Corrosion of organosilane coated Mg4Y alloy in sodium chloride solution evaluated by impedance spectroscopy and pH changes

Electrochemical impedance spectroscopy (EIS), open circuit potential and pH changes were used to examine the corrosion of magnesium 4% yttrium alloy (Mg4Y) with and without a silane-epoxy-coating (SEC) in a stirred 0.154M NaCl solution at 37°C. For a good quality SEC we find a relatively low non-Far...

Full description

Saved in:

Bibliographic Details
Published in:	Electrochimica acta Vol. 70; pp. 165 - 170
Main Authors:	Doepke, Amos, Xue, Dingchuan, Yun, Yeoheung, Vanooij, William J., Brian Halsall, H., Heineman, William R.
Format:	Journal Article
Language:	English
Published:	Kidlington Elsevier Ltd 30.05.2012 Elsevier
Subjects:	Applied sciences Corrosion Corrosion mechanisms Corrosion tests EIS Electrochemical impedance spectroscopy Exact sciences and technology Magnesium Magnesium base alloys Metals. Metallurgy Open circuit potential Yttrium base alloys Corrosion EIS Magnesium Silicon Organic compounds Organic silane Alkaline earth metal Coated material Magnesium alloy pH Yttrium alloy Binary alloy Sodium Chlorides Electrochemical impedance spectroscopy
ISSN:	0013-4686, 1873-3859
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!

Abstract	Electrochemical impedance spectroscopy (EIS), open circuit potential and pH changes were used to examine the corrosion of magnesium 4% yttrium alloy (Mg4Y) with and without a silane-epoxy-coating (SEC) in a stirred 0.154M NaCl solution at 37°C. For a good quality SEC we find a relatively low non-Faradaic resistance of 266Ωcm2. The quality of the SEC was affected by the curing temperature. In this article we compare the electrochemical measurements taken during corrosion of bare Mg4Y, Mg4Y with a SEC that remained intact, and a SEC that did not protect the Mg from corrosion.
AbstractList	Electrochemical impedance spectroscopy (EIS), open circuit potential and pH changes were used to examine the corrosion of magnesium 4% yttrium alloy (Mg4Y) with and without a silane-epoxy-coating (SEC) in a stirred 0.154 M NaCl solution at 37 [deg]C. For a good quality SEC we find a relatively low non-Faradaic resistance of 266 ICO cm2. The quality of the SEC was affected by the curing temperature. In this article we compare the electrochemical measurements taken during corrosion of bare Mg4Y, Mg4Y with a SEC that remained intact, and a SEC that did not protect the Mg from corrosion. Electrochemical impedance spectroscopy (EIS), open circuit potential and pH changes were used to examine the corrosion of magnesium 4% yttrium alloy (Mg4Y) with and without a silane-epoxy-coating (SEC) in a stirred 0.154M NaCl solution at 37°C. For a good quality SEC we find a relatively low non-Faradaic resistance of 266Ωcm2. The quality of the SEC was affected by the curing temperature. In this article we compare the electrochemical measurements taken during corrosion of bare Mg4Y, Mg4Y with a SEC that remained intact, and a SEC that did not protect the Mg from corrosion.
Author	Brian Halsall, H. Doepke, Amos Xue, Dingchuan Yun, Yeoheung Vanooij, William J. Heineman, William R.
