Quantum Monte Carlo estimation of complex-time correlations for the study of the ground-state dynamic structure function

We present a method based on the path integral Monte Carlo formalism for the calculation of ground-state time correlation functions in quantum systems. The key point of the method is the consideration of time as a complex variable whose phase δ acts as an adjustable parameter. By using high-order ap...

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Vydáno v:The Journal of chemical physics Ročník 142; číslo 11; s. 114114
Hlavní autoři: Rota, R, Casulleras, J, Mazzanti, F, Boronat, J
Médium: Journal Article
Jazyk:angličtina
Vydáno: United States 21.03.2015
ISSN:1089-7690
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Shrnutí:We present a method based on the path integral Monte Carlo formalism for the calculation of ground-state time correlation functions in quantum systems. The key point of the method is the consideration of time as a complex variable whose phase δ acts as an adjustable parameter. By using high-order approximations for the quantum propagator, it is possible to obtain Monte Carlo data all the way from purely imaginary time to δ values near the limit of real time. As a consequence, it is possible to infer accurately the spectral functions using simple inversion algorithms. We test this approach in the calculation of the dynamic structure function S(q, ω) of two one-dimensional model systems, harmonic and quartic oscillators, for which S(q, ω) can be exactly calculated. We notice a clear improvement in the calculation of the dynamic response with respect to the common approach based on the inverse Laplace transform of the imaginary-time correlation function.
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ISSN:1089-7690
DOI:10.1063/1.4914995