Variations in Electric Switching and Transverse Resistance of GeTe/ Sb2Te3 Superlattices at Elevated Temperature Studied by Conductive Scanning Probe Microscopy
Temperature-dependent variations in electric switching and transverse resistance of phase-change [(GeTe) 2 (Sb 2 Te 3 )] n (n=4 and 8) chalcogenide superlattice (CSL) films were studied using conductive scanning probe microscopy (SPM). Three temperature regions with different electric transport prop...
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| Published in: | MRS advances Vol. 3; no. 5; pp. 241 - 246 |
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| Format: | Journal Article |
| Language: | English |
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New York, USA
Materials Research Society
2018
Springer International Publishing |
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| ISSN: | 2059-8521, 2059-8521 |
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| Abstract | Temperature-dependent variations in electric switching and transverse resistance of phase-change [(GeTe)
2
(Sb
2
Te
3
)]
n
(n=4 and 8) chalcogenide superlattice (CSL) films were studied using conductive scanning probe microscopy (SPM). Three temperature regions with different electric transport properties were recognized in point current-voltage (I-V) spectra and the surface potential maps measured with tantalum and platinum-coated SPM cantilevers. At around 80°C the switching voltage decreased abruptly from ∼2 V to 0.5 V and the thermal coefficient of resistance changes its sign, indicating different carrier transport mechanisms. The observed changes correlated with decrease in the surface potential by ∼150 meV from 25 to 150°C. The results were ascribed to an opening of the CSL electronic band gap near the Fermi energy caused by thermal stress, which led to the transition from a Dirac-like semimetal to a narrow-gap semiconductor. |
|---|---|
| AbstractList | Temperature-dependent variations in electric switching and transverse resistance of phase-change
[(GeTe)
2
(Sb
2
Te
3
)]
n
(n=4 and 8) chalcogenide superlattice (CSL) films were studied using conductive scanning probe microscopy (SPM). Three temperature regions with different electric transport properties were recognized in point current-voltage (I-V) spectra and the surface potential maps measured with tantalum and platinum-coated SPM cantilevers. At around 80°C the switching voltage decreased abruptly from ∼2 V to 0.5 V and the thermal coefficient of resistance changes its sign, indicating different carrier transport mechanisms. The observed changes correlated with decrease in the surface potential by ∼150 meV from 25 to 150°C. The results were ascribed to an opening of the CSL electronic band gap near the Fermi energy caused by thermal stress, which led to the transition from a Dirac-like semimetal to a narrow-gap semiconductor. Temperature-dependent variations in electric switching and transverse resistance of phase-change [(GeTe) 2 (Sb 2 Te 3 )] n (n=4 and 8) chalcogenide superlattice (CSL) films were studied using conductive scanning probe microscopy (SPM). Three temperature regions with different electric transport properties were recognized in point current-voltage (I-V) spectra and the surface potential maps measured with tantalum and platinum-coated SPM cantilevers. At around 80°C the switching voltage decreased abruptly from ∼2 V to 0.5 V and the thermal coefficient of resistance changes its sign, indicating different carrier transport mechanisms. The observed changes correlated with decrease in the surface potential by ∼150 meV from 25 to 150°C. The results were ascribed to an opening of the CSL electronic band gap near the Fermi energy caused by thermal stress, which led to the transition from a Dirac-like semimetal to a narrow-gap semiconductor. |