Author_xml	– sequence: 1 givenname: Amos surname: Doepke fullname: Doepke, Amos organization: Department of Chemistry, University of Cincinnati, Cincinnati, OH 45221, United States – sequence: 2 givenname: Dingchuan surname: Xue fullname: Xue, Dingchuan organization: College of Engineering, University of Cincinnati, Cincinnati, OH 45221, United States – sequence: 3 givenname: Yeoheung surname: Yun fullname: Yun, Yeoheung organization: North Carolina Agricultural and Technical State University, Greensboro, NC 27411, United States – sequence: 4 givenname: William J. surname: Vanooij fullname: Vanooij, William J. organization: Ecosil Technologies LLC, Fairfield, OH 45014, United States – sequence: 5 givenname: H. surname: Brian Halsall fullname: Brian Halsall, H. organization: Department of Chemistry, University of Cincinnati, Cincinnati, OH 45221, United States – sequence: 6 givenname: William R. surname: Heineman fullname: Heineman, William R. email: heinemwr@ucmail.uc.edu organization: Department of Chemistry, University of Cincinnati, Cincinnati, OH 45221, United States
BackLink	http://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=25867048$$DView record in Pascal Francis
BookMark	eNqFkcFvFCEUxompidvq3yAXEy8zhYEB5uCh2VhrUuNFD54IC29WNiyMMNNk-9fLuNWDlyYk5IXv9x7v-y7RRUwREHpLSUsJFdeHFgLY2dTTdoR2LWEt4eQF2lAlWcNUP1ygDSGUNVwo8QpdlnIghEghyQY9blPOqfgUcRpxynsTaxVMBGyTmcHhL3v-A5sQ0gn7iEtyfjli-zOk7B3UOizzSsODCcsfYFeFxwmciba-T_VvdYBN0wmb6PB0V2ET91Beo5ejCQXePN1X6Pvtx2_bu-b-66fP25v7xjKp5mYgw8BFZ7hwfW9IP3LJd5bvRtPByAYnqQJFhbSwc1IqSUbWUQtUmN7yAQS7Qu_Pfaecfi1QZn30xUJYl0xL0ZQw1YmO9rRK3z1JTbEmjLnu4Iuesj-afNJdr6ppXFXdh7PO1tVKhlFbP5vVhzkbH2pLvWajD_pfNnrNRhOmazaVl__xf0c8T96cSaiOPXjIulgP1Wnnc9Vrl_yzPX4DRaGyTA
CODEN	ELCAAV
CitedBy_id	crossref_primary_10_1016_j_actbio_2013_07_011 crossref_primary_10_1016_j_porgcoat_2013_03_004 crossref_primary_10_1016_j_porgcoat_2013_01_010 crossref_primary_10_1007_s11665_023_09015_9 crossref_primary_10_1016_j_mser_2014_01_001 crossref_primary_10_1016_j_actbio_2016_11_039 crossref_primary_10_1007_s12598_016_0784_6 crossref_primary_10_1021_acsbiomaterials_6b00585 crossref_primary_10_1093_rb_rbx004 crossref_primary_10_1016_j_corsci_2020_108729 crossref_primary_10_1016_j_mtcomm_2023_106051 crossref_primary_10_1016_j_surfcoat_2017_06_031
Cites_doi	10.1136/heart.89.6.651 10.1016/j.corsci.2009.10.016 10.1149/1.2401056 10.1016/j.electacta.2011.02.050 10.1149/1.2428817 10.3109/15563659309000375 10.1016/S0300-9440(02)00217-5 10.1016/j.elecom.2007.12.003 10.1016/S0022-0728(74)80298-6 10.1002/jbm.a.32106 10.1016/S0378-7753(96)02456-1 10.1149/1.2049981 10.1016/j.corsci.2009.04.025 10.1016/j.corsci.2010.09.016 10.1016/j.biomaterials.2004.09.049 10.1163/156856192X00106 10.1016/j.corsci.2005.01.010 10.1002/adem.200310405 10.4028/www.scientific.net/AMM.52-54.1947 10.1149/1.1415722 10.1149/1.3421651 10.1016/S0010-938X(96)00172-2 10.1002/ccd.20520 10.1016/j.corsci.2008.08.023 10.1016/j.porgcoat.2011.08.005 10.1016/j.biomaterials.2005.10.003 10.1149/1.2918900 10.1016/S1369-7021(09)70273-1 10.1016/j.tsf.2006.02.023
ContentType	Journal Article
Copyright	2012 Elsevier Ltd 2015 INIST-CNRS
Copyright_xml	– notice: 2012 Elsevier Ltd – notice: 2015 INIST-CNRS
DBID	AAYXX CITATION IQODW 7QF 7SE 7SR 7U5 8BQ 8FD JG9 L7M
DOI	10.1016/j.electacta.2012.03.040
DatabaseName	CrossRef Pascal-Francis Aluminium Industry Abstracts Corrosion Abstracts Engineered Materials Abstracts Solid State and Superconductivity Abstracts METADEX Technology Research Database Materials Research Database Advanced Technologies Database with Aerospace
DatabaseTitle	CrossRef Materials Research Database Engineered Materials Abstracts Aluminium Industry Abstracts Technology Research Database Solid State and Superconductivity Abstracts Corrosion Abstracts Advanced Technologies Database with Aerospace METADEX
DatabaseTitleList	Materials Research Database
DeliveryMethod	fulltext_linktorsrc
Discipline	Engineering Chemistry Applied Sciences
EISSN	1873-3859
EndPage	170
ExternalDocumentID	25867048 10_1016_j_electacta_2012_03_040 S0013468612003799
