DFT Investigation of the Molecular Properties of the Dimethylglyoximato Complexes [M(Hdmg)2] (M = Ni, Pd, Pt)

Important applications of the NiII, PdII and PtII complexes [M(Hdmg)2] (H2dmg = dimethylglyoxime) stem from their metal...metal stacked virtually insoluble aggregates. Given the virtual insolubility of the materials, we postulated that the rare reports on dissolved species in solution do not represe...

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Vydané v:Inorganics Ročník 9; číslo 6; s. 47
Hlavní autori: Niazi, Maryam, Klein, Axel
Médium: Journal Article
Jazyk:English
Vydavateľské údaje: Basel MDPI AG 07.06.2021
Predmet:
Biological effects
Charge transfer
Density functional theory
DFT
Dimethyl sulfoxide
dimethylglyoxime
Hydrogen bonds
Ligands
Metals
Molecular properties
NiII
Oligomers
Palladium
PdII
Platinum
PtII
Rare species
Solvents
Spectra
ISSN:2304-6740, 2304-6740
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Abstract Important applications of the NiII, PdII and PtII complexes [M(Hdmg)2] (H2dmg = dimethylglyoxime) stem from their metal...metal stacked virtually insoluble aggregates. Given the virtual insolubility of the materials, we postulated that the rare reports on dissolved species in solution do not represent monomolecular species but oligomers. We thus studied the structural and spectral properties of the monomolecular entities of these compounds using density functional theory (DFT) and time-dependent DFT computations in dimethyl sulfoxide (DMSO) as a solvent. The molecular geometries, IR and UV-vis spectra, and frontier orbitals properties were computed using LANL2DZ ecp and def2TZVP as basis sets and M06-2X as the functional. The results are compared with the available experimental and other calculated data. The optimised molecular geometries proved the asymmetric character of the two formed O–H…O bonds which connect the two Hdmg‒ ligands in the completely planar molecules. Calculated UV-vis spectra revealed the presence of three absorptions in the range 180 to 350 nm that are red-shifted along the series Ni–Pd–Pt. They were assigned to essentially ligand-centred π−π* transitions in part with metal(d) to ligand(π*) charge transfer (MLCT) contributions. The notorious d‒p transitions dominating the colour and electronics of the compounds in the solid-state and oligomeric stacks are negligible in our monomolecular models strongly supporting the idea that the previously reported spectroscopic observations or biological effects in solutions are not due to monomolecular complexes but rather to oligomeric dissolved species.
AbstractList Important applications of the NiII, PdII and PtII complexes [M(Hdmg)2] (H2dmg = dimethylglyoxime) stem from their metal...metal stacked virtually insoluble aggregates. Given the virtual insolubility of the materials, we postulated that the rare reports on dissolved species in solution do not represent monomolecular species but oligomers. We thus studied the structural and spectral properties of the monomolecular entities of these compounds using density functional theory (DFT) and time-dependent DFT computations in dimethyl sulfoxide (DMSO) as a solvent. The molecular geometries, IR and UV-vis spectra, and frontier orbitals properties were computed using LANL2DZ ecp and def2TZVP as basis sets and M06-2X as the functional. The results are compared with the available experimental and other calculated data. The optimised molecular geometries proved the asymmetric character of the two formed O–H…O bonds which connect the two Hdmg‒ ligands in the completely planar molecules. Calculated UV-vis spectra revealed the presence of three absorptions in the range 180 to 350 nm that are red-shifted along the series Ni–Pd–Pt. They were assigned to essentially ligand-centred π−π* transitions in part with metal(d) to ligand(π*) charge transfer (MLCT) contributions. The notorious d‒p transitions dominating the colour and electronics of the compounds in the solid-state and oligomeric stacks are negligible in our monomolecular models strongly supporting the idea that the previously reported spectroscopic observations or biological effects in solutions are not due to monomolecular complexes but rather to oligomeric dissolved species.
