Unprecedented ROMP Activity of Low-Valent Rhenium-Nitrosyl Complexes: Mechanistic Evaluation of an Electrophilic Olefin Metathesis System

The reaction of [Re(H)(NO)2(PR3)2] complexes (1 a: R = PCy3; 1 b: R = PiPr3) with [H(OEt2)2][BArF4] ([BArF4] = tetrakis{3,5‐bis(trifluoromethyl)phenyl}borate) in benzene at room temperature gave the corresponding cations [Re(NO)2(PR3)2][BArF4] (2 a and 2 b). The addition of phenyldiazomethane to ben...

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Bibliographic Details

Published in:	Chemistry : a European journal Vol. 12; no. 12; pp. 3325 - 3338
Main Authors:	Frech, Christian M., Blacque, Olivier, Schmalle, Helmut W., Berke, Heinz, Adlhart, Christian, Chen, Peter
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 12.04.2006 WILEY‐VCH Verlag
Subjects:	density functional calculations metathesis reaction mechanisms rhenium ring- opening polymerization
ISSN:	0947-6539, 1521-3765
Online Access:	Get full text
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