GroupedDBID	--K --M -~X .~1 0R~ 1B1 1RT 1~. 1~5 4.4 457 4G. 5GY 5VS 7-5 71M 8P~ 9JN AABNK AACTN AAEDT AAEDW AAIAV AAIKJ AAKOC AALRI AAOAW AAQFI AARLI AAXUO ABFNM ABFRF ABJNI ABMAC ABNUV ABXDB ABYKQ ACBEA ACDAQ ACGFO ACGFS ACIWK ACNCT ACNNM ACRLP ADBBV ADECG ADEWK ADEZE ADIYS ADMUD AEBSH AEFWE AEKER AENEX AFKWA AFTJW AFZHZ AGHFR AGUBO AGYEJ AHHHB AHPOS AIEXJ AIKHN AITUG AJBFU AJOXV AJSZI AKURH ALMA_UNASSIGNED_HOLDINGS AMFUW AMRAJ AXJTR BKOJK BLXMC CS3 DU5 EBS EFJIC EFLBG ENUVR EO8 EO9 EP2 EP3 F5P FDB FIRID FLBIZ FNPLU FYGXN G-Q GBLVA HZ~ IHE J1W KOM M36 M41 MO0 N9A O-L O9- OAUVE OZT P-8 P-9 P2P PC. Q38 RIG RNS ROL RPZ SDF SDG SDP SES SPC SPCBC SSG SSK SSZ T5K TWZ UPT WH7 XPP YK3 ZMT ~02 ~G- 29G 41~ 53G 9DU AAQXK AATTM AAXKI AAYWO AAYXX ABEFU ABWVN ACLOT ACRPL ACVFH ADCNI ADNMO AEIPS AEUPX AFJKZ AFPUW AGQPQ AI. AIDUJ AIGII AIIUN AJQLL AKBMS AKRWK AKYEP ANKPU APXCP ASPBG AVWKF AZFZN CITATION EFKBS EJD FEDTE FGOYB HMU HVGLF H~9 LPU R2- SC5 SCB SCH SEW T9H VH1 WUQ XOL ZY4 ~HD AFXIZ AGCQF AGRNS BNPGV IQODW SSH 7QF 7SE 7SR 7U5 8BQ 8FD JG9 L7M
ID	FETCH-LOGICAL-c378t-9099462a46d55a05f474bc4bfa2ef39d718e8167cebd77870f321ce16a5c49e63
ISICitedReferencesCount	14
ISICitedReferencesURI	http://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestLinkType=CitingArticles&DestApp=WOS_CPL&KeyUT=000304497000023&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D
ISSN	0013-4686
IngestDate	Sun Sep 28 00:43:39 EDT 2025 Mon Jul 21 09:16:08 EDT 2025 Sat Nov 29 03:01:02 EST 2025 Tue Nov 18 20:56:33 EST 2025 Fri Feb 23 02:17:33 EST 2024
IsPeerReviewed	true
IsScholarly	true
Keywords	Corrosion EIS Magnesium Silicon Organic compounds Organic silane Alkaline earth metal Coated material Magnesium alloy pH Yttrium alloy Binary alloy Sodium Chlorides Electrochemical impedance spectroscopy
Language	English
License	https://www.elsevier.com/tdm/userlicense/1.0 CC BY 4.0
LinkModel	OpenURL
MergedId	FETCHMERGED-LOGICAL-c378t-9099462a46d55a05f474bc4bfa2ef39d718e8167cebd77870f321ce16a5c49e63
Notes	ObjectType-Article-2 SourceType-Scholarly Journals-1 ObjectType-Feature-1 content type line 23
PQID	1038262151
PQPubID	23500
PageCount	6
ParticipantIDs	proquest_miscellaneous_1038262151 pascalfrancis_primary_25867048 crossref_citationtrail_10_1016_j_electacta_2012_03_040 crossref_primary_10_1016_j_electacta_2012_03_040 elsevier_sciencedirect_doi_10_1016_j_electacta_2012_03_040
PublicationCentury	2000
PublicationDate	2012-05-30
PublicationDateYYYYMMDD	2012-05-30
PublicationDate_xml	– month: 05 year: 2012 text: 2012-05-30 day: 30
PublicationDecade	2010
PublicationPlace	Kidlington
PublicationPlace_xml	– name: Kidlington
PublicationTitle	Electrochimica acta
PublicationYear	2012
Publisher	Elsevier Ltd Elsevier
Publisher_xml	– name: Elsevier Ltd – name: Elsevier
References	Staiger, Pietak, Huadmai, Dias (bib0005) 2006; 27 G.B. Stroganov, E.M. Savitsky, N.M. Tikhova, V.F. Terekhova, M.V. Volkov, K.M. Sivash, V.S. Borodkin,;1; Magnesium-base alloy for use in bone surgery, United States Patent US 3687135 (1972). Shi, Atrens (bib0120) 2011; 53 Hoffman, Smilkstein, Rowland, Goldfrank (bib0105) 1993; 31 Lamaka, Karavai, Bastos, Zheludkevich, Ferreira (bib0060) 2008; 10 Mueller, Fernández Lorenzo de Mele, Nascimento, Zeddies (bib0085) 2009; 90A Nordlien, Ono, Masuko, Nişancioglu (bib0070) 1995; 142 Baril, Galicia, Deslouis, Pébère, Tribollet, Vivier (bib0140) 2007; 154 Zhang, Yan, Wang, Li (bib0150) 2005; 47 Hoey, Cohen (bib0055) 1958; 105 Williams, McMurray (bib0065) 2008; 155 Zhang, Wang, Liu, Ying (bib0130) 2011; 52–54 Liu, Schlesinger (bib0035) 2009; 51 Song, Atrens (bib0050) 2003; 5 Heublein, Rohde, Kaese, Niemeyer, Hartung, Haverich (bib0080) 2003; 89 Shi, Liu, Atrens (bib0115) 2010; 52 Yun, Dong, Lee, Liu, Xue, Guo, Kuhlmann, Doepke, Halsall, Heineman, Sundaramurthy, Schulz, Yin, Shanov, Hurd, Nagy, Li, Fox (bib0010) 2009; 12 Baril, Blanc, Pébère (bib0135) 2001; 148 Perrault (bib0040) 1974; 51 Khramov, Balbyshev, Kasten, Mantz (bib0025) 2006; 514 Osterholtz, Pohl (bib0125) 1992; 6 Zartner, Cesnjevar, Singer, Weyand (bib0095) 2005; 66 Correa, Malfatti, Azambuja (bib0030) 2011; 