Author Niazi, Maryam
Klein, Axel
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  surname: Klein
  fullname: Klein, Axel
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Cites_doi 10.1021/acs.inorgchem.9b00403
10.1016/S0020-1693(00)94658-9
10.1063/1.451839
10.1016/j.jcat.2020.05.013
10.1007/s00214-007-0310-x
10.1021/cm990224k
10.1021/ic50055a013
10.1021/jacs.0c12568
10.1016/0020-1650(70)80216-1
10.20964/2016.09.47
10.1021/acs.inorgchem.7b00796
10.1039/D1DT00272D
10.1021/acs.organomet.0c00015
10.1246/bcsj.63.3686
10.1039/c3nr01578e
10.2183/pjab.68.57
10.1021/ic00238a025
10.1021/ed049p227
10.1107/S0567740879004313
10.1021/ic50093a034
10.1021/ct8000409
10.1038/s41598-021-86060-1
10.1016/0584-8539(71)80221-0
10.1021/ja01512a066
10.1021/om9000499
10.1016/S0022-2313(99)00334-8
10.1039/CS9720100099
10.1080/00958970902852926
10.1107/S0365110X60002193
10.1007/s13738-020-01912-3
10.1039/D0DT02237C
10.1016/0022-328X(87)85041-6
10.1021/om400812w
10.1016/S0020-1693(02)01375-0
10.1039/jm9910101041
10.1016/S0379-6779(96)04515-8
10.1039/C9CP05603C
10.1088/1742-6596/215/1/012065
10.1246/bcsj.65.1078
10.1039/D0CC01254H
10.1021/acs.inorgchem.8b00724
10.1063/1.1700787
10.1039/D0RA09240A
10.1063/1.1480445
10.1016/j.jorganchem.2006.05.028
10.1016/0584-8539(80)80086-9
10.1246/bcsj.51.3257
10.1063/1.448975
10.1063/1.448799
10.1002/adfm.202004208
10.1021/ic50020a005
10.1016/j.jorganchem.2007.08.024
10.1016/S0020-1693(03)00364-5
10.1021/jp508939g
10.1107/S0365110X5300137X
10.1039/jr9570000281
10.1134/S1070363214120111
10.1107/S0108768188012285
10.1016/0379-6779(94)03023-Y
10.1016/j.optmat.2005.05.001
10.1002/ejic.200400524
10.1016/j.comptc.2017.05.022
10.1021/acs.inorgchem.1c00680
10.1039/C6DT02328B
10.1107/S0365110X59002870
10.1016/0022-1902(65)80208-1
10.1016/j.apcata.2017.07.033
10.1021/acs.jpca.9b06762
10.1016/j.ica.2020.120093
10.1021/cm980286v
10.1002/adfm.202000534
10.1002/1521-3773(20020104)41:1<48::AID-ANIE48>3.0.CO;2-U
10.1021/ic00295a020
10.1016/j.electacta.2008.07.080
10.1021/ac3003352
10.1016/0022-328X(84)80478-7
10.1016/0039-9140(66)80195-9
10.1080/15421400600598412
10.1007/s10967-014-3707-8
10.1016/j.poly.2014.11.013
10.1039/b508541a
10.1063/1.112046
10.1063/1.474671
10.1107/S0365110X67003391
10.1016/j.apsusc.2019.02.071
10.1107/S1600536803024656
10.1039/C8NJ04195D
10.1021/acs.cgd.0c00913
10.1039/JR9580004536
10.1039/D0AN02200D
10.1016/j.ica.2005.03.026
10.2174/187794410501150630184338
10.1039/C6AN00926C
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References Ali (ref_1) 2019; 123
