room temperature gave the corresponding cations [Re(NO)2(PR3)2][BArF4] (2 a and 2 b). The addition of phenyldiazomethane to ben...

Celý popis

Podrobná bibliografia

Vydané v:	Chemistry : a European journal Ročník 12; číslo 12; s. 3325 - 3338
Hlavní autori:	Frech, Christian M., Blacque, Olivier, Schmalle, Helmut W., Berke, Heinz, Adlhart, Christian, Chen, Peter
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	Weinheim WILEY-VCH Verlag 12.04.2006 WILEY‐VCH Verlag
Predmet:	density functional calculations metathesis reaction mechanisms rhenium ring- opening polymerization
ISSN:	0947-6539, 1521-3765
On-line prístup:	Získať plný text
Tagy:	Pridať tag Žiadne tagy, Buďte prvý, kto otaguje tento záznam!