72 Zhao, Liu, Song, Atrens (bib0110) 2008; 50 Angelini, Grassini, Rosalbino, Fracassi, d’Agostino (bib0015) 2003; 46 Banerjee, Raman (bib0020) 2011; 56 Xin, Hu, Chu (bib0075) 2010; 157 Song, Atrens, Stjohn, Nairn, Li (bib0045) 1997; 39 Witte, Kaese, Haferkamp, Switzer, Meyer-Lindenberg, Wirth, Windhagen (bib0090) 2005; 26 Udhayan, Bhatt (bib0145) 1996; 63 Khramov (10.1016/j.electacta.2012.03.040_bib0025) 2006; 514 Udhayan (10.1016/j.electacta.2012.03.040_bib0145) 1996; 63 Correa (10.1016/j.electacta.2012.03.040_bib0030) 2011; 72 Song (10.1016/j.electacta.2012.03.040_bib0045) 1997; 39 Lamaka (10.1016/j.electacta.2012.03.040_bib0060) 2008; 10 Liu (10.1016/j.electacta.2012.03.040_bib0035) 2009; 51 Staiger (10.1016/j.electacta.2012.03.040_bib0005) 2006; 27 Yun (10.1016/j.electacta.2012.03.040_bib0010) 2009; 12 Zhang (10.1016/j.electacta.2012.03.040_bib0130) 2011; 52–54 Zhang (10.1016/j.electacta.2012.03.040_bib0150) 2005; 47 Baril (10.1016/j.electacta.2012.03.040_bib0140) 2007; 154 Baril (10.1016/j.electacta.2012.03.040_bib0135) 2001; 148 Shi (10.1016/j.electacta.2012.03.040_bib0115) 2010; 52 Williams (10.1016/j.electacta.2012.03.040_bib0065) 2008; 155 Banerjee (10.1016/j.electacta.2012.03.040_bib0020) 2011; 56 Angelini (10.1016/j.electacta.2012.03.040_bib0015) 2003; 46 10.1016/j.electacta.2012.03.040_bib0100 Hoffman (10.1016/j.electacta.2012.03.040_bib0105) 1993; 31 Perrault (10.1016/j.electacta.2012.03.040_bib0040) 1974; 51 Xin (10.1016/j.electacta.2012.03.040_bib0075) 2010; 157 Hoey (10.1016/j.electacta.2012.03.040_bib0055) 1958; 105 Nordlien (10.1016/j.electacta.2012.03.040_bib0070) 1995; 142 Osterholtz (10.1016/j.electacta.2012.03.040_bib0125) 1992; 6 Mueller (10.1016/j.electacta.2012.03.040_bib0085) 2009; 90A Zartner (10.1016/j.electacta.2012.03.040_bib0095) 2005; 66 Heublein (10.1016/j.electacta.2012.03.040_bib0080) 2003; 89 Shi (10.1016/j.electacta.2012.03.040_bib0120) 2011; 53 Witte (10.1016/j.electacta.2012.03.040_bib0090) 2005; 26 Song (10.1016/j.electacta.2012.03.040_bib0050) 2003; 5 Zhao (10.1016/j.electacta.2012.03.040_bib0110) 2008; 50
References_xml	– volume: 27 start-page: 1728 year: 2006 ident: bib0005 article-title: Magnesium and its alloys as orthopedic biomaterials: a review publication-title: Biomaterials – volume: 90A start-page: 487 year: 2009 ident: bib0085 article-title: Degradation of magnesium and its alloys: dependence on the composition of the synthetic biological media publication-title: Journal of Biomedical Materials Research Part A – volume: 66 start-page: 590 year: 2005 ident: bib0095 article-title: First successful implantation of a biodegradable metal stent into the left pulmonary artery of a preterm baby publication-title: Catheterization and Cardiovascular Interventions – volume: 157 start-page: C238 year: 2010 ident: bib0075 article-title: Influence of test solutions on in vitro studies of biomedical magnesium alloys publication-title: Journal of The Electrochemical Society – volume: 10 start-page: 259 year: 2008 ident: bib0060 article-title: Monitoring local spatial distribution of Mg publication-title: Electrochemistry Communications – volume: 154 start-page: C108 year: 2007 ident: bib0140 article-title: An impedance investigation of the mechanism of pure magnesium corrosion in sodium sulfate solutions publication-title: Journal of The Electrochemical Society – volume: 26 start-page: 3557 year: 2005 ident: bib0090 article-title: In vivo corrosion of four magnesium alloys and the associated bone response publication-title: Biomaterials – volume: 52–54 start-page: 1947 year: 2011 ident: bib0130 article-title: Effects of cure temperature on corrosion property of vinyltriethoxysilane films on carbon steel surfaces publication-title: Applied Mechanics and Materials – volume: 148 start-page: B489 year: 2001 ident: bib0135 article-title: AC impedance spectroscopy in characterizing time-dependent corrosion of AZ91 and AM50 magnesium alloys characterization with respect to their microstructures publication-title: Journal of The Electrochemical Society – volume: 39 start-page: 855 