Kurz (ref_58) 2021; 143
Takeda (ref_28) 2006; 460
Kohler (ref_90) 1984; 272
Dong (ref_43) 2019; 479
Yuan (ref_41) 2020; 30
Rundle (ref_84) 1952; 20
Shirotani (ref_29) 1992; 65
Zakharov (ref_4) 2014; 118
Godycki (ref_24) 1953; 6
Wang (ref_42) 2020; 30
Kamata (ref_51) 1995; 71
Dakhel (ref_45) 2006; 691
Shirotani (ref_30) 1991; 1
(ref_87) 2003; 651–653
Suzuki (ref_47) 1990; 63
Dey (ref_80) 2004; 22
Kamata (ref_50) 1996; 83
Garbe (ref_61) 2020; 39
Hussain (ref_13) 1979; 35
Nishida (ref_93) 1979; 34
Nagakura (ref_57) 1970; 9
ref_68
Thomas (ref_9) 1972; 1
ref_23
Shirotani (ref_27) 1992; 68
ref_21
ref_65
Frasson (ref_18) 1960; 13
Mirhashemi (ref_33) 2020; 17
Bigotto (ref_89) 1971; 27
Qi (ref_37) 2020; 389
Huheey (ref_82) 1972; 49
Iwai (ref_48) 2000; 87–89
Patra (ref_2) 2017; 1114
Frasson (ref_20) 1959; 12
Kar (ref_78) 2016; 45
Phadnis (ref_81) 2003; 346
Kluge (ref_55) 2013; 32
Friese (ref_62) 2020; 22
Krause (ref_66) 2021; 518
Heil (ref_60) 2019; 58
Hay (ref_75) 1985; 82
Yoshida (ref_7) 2020; 20
Zhao (ref_71) 2008; 120
Feng (ref_40) 2013; 5
Roy (ref_73) 2008; 4
Weigend (ref_72) 2005; 7
Casarin (ref_6) 1988; 27
Orel (ref_86) 1980; 36
Huila (ref_22) 2012; 84
Potocny (ref_77) 2017; 56
Martin (ref_15) 1998; 10
Phadnis (ref_79) 2005; 358
Biancalana (ref_54) 2018; 42
Berkefeld (ref_59) 2020; 56
Cossi (ref_70) 2002; 117
Ferraro (ref_31) 1970; 6
Mews (ref_63) 2020; 49
Kordatos (ref_44) 2009; 54
Benoit (ref_53) 2021; 11
Barone (ref_69) 1997; 107
Andris (ref_35) 2015; 304
Titova (ref_39) 2014; 84
Hay (ref_76) 1985; 82
Caton (ref_16) 1966; 13
Yang (ref_52) 2016; 141
Burger (ref_17) 1965; 27
Rohlfing (ref_74) 1986; 85
Konno (ref_12) 1989; 45
Pokol (ref_88) 2009; 62
Tauzher (ref_10) 2003; 355
Olorundare (ref_34) 2016; 11
Liu (ref_3) 2015; 87
Yoshida (ref_91) 1978; 51
Kaim (ref_94) 1987; 321
Poirier (ref_67) 2018; 57
Schwieger (ref_56) 2009; 28
Kamata (ref_49) 1994; 65
Steiner (ref_83) 2002; 41
Kamnoet (ref_32) 2021; 146
Murmann (ref_14) 1967; 23
Manuta (ref_95) 1986; 25
Kovacs (ref_5) 2007; 692
Dakhel (ref_46) 2006; 28
Haseloer (ref_64) 2021; 50
Basu (ref_92) 1964; 3
Williams (ref_19) 1959; 81
Li (ref_11) 2003; 59
Takeda (ref_8) 2010; 215
Takeda (ref_26) 2000; 12
Ma (ref_36) 2021; 11
Gerasimchuk (ref_25) 2015; 5
Caton (ref_85) 1967; 6
Sarkar (ref_38) 2017; 545
References_xml – volume: 58
  start-page: 6123
  year: 2019
  ident: ref_60
  article-title: Structure—Emission Property Relationships in Cyclometalated Pt(II) β-Diketonate Complexes
  publication-title: Inorg. Chem.