| Author | Tominaga, Junji Tada, Tetsuya Saito, Yuta Bolotov, Leonid |
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| Cites_doi | 10.1038/srep33223 10.1038/srep29162 10.1016/j.tsf.2008.08.194 10.1038/nnano.2011.96 10.1002/pssb.201552335 10.1021/acsami.7b04450 10.1002/admi.201300027 10.1103/PhysRevB.89.075124 10.7567/JJAP.55.04EK02 10.1063/1.3651275 10.1063/1.4948536 10.1038/srep12612 10.1103/PhysRevLett.119.136806 10.1038/srep38799 |
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| References | YuXRobinsonJScientific Reports20155126121:CAS:528:DC%2BC2MXhtlCjsLfO10.1038/srep12612 WangC MSunHai-PengLuHai-ZhouXieX CPhys. Rev. Lett20171191368061:STN:280:DC%2BC1MvhsV2lsA%3D%3D10.1103/PhysRevLett.119.136806 SaitoYFonsPBolotovLMiyataNKolobovAVTominagaJAIP Adv2016604522010.1063/1.4948536 CiocchiniNLaudatoMBoniardiMWaresiEFantiniPLacaitaALIelminiDScientific Reports20166291621:CAS:528:DC%2BC28XhtFaht7fJ10.1038/srep29162 BolotovLTadaTSaitoYTominagaJJpn. J. Appl. Phys20165504EK0210.7567/JJAP.55.04EK02 EremeevSVRusinovIPEcheniquePMChulkovEVScientific Reports20166387991:CAS:528:DC%2BC28XitFGjtr%2FP10.1038/srep38799 TominagaJKolobovAVFonsPNakanoTMurakamiSAdv. Mater. Interfaces20141130002710.1002/admi.201300027 SaitoYMakinoKFonsPKolobovAVTominagaJACS Appl. Mater. Interfaces2017923918239251:CAS:528:DC%2BC2sXhtVKisL3O10.1021/acsami.7b04450 MitrofanovKVSaitoYMiyataNFonsPKolobovAVTominagaJExt. Abstracts of Int. Conf. on Solid State Devices and Materials, Sendai, Japan, Sept.20171922 TominagaJSimpsonREFonsPKolobovAVAppl. Phys. Lett20119915210510.1063/1.3651275 BolotovLSaitoYTadaTTominagaJScientific Reports20166332231:CAS:528:DC%2BC28XhsFWmsrrJ10.1038/srep33223 LandsteinerKPhys. Rev. B20148907512410.1103/PhysRevB.89.075124 ParkIMJungJKRyuSOChoiKJYuBGParkYBHanSMJooYCThin Solid Films20085178488521:CAS:528:DC%2BD1cXhtlGju7%2FI10.1016/j.tsf.2008.08.194 SimpsonREFonsPKolobovAVFukayaTKrbalMYagiTTominagaJNat. Nanotachnol201165015051:CAS:528:DC%2BC3MXotlCktL4%3D10.1038/nnano.2011.96 J. Kim, J. Kim, Y.S. Song, R. Wu, S.H. Jhi, N. Kioussis, arXiv preprint arXiv: 1702.05579 (Feb.2017) SaitoYFonsPKolobovAVTominagaJPhys. Stat. Solidi (b)2015252215121581:CAS:528:DC%2BC2MXhtlSlu73I10.1002/pssb.201552335 K Landsteiner (3050241_CR12) 2014; 89 KV Mitrofanov (3050241_CR7) 2017 N Ciocchini (3050241_CR6) 2016; 6 X Yu (3050241_CR8) 2015; 5 L Bolotov (3050241_CR4) 2016; 6 Y Saito (3050241_CR16) 2017; 9 3050241_CR10 IM Park (3050241_CR15) 2008; 517 RE Simpson (3050241_CR1) 2011; 6 J Tominaga (3050241_CR3) 2011; 99 J Tominaga (3050241_CR2) 2014; 1 C M Wang (3050241_CR11) 2017; 119 SV Eremeev (3050241_CR9) 2016; 6 Y Saito (3050241_CR14) 2015; 252 L Bolotov (3050241_CR5) 2016; 55 Y Saito (3050241_CR13) 2016; 6 |
| References_xml | – reference: YuXRobinsonJScientific Reports20155126121:CAS:528:DC%2BC2MXhtlCjsLfO10.1038/srep12612 – reference: TominagaJSimpsonREFonsPKolobovAVAppl. Phys. Lett20119915210510.1063/1.3651275 – reference: SaitoYFonsPBolotovLMiyataNKolobovAVTominagaJAIP Adv2016604522010.1063/1.4948536 – reference: SaitoYMakinoKFonsPKolobovAVTominagaJACS Appl. Mater. Interfaces2017923918239251:CAS:528:DC%2BC2sXhtVKisL3O10.1021/acsami.7b04450 – reference: SimpsonREFonsPKolobovAVFukayaTKrbalMYagiTTominagaJNat. Nanotachnol201165015051:CAS:528:DC%2BC3MXotlCktL4%3D10.1038/nnano.2011.96 – reference: BolotovLTadaTSaitoYTominagaJJpn. J. Appl. Phys20165504EK0210.7567/JJAP.55.04EK02 – reference: WangC MSunHai-PengLuHai-ZhouXieX CPhys. Rev. Lett20171191368061:STN:280:DC%2BC1MvhsV2lsA%3D%3D10.1103/PhysRevLett.119.136806 – reference: EremeevSVRusinovIPEcheniquePMChulkovEVScientific Reports20166387991:CAS:528:DC%2BC28XitFGjtr%2FP10.1038/srep38799 – reference: J. Kim, J. Kim, Y.S. Song, R. Wu, S.H. Jhi, N. Kioussis, arXiv preprint arXiv: 1702.05579 (Feb.2017) – reference: CiocchiniNLaudatoMBoniardiMWaresiEFantiniPLacaitaALIelminiDScientific Reports20166291621:CAS:528:DC%2BC28XhtFaht7fJ10.1038/srep29162 – reference: ParkIMJungJKRyuSOChoiKJYuBGParkYBHanSMJooYCThin Solid Films20085178488521:CAS:528:DC%2BD1cXhtlGju7%2FI10.1016/j.tsf.2008.08.194 – reference: MitrofanovKVSaitoYMiyataNFonsPKolobovAVTominagaJExt. Abstracts of Int. Conf. on Solid State Devices and Materials, Sendai, Japan, Sept.20171922 – reference: TominagaJKolobovAVFonsPNakanoTMurakamiSAdv. Mater. Interfaces20141130002710.1002/admi.201300027 – reference: BolotovLSaitoYTadaTTominagaJScientific Reports20166332231:CAS:528:DC%2BC28XhsFWmsrrJ10.1038/srep33223 – reference: LandsteinerKPhys. Rev. B20148907512410.1103/PhysRevB.89.075124 – reference: SaitoYFonsPKolobovAVTominagaJPhys. Stat. Solidi (b)2015252215121581:CAS:528:DC%2BC2MXhtlSlu73I10.1002/pssb.201552335 – volume: 6 start-page: 33223 year: 2016 ident: 3050241_CR4 publication-title: Scientific Reports doi: 10.1038/srep33223 – volume: 6 start-page: 29162 year: 2016 ident: 3050241_CR6 publication-title: Scientific Reports doi: 10.1038/srep29162 – ident: 3050241_CR10 – start-page: 19 volume-title: Ext. Abstracts of Int. Conf. on Solid State Devices and Materials, Sendai, Japan, Sept. year: 2017 ident: 3050241_CR7 – volume: 517 start-page: 848 year: 2008 ident: 3050241_CR15 publication-title: Thin Solid Films doi: 10.1016/j.tsf.2008.08.194 – volume: 6 start-page: 501 year: 2011 ident: 3050241_CR1 publication-title: Nat. Nanotachnol doi: 10.1038/nnano.2011.96 – volume: 252 start-page: 2151 year: 2015 ident: 3050241_CR14 publication-title: Phys. Stat. Solidi (b) doi: 10.1002/pssb.201552335 – volume: 9 start-page: 23918 year: 2017 ident: 3050241_CR16 publication-title: ACS Appl. Mater. Interfaces doi: 10.1021/acsami.7b04450 – volume: 1 start-page: 1300027 year: 2014 ident: 3050241_CR2 publication-title: Adv. Mater. Interfaces doi: 10.1002/admi.201300027 – volume: 89 start-page: 075124 year: 2014 ident: 3050241_CR12 publication-title: Phys. Rev. B doi: 10.1103/PhysRevB.89.075124 – volume: 55 start-page: 04EK02 year: 2016 ident: 3050241_CR5 publication-title: Jpn. J. Appl. Phys doi: 10.7567/JJAP.55.04EK02 – volume: 99 start-page: 152105 year: 2011 ident: 3050241_CR3 publication-title: Appl. Phys. Lett doi: 10.1063/1.3651275 – volume: 6 start-page: 045220 year: 2016 ident: 3050241_CR13 publication-title: AIP Adv doi: 10.1063/1.4948536 – volume: 5 start-page: 12612 year: 2015 ident: 3050241_CR8 publication-title: Scientific Reports doi: 10.1038/srep12612 – volume: 119 start-page: 136806 year: 2017 ident: 3050241_CR11 publication-title: Phys. Rev. Lett doi: 10.1103/PhysRevLett.119.136806 – volume: 6 start-page: 38799 year: 2016 ident: 3050241_CR9 publication-title: Scientific Reports doi: 10.1038/srep38799 |
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| Snippet | Temperature-dependent variations in electric switching and transverse resistance of phase-change [(GeTe)
2
(Sb
2
Te
3
)]
n
(n=4 and 8) chalcogenide... Temperature-dependent variations in electric switching and transverse resistance of phase-change [(GeTe) 2 (Sb 2 Te 3 )] n (n=4 and 8) chalcogenide... |
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| SubjectTerms | Applied and Technical Physics Biomaterials Characterization and Evaluation of Materials Materials Engineering Materials Science Nanotechnology |
| Title | Variations in Electric Switching and Transverse Resistance of GeTe/ Sb2Te3 Superlattices at Elevated Temperature Studied by Conductive Scanning Probe Microscopy |
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