year: 1997 ident: bib0045 article-title: The electrochemical corrosion of pure magnesium in 1 N NaCl publication-title: Corrosion Science – volume: 52 start-page: 579 year: 2010 ident: bib0115 article-title: Measurement of the corrosion rate of magnesium alloys using Tafel extrapolation publication-title: Corrosion Science – volume: 72 start-page: 739 year: 2011 ident: bib0030 article-title: Corrosion behavior study of AZ91 magnesium alloy coated with methyltriethoxysilane doped with cerium ions publication-title: Progress in Organic Coatings – volume: 50 start-page: 3168 year: 2008 ident: bib0110 article-title: Influence of pH and chloride ion concentration on the corrosion of Mg alloy ZE41 publication-title: Corrosion Science – volume: 46 start-page: 107 year: 2003 ident: bib0015 article-title: Electrochemical impedance spectroscopy evaluation of the corrosion behaviour of Mg alloy coated with PECVD organosilicon thin film publication-title: Progress in Organic Coatings – volume: 514 start-page: 174 year: 2006 ident: bib0025 article-title: Sol–gel coatings with phosphonate functionalities for surface modification of magnesium alloys publication-title: Thin Solid Films – volume: 105 start-page: 245 year: 1958 ident: bib0055 article-title: Corrosion of anodically and cathodically polarized magnesium in aqueous media publication-title: Journal of The Electrochemical Society – volume: 5 start-page: 837 year: 2003 ident: bib0050 article-title: Understanding magnesium corrosion – a framework for improved alloy performance publication-title: Advanced Engineering Materials – volume: 12 start-page: 22 year: 2009 ident: bib0010 article-title: Revolutionizing biodegradable metals publication-title: Materials Today – volume: 89 start-page: 651 year: 2003 ident: bib0080 article-title: Biocorrosion of magnesium alloys: a new principle in cardiovascular implant technology? publication-title: Heart – volume: 31 start-page: 81 year: 1993 ident: bib0105 article-title: Osmol gaps revisited: normal values and limitations publication-title: Clinical Toxicology – volume: 63 start-page: 103 year: 1996 ident: bib0145 article-title: On the corrosion behaviour of magnesium and its alloys using electrochemical techniques publication-title: Journal of Power Sources – volume: 51 start-page: 107 year: 1974 ident: bib0040 article-title: The potential-pH diagram of the magnesium–water system publication-title: Journal of Electroanalytical Chemistry and Interfacial Electrochemistry – volume: 6 start-page: 127 year: 1992 ident: bib0125 article-title: Kinetics of the hydrolysis and condensation of organofunctional alkoxysilanes: a review publication-title: Journal of Adhesion Science and Technology – volume: 47 start-page: 2816 year: 2005 ident: bib0150 article-title: Electrochemical behavior of anodized Mg alloy AZ91D in chloride containing aqueous solution publication-title: Corrosion Science – volume: 53 start-page: 226 year: 2011 ident: bib0120 article-title: An innovative specimen configuration for the study of Mg corrosion publication-title: Corrosion Science – volume: 56 start-page: 3790 year: 2011 ident: bib0020 article-title: Electrochemical impedance spectroscopic investigation of the role of alkaline pre-treatment in corrosion resistance of a silane coating on magnesium alloy, ZE41 publication-title: Electrochimica Acta – reference: G.B. Stroganov, E.M. Savitsky, N.M. Tikhova, V.F. Terekhova, M.V. Volkov, K.M. Sivash, V.S. Borodkin,;1; Magnesium-base alloy for use in bone surgery, United States Patent US 3687135 (1972). – volume: 142 start-page: 3320 year: 1995 ident: bib0070 article-title: Morphology and structure of oxide films formed on magnesium by exposure to air and water publication-title: Journal of The Electrochemical Society – volume: 155 start-page: C340 year: 2008 ident: bib0065 article-title: Localized corrosion of magnesium in chloride-containing electrolyte studied by a scanning vibrating electrode technique publication-title: Journal of The Electrochemical Society – volume: 51 start-page: 1733 year: 2009 ident: bib0035 article-title: Corrosion of magnesium and its alloys publication-title: Corrosion Science – volume: 89 start-page: 651 year: 2003 ident: 10.1016/j.electacta.2012.03.040_bib0080 article-title: Biocorrosion of magnesium alloys: a new principle in cardiovascular implant technology? publication-title: Heart doi: 10.1136/heart.89.6.651 – volume: 52 start-page: 579 year: 2010 ident: 10.1016/j.electacta.2012.03.040_bib0115 article-title: Measurement of the corrosion rate of magnesium alloys using Tafel extrapolation publication-title: Corrosion Science doi: 10.1016/j.corsci.2009.10.016 – volume: 154 start-page: C108 year: 2007 ident: 10.1016/j.electacta.2012.03.040_bib0140 article-title: An impedance investigation of the mechanism of pure magnesium corrosion in sodium sulfate solutions publication-title: Journal of The Electrochemical Society doi: 10.1149/1.2401056 – volume: 56 start-page: 3790 year: 2011 ident: 10.1016/j.electacta.2012.03.040_bib0020 article-title: Electrochemical impedance spectroscopic investigation of the role of alkaline pre-treatment in corrosion resistance of a silane coating on magnesium alloy, ZE41 publication-title: Electrochimica Acta doi: 10.1016/j.electacta.2011.02.050 – volume: 105 start-page: 245 year: 1958 ident: 10.1016/j.electacta.2012.03.040_bib0055 article-title: Corrosion of anodically and cathodically polarized magnesium in aqueous media publication-title: Journal of The Electrochemical Society doi: 10.1149/1.2428817 – volume: 31 start-page: 81 year: 1993 ident: 10.1016/j.electacta.2012.03.040_bib0105 article-title: Osmol gaps revisited: normal values and limitations publication-title: Clinical Toxicology doi: 10.3109/15563659309000375 – volume: 46 start-page: 107 year: 2003 ident: 10.1016/j.electacta.2012.03.040_bib0015 article-title: Electrochemical impedance spectroscopy evaluation of the corrosion behaviour of Mg alloy coated with PECVD organosilicon thin film publication-title: Progress in Organic Coatings doi: 10.1016/S0300-9440(02)00217-5 – volume: 10 start-page: 259 year: 2008 ident: 10.1016/j.electacta.2012.03.040_bib0060 article-title: Monitoring local spatial distribution of Mg2+, pH and ionic currents publication-title: Electrochemistry Communications doi: 10.1016/j.elecom.2007.12.003 – volume: 51 start-page: 107 year: 1974 ident: 10.1016/j.electacta.2012.03.040_bib0040 article-title: The potential-pH diagram of the magnesium–water system publication-title: Journal of Electroanalytical Chemistry and Interfacial Electrochemistry doi: 10.1016/S0022-0728(74)80298-6 – volume: 90A start-page: 487 year: 2009 ident: 10.1016/j.electacta.2012.03.040_bib0085 article-title: Degradation of magnesium and its alloys: dependence on the composition of the synthetic biological media publication-title: Journal of Biomedical Materials Research Part A doi: 10.1002/jbm.a.32106 – volume: 63 start-page: 103 year: 1996 ident: 10.1016/j.electacta.2012.03.040_bib0145 article-title: On the corrosion behaviour of magnesium and its alloys using electrochemical techniques publication-title: Journal of Power Sources doi: 10.1016/S0378-7753(96)02456-1 – volume: 142 start-page: 3320 year: 1995 ident: 10.1016/j.electacta.2012.03.040_bib0070 article-title: Morphology and structure of oxide films formed on magnesium by exposure to air and water publication-title: Journal of The Electrochemical Society doi: 10.1149/1.2049981 – volume: 51 start-page: 1733 year: 2009 ident: 10.1016/j.electacta.2012.03.040_bib0035 article-title: Corrosion of magnesium and its alloys publication-title: Corrosion Science doi: 10.1016/j.corsci.2009.04.025 – volume: 53 start-page: 226 year: 2011 ident: 10.1016/j.electacta.2012.03.040_bib0120 article-title: An innovative specimen configuration for the study of Mg corrosion publication-title: Corrosion Science doi: 10.1016/j.corsci.2010.09.016 – volume: 26 start-page: 3557 year: 2005 ident: 10.1016/j.electacta.2012.03.040_bib0090 article-title: In vivo corrosion of four magnesium alloys and the associated bone response publication-title: Biomaterials doi: 