  doi: 10.1021/acs.inorgchem.9b00403
– volume: 34
  start-page: L273
  year: 1979
  ident: ref_93
  article-title: Resonance raman spectra of [Ni(dmg)2], [Pd(dmg)2] and [Pt(dmg)2] in the solid state (dmgH = dimethylglyoxime)
  publication-title: Inorg. Chim. Acta
  doi: 10.1016/S0020-1693(00)94658-9
– volume: 85
  start-page: 1447
  year: 1986
  ident: ref_74
  article-title: An effective core potential investigation of Ni, Pd, and Pt and their monohydrides
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.451839
– volume: 389
  start-page: 29
  year: 2020
  ident: ref_37
  article-title: Active Nickel Derived from Coordination Complex with Weak Inter/Intra-molecular Interactions for Efficient Hydrogen Evolution via a Tandem Mechanism
  publication-title: J. Catal.
  doi: 10.1016/j.jcat.2020.05.013
– volume: 120
  start-page: 215
  year: 2008
  ident: ref_71
  article-title: The M06 suite of density functionals for main group thermochemistry, thermochemical kinetics, noncovalent interactions, excited states, and transition elements: Two new functionals and systematic testing of four M06-class functionals and 12 other functionals
  publication-title: Theor. Chem. Acc.
  doi: 10.1007/s00214-007-0310-x
– volume: 12
  start-page: 912
  year: 2000
  ident: ref_26
  article-title: Pressure-Induced Insulator-to-Metal-to-Insulator Transitions in One-Dimensional Bis(dimethylglyoximato)platinum(II), Pt(dmg)2
  publication-title: Chem. Mater.
  doi: 10.1021/cm990224k
– volume: 6
  start-page: 1670
  year: 1967
  ident: ref_85
  article-title: Hydrogen bonding in some copper(II) and nickel(II) vic-dioximes
  publication-title: Inorg. Chem.
  doi: 10.1021/ic50055a013
– volume: 143
  start-page: 3466
  year: 2021
  ident: ref_58
  article-title: A Flu-orescence-Detected Coordination-Induced Spin State Switch
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/jacs.0c12568
– ident: ref_68
– volume: 6
  start-page: 823
  year: 1970
  ident: ref_31
  article-title: Some possible new internal pressure calibrants
  publication-title: Inorg. Nucl. Chem. Lett.
  doi: 10.1016/0020-1650(70)80216-1
– volume: 11
  start-page: 7318
  year: 2016
  ident: ref_34
  article-title: Voltammetric Determination of Nitrophenols at a Nickel Dimethylglyoxime Complex—Gold Nanoparticle Modified Glassy Carbon Electrode
  publication-title: Int. J. Electrochem. Sci.
  doi: 10.20964/2016.09.47
– volume: 56
  start-page: 12703
  year: 2017
  ident: ref_77
  article-title: Electrochemical, Spectroscopic, and 1O2 Sensitization Characteristics of Synthetically Accessible Linear Tetrapyrrole Complexes of Palladium and Platinum
  publication-title: Inorg. Chem.
  doi: 10.1021/acs.inorgchem.7b00796
– volume: 50
  start-page: 4311
  year: 2021
  ident: ref_64
  article-title: Ni, Pd, and Pt complexes of a tetradentate dianionic thiosemicarbazone-based O^N^N^S ligand
  publication-title: Dalton Trans.
  doi: 10.1039/D1DT00272D
– volume: 39
  start-page: 746
  year: 2020
  ident: ref_61
  article-title: Cyclometalated Pt Complexes of CNC Pincer Ligands: Luminescence and Cytotoxic Properties
  publication-title: Organometallics
  doi: 10.1021/acs.organomet.0c00015
– volume: 63
  start-page: 3686
  year: 1990
  ident: ref_47
  article-title: Vacuum Sublimation Behavior of Nickel(II), Palladium(II), and Platinum(II) Chelates with Dimethylglyoxime
  publication-title: Bull. Chem. Soc. Jpn.