10.1016/j.biomaterials.2004.09.049 – volume: 6 start-page: 127 year: 1992 ident: 10.1016/j.electacta.2012.03.040_bib0125 article-title: Kinetics of the hydrolysis and condensation of organofunctional alkoxysilanes: a review publication-title: Journal of Adhesion Science and Technology doi: 10.1163/156856192X00106 – volume: 47 start-page: 2816 year: 2005 ident: 10.1016/j.electacta.2012.03.040_bib0150 article-title: Electrochemical behavior of anodized Mg alloy AZ91D in chloride containing aqueous solution publication-title: Corrosion Science doi: 10.1016/j.corsci.2005.01.010 – volume: 5 start-page: 837 year: 2003 ident: 10.1016/j.electacta.2012.03.040_bib0050 article-title: Understanding magnesium corrosion – a framework for improved alloy performance publication-title: Advanced Engineering Materials doi: 10.1002/adem.200310405 – volume: 52–54 start-page: 1947 year: 2011 ident: 10.1016/j.electacta.2012.03.040_bib0130 article-title: Effects of cure temperature on corrosion property of vinyltriethoxysilane films on carbon steel surfaces publication-title: Applied Mechanics and Materials doi: 10.4028/www.scientific.net/AMM.52-54.1947 – volume: 148 start-page: B489 year: 2001 ident: 10.1016/j.electacta.2012.03.040_bib0135 article-title: AC impedance spectroscopy in characterizing time-dependent corrosion of AZ91 and AM50 magnesium alloys characterization with respect to their microstructures publication-title: Journal of The Electrochemical Society doi: 10.1149/1.1415722 – volume: 157 start-page: C238 year: 2010 ident: 10.1016/j.electacta.2012.03.040_bib0075 article-title: Influence of test solutions on in vitro studies of biomedical magnesium alloys publication-title: Journal of The Electrochemical Society doi: 10.1149/1.3421651 – volume: 39 start-page: 855 year: 1997 ident: 10.1016/j.electacta.2012.03.040_bib0045 article-title: The electrochemical corrosion of pure magnesium in 1 N NaCl publication-title: Corrosion Science doi: 10.1016/S0010-938X(96)00172-2 – volume: 66 start-page: 590 year: 2005 ident: 10.1016/j.electacta.2012.03.040_bib0095 article-title: First successful implantation of a biodegradable metal stent into the left pulmonary artery of a preterm baby publication-title: Catheterization and Cardiovascular Interventions doi: 10.1002/ccd.20520 – volume: 50 start-page: 3168 year: 2008 ident: 10.1016/j.electacta.2012.03.040_bib0110 article-title: Influence of pH and chloride ion concentration on the corrosion of Mg alloy ZE41 publication-title: Corrosion Science doi: 10.1016/j.corsci.2008.08.023 – volume: 72 start-page: 739 year: 2011 ident: 10.1016/j.electacta.2012.03.040_bib0030 article-title: Corrosion behavior study of AZ91 magnesium alloy coated with methyltriethoxysilane doped with cerium ions publication-title: Progress in Organic Coatings doi: 10.1016/j.porgcoat.2011.08.005 – volume: 27 start-page: 1728 year: 2006 ident: 10.1016/j.electacta.2012.03.040_bib0005 article-title: Magnesium and its alloys as orthopedic biomaterials: a review publication-title: Biomaterials doi: 10.1016/j.biomaterials.2005.10.003 – ident: 10.1016/j.electacta.2012.03.040_bib0100 – volume: 155 start-page: C340 year: 2008 ident: 10.1016/j.electacta.2012.03.040_bib0065 article-title: Localized corrosion of magnesium in chloride-containing electrolyte studied by a scanning vibrating electrode technique publication-title: Journal of The Electrochemical Society doi: 10.1149/1.2918900 – volume: 12 start-page: 22 year: 2009 ident: 10.1016/j.electacta.2012.03.040_bib0010 article-title: Revolutionizing biodegradable metals publication-title: Materials Today doi: 10.1016/S1369-7021(09)70273-1 – volume: 514 start-page: 174 year: 2006 ident: 10.1016/j.electacta.2012.03.040_bib0025 article-title: Sol–gel coatings with phosphonate functionalities for surface modification of magnesium alloys publication-title: Thin Solid Films doi: 10.1016/j.tsf.2006.02.023
SSID	ssj0007670
Score	2.1320248
Snippet	Electrochemical impedance spectroscopy (EIS), open circuit potential and pH changes were used to examine the corrosion of magnesium 4% yttrium alloy (Mg4Y)...
SourceID	proquest pascalfrancis crossref elsevier
SourceType	Aggregation Database Index Database Enrichment Source Publisher
StartPage	165
SubjectTerms	Applied sciences Corrosion Corrosion mechanisms Corrosion tests EIS Electrochemical impedance spectroscopy Exact sciences and technology Magnesium Magnesium base alloys Metals. Metallurgy Open circuit potential Yttrium base alloys
Title	Corrosion of organosilane coated Mg4Y alloy in sodium chloride solution evaluated by impedance spectroscopy and pH changes
URI	https://dx.doi.org/10.1016/j.electacta.2012.03.040 https://www.proquest.com/docview/1038262151
Volume	70
WOSCitedRecordID	wos000304497000023&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D
hasFullText	1
inHoldings	1
isFullTextHit
isPrint
journalDatabaseRights	– providerCode: PRVESC databaseName: Elsevier SD Freedom Collection Journals 2021 customDbUrl: eissn: 1873-3859 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0007670 issn: 0013-4686 databaseCode: AIEXJ dateStart: 19950101 isFulltext: true titleUrlDefault: https://www.sciencedirect.com providerName: Elsevier
link	http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwtV1bb9MwFLZKhwQIIRggxmUyEuKlCsrFiRPeqq5TQaXw0Entk5U4Du20xaFtpomfwS_mOLazVgNtPPASpWmuPV_P-WKfcz6E3gXgd3mY5U5B48whqntrmhC1BlwEQgR1daHwmE4m8WyWfOt0ftlamIszWpbx5WVS_VdTwzYwtiqd_QdztyeFDbAORoclmB2WtzL8QK4g8hke2Ig2wSeV0trjMlX88st3Mu-p-fam5G8t82V93uMLlYqXi569OdsHXDPUJbDrvKkuaEozVQtMWenWTdXIVA-vd0b5tbwOXyxVPwLVsqP1_0dSVDolqH8uW0o_q5tNRxBK-aK-wuy8bvziXMiFqE2Y1QJhUuqpJzNkZCa4zAiGSgUJ7WSM8cpe4JDItMQ2XlnLiRi36mk9CROhPf3dNeevxyFOPzQCQuq5VOae3_Sw1S2hdtttT76y45PxmE2Hs-n76oejlMjUjL2RZbmD9nwaJnEX7fU_DWef2_hOI-paXQx11ztZg3-89t84z8MqXcM_sdASKtfYQENxpo_RI_NugvsaU09QR5T76N7ASgLuowdb3Sufop8t0rAs8DbSsEYaVkjDDdLwssQaadgiDVuk4RZpOIMdLdLwNtIwIA1XI2yQ9gydHA-ng5FjpDwcHtB44yTwIkIiPyVRHoapGxaEkoyTrEh9UQRJDgxJxF5EuchyqmJIEfgeF16UhpwkIgqeo24pS_EC4SzIkyKnRZpncI4wyPIiSFM_AabpkyKKD1Bkf2zGTZ97JbdyxmxC4ylrrcSUlZgbMLDSAXLbAyvd6uXmQz5aazLDWDUTZYDJmw8-3LF_e1E_jAFiBJ7krQUEA0OrmTwwoazXTKka-JFi6y9vsc8rdP_qb_cadTerWrxBd_nFZrleHRp4_wZFtNY0
linkProvider	Elsevier
openUrl	ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Corrosion+of+organosilane+coated+Mg4Y+alloy+in+sodium+chloride+solution+evaluated+by+impedance+spectroscopy+and+pH+changes&rft.jtitle=Electrochimica+acta&rft.au=Doepke%2C+Amos&rft.au=Xue%2C+Dingchuan&rft.au=Yun%2C+Yeoheung&rft.au=Vanooij%2C+William+J&rft.date=2012-05-30&rft.issn=0013-4686&rft.volume=70&rft.spage=165&rft.epage=170&rft_id=info:doi/10.1016%2Fj.electacta.2012.03.040&rft.externalDBID=NO_FULL_TEXT
thumbnail_l	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0013-4686&client=summon
thumbnail_m	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0013-4686&client=summon
thumbnail_s	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0013-4686&client=summon