  doi: 10.1246/bcsj.63.3686
– volume: 5
  start-page: 6754
  year: 2013
  ident: ref_40
  article-title: Facile synthesis of porous worm-like Pd nanotubes with high electrocatalytic activity and stability towards ethylene glycol oxidation
  publication-title: Nanoscale
  doi: 10.1039/c3nr01578e
– volume: 68
  start-page: 57
  year: 1992
  ident: ref_27
  article-title: Pressure-sensitive Optical Properties of Bis(1,2-dionedioximato)-Palladium(II) Complexes
  publication-title: Proc. Jpn. Acad. Ser. B
  doi: 10.2183/pjab.68.57
– volume: 25
  start-page: 3212
  year: 1986
  ident: ref_95
  article-title: Solvatochromism of the Metal to Ligand Charge-Transfer Transitions of Zerovalent Tungsten Carbonyl Complexes
  publication-title: Inorg. Chem.
  doi: 10.1021/ic00238a025
– volume: 49
  start-page: 227
  year: 1972
  ident: ref_82
  article-title: Anomalous properties of elements that follow “long periods” of elements
  publication-title: J. Chem. Educ.
  doi: 10.1021/ed049p227
– volume: 35
  start-page: 628
  year: 1979
  ident: ref_13
  article-title: Three-dimensional determinations of the crystal structures of bis(dimethylglyoximato)palladium(II) and bis(dimethylglyoximato)platinum(II)
  publication-title: Acta Crystallogr. Sect. B Struct. Crystallogr. Cryst. Chem.
  doi: 10.1107/S0567740879004313
– volume: 9
  start-page: 2551
  year: 1970
  ident: ref_57
  article-title: Spectroscopic study of the interaction between the central metal ions in the crystals of bis(dimethylglyoximato)nickel(II) and related complexes
  publication-title: Inorg. Chem.
  doi: 10.1021/ic50093a034
– volume: 4
  start-page: 1029
  year: 2008
  ident: ref_73
  article-title: Revised Basis Sets for the LANL Effective Core Potentials
  publication-title: J. Chem. Theory Comput.
  doi: 10.1021/ct8000409
– volume: 11
  start-page: 1
  year: 2021
  ident: ref_53
  article-title: The nickel-chelator dimethylglyoxime inhibits human amyloid beta peptide in vitro aggregation
  publication-title: Sci. Rep.
  doi: 10.1038/s41598-021-86060-1
– volume: 27
  start-page: 1659
  year: 1971
  ident: ref_89
  article-title: Infrared spectra of transition metal glyoximates
  publication-title: Spectrochim. Acta Part A Mol. Spectrosc.
  doi: 10.1016/0584-8539(71)80221-0
– volume: 81
  start-page: 755
  year: 1959
  ident: ref_19
  article-title: Crystal Structures of Nickel And Palladium Dimethylglyoximes
  publication-title: J. Am. Chem. Soc.
  doi: 10.1021/ja01512a066
– volume: 651–653
  start-page: 547
  year: 2003
  ident: ref_87
  article-title: Vibrational analysis of the bis(dimethylglyoximato)nickel(II) complex
  publication-title: J. Mol. Struct.
– volume: 28
  start-page: 2485
  year: 2009
  ident: ref_56
  article-title: A Bis(acetyl)-Bridged Platinum(II) Coordination Polymer as a Building Block for Diacetylplatinum(II) Complexes and Platina-β-diketones
  publication-title: Organometallics
  doi: 10.1021/om9000499
– volume: 87–89
  start-page: 629
  year: 2000
  ident: ref_48
  article-title: Wavepacket motion during thermalization of self-trapped exciton driven by an intramolecular vibration in one-dimensional platinum dimethylglyoxime complex
  publication-title: J. Lumin.
  doi: 10.1016/S0022-2313(99)00334-8
– volume: 1
  start-page: 99
  year: 1972
  ident: ref_9
  article-title: Metal–metal interactions in transition-metal complexes containing infinite chains of metal atoms
  publication-title: Chem. Soc. Rev.
  doi: 10.1039/CS9720100099
– volume: 62
  start-page: 2429
  year: 2009
  ident: ref_88
  article-title: Comparative spectral and thermal studies of [Pt(DioxH)2] chelates
  publication-title: J. Coord. Chem.
  doi: 10.1080/00958970902852926
– volume: 13
  start-page: 893
  year: 1960
  ident: ref_18
  article-title: X-ray studies on the metal complexes with the glyoximes. IV. Structure of Ni-methyl-ethyl-glyoxime
  publication-title: Acta Crystallogr.
  doi: 10.1107/S0365110X60002193
– volume: 17
  start-page: 2073
  year: 2020
  ident: ref_33
  article-title: Synthesis and evaluation of Fe3O4–Al2O3/SDS–DMG adsorbent for extraction and preconcentration of Pd(II) from real samples
  publication-title: J. Iran. Chem. Soc.
  doi: 10.1007/s13738-020-01912-3
– volume: 49
  start-page: 9735
  year: 2020
  ident: ref_63
  article-title: A four-parameter system for rationalising the electronic properties of transition metal–radical ligand complexes
  publication-title: Dalton Trans.
  doi: 10.1039/D0DT02237C
– volume: 321
  start-page: 215
  year: 1987
  ident: ref_94
  article-title: What determines the solvatochromism of metal-to-ligand charge transfer transitions? A demonstration involving 17 tungsten carbonyl complexes
  publication-title: J. Organomet. Chem.
  doi: 10.1016/0022-328X(87)85041-6
– volume: 32
  start-page: 7090
  year: 2013
  ident: ref_55
  article-title: Activation of Acetyl Ligands through Hydrogen Bonds: A New Way to Platinum(II) Complexes Bearing Protonated Imino-acetyl Ligands
  publication-title: Organometallics
  doi: 10.1021/om400812w
– volume: 346
  start-page: 119
  year: 2003
  ident: ref_81
  article-title: Configurational selectivity in benzyldimethylarsine complexes of palladium(II) and platinum(II): Synthesis, spectroscopy and structures
  publication-title: Inorg. Chim. Acta
  doi: 10.1016/S0020-1693(02)01375-0
– volume: 1
  start-page: 1041
  year: 1991
  ident: ref_30
  article-title: Pressure-sensitive absorption spectra of thin films of bis(diphenylglyoximato)platinum(II), Pt(dpg)2: Potential application as an indicator of pressure
  publication-title: J. Mater. Chem.
  doi: 10.1039/jm9910101041
– volume: 83
  start-page: 267
  year: 1996
  ident: ref_50
  article-title: Third-order nonlinear optical prop-erties of evaporated thin films of platinum-alkyldionedioxime complexes: Effects of metal—Metal distance
  publication-title: Synth. Met.
  doi: 10.1016/S0379-6779(96)04515-8
– volume: 22
  start-page: 3217
  year: 2020
  ident: ref_62
  article-title: On the photophysical properties of IrIII, PtII, and PdII (phenylpyrazole) (phenyldipyrrin) complexes
  publication-title: Phys. Chem. Chem. Phys.
  doi: 10.1039/C9CP05603C
– volume: 215
  start-page: 012065
  year: 2010
  ident: ref_8
  article-title: X-ray and optical studies of one-dimensional bis(dimethylglyoximato)Pd(II), Pd(dmg)2 at high pressures
  publication-title: J. Phys. Conf. Ser.
  doi: 10.1088/1742-6596/215/1/012065
– volume: 65
  start-page: 1078
  year: 1992
  ident: ref_29
  article-title: Absorption Spectra and Electrical Resistivities of Bis(1,2-dione dioximato)nickel(II) Complexes at High Pressures
  publication-title: Bull. Chem. Soc. Jpn.
  doi: 10.1246/bcsj.65.1078
– volume: 56
  start-page: 3987
  year: 2020
  ident: ref_59
  article-title: Selective metalation of phenol-type proligands for preparative organometallic chemistry
  publication-title: Chem. Commun.
  doi: 10.1039/D0CC01254H
– volume: 57
  start-page: 7713
  year: 2018
  ident: ref_67
  article-title: Variation of M·H–C Interactions in Square-Planar Complexes of Nickel(II), Palladium(II), and Platinum(II) Probed by Luminescence Spectroscopy and X-ray Diffraction at Variable Pressure
  publication-title: Inorg. Chem.
  doi: 10.1021/acs.inorgchem.8b00724
– volume: 20
  start-page: 1487
  year: 1952
  ident: ref_84
  article-title: O–H Stretching Frequencies in Very Short and Possibly Symmetrical Hydrogen Bonds
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.1700787
– volume: 11
  start-page: 5035
  year: 2021
  ident: ref_36
  article-title: Effective oil–water mixture separation and photocatalytic dye de-contamination through nickel-dimethylglyoxime microtubes coated superhydrophobic and superoleophilic films
  publication-title: RSC Adv.
  doi: 10.1039/D0RA09240A
– volume: 117
  start-page: 43
  year: 2002
  ident: ref_70
  article-title: New developments in the polarizable continuum model for quantum mechanical and classical calculations on molecules in solution
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.1480445
– volume: 691
  start-page: 3760
  year: 2006
  ident: ref_45
  article-title: Characterisation and ac-electrical investigation of sublimated bis(dimethylglyoximato)palladium(II) thin films
  publication-title: J. Organomet. Chem.
  doi: 10.1016/j.jorganchem.2006.05.028
– volume: 36
  start-page: 859
  year: 1980
  ident: ref_86
  article-title: Infrared and resonance enhanced Raman spectra of some metal vic-dioximes with short hydrogen bonds
  publication-title: Spectrochim. Acta Part A Mol. Spectrosc.
  doi: 10.1016/0584-8539(80)80086-9
– volume: 51
  start-page: 3257
  year: 1978
  ident: ref_91
  article-title: An X-Ray Photoelectron Spectroscopic Study of Dioxime Metal Complexes
  publication-title: Bull. Chem. Soc. Jpn.
  doi: 10.1246/bcsj.51.3257
– volume: 82
  start-page: 299
  year: 1985
  ident: ref_75
  article-title: Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitals
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.448975
– volume: 82
  start-page: 270
  year: 1985
  ident: ref_76
  article-title: Ab initio effective core potentials for molecular calculations. Potentials for the transition metal atoms Sc to Hg
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.448799
– volume: 30
  start-page: 2004208
  year: 2020
  ident: ref_41
  article-title: Engineering Surface Atomic Architecture of NiTe Nanocrystals Toward Efficient Electrochemical N2 Fixation
  publication-title: Adv. Funct. Mater.
  doi: 10.1002/adfm.202004208
– volume: 3
  start-page: 1361
  year: 1964
  ident: ref_92
  article-title: The Green Band of Crystalline Nickel Dimethylglyoxime. I. Mixed Crystals with Palladium, Platinum, and Copper and the Questions of Nonlocalized or d-p Transitions
  publication-title: Inorg. Chem.
  doi: 10.1021/ic50020a005
– volume: 692
  start-page: 5383
  year: 2007
  ident: ref_5
  article-title: Theoretical study of the strong intramolecular hydrogen bond and metal–ligand interactions in group 10 (Ni, Pd, Pt) bis(dimethylglyoximato) complexes
  publication-title: J. Organomet. Chem.
  doi: 10.1016/j.jorganchem.2007.08.024
– volume: 355
  start-page: 361
  year: 2003
  ident: ref_10
  article-title: Intramolecular and intermolecular O‒H‒O hydrogen bond in some nickel(II) complexes with tridentate amino‒oxime ligands
  publication-title: Inorg. Chim. Acta
  doi: 10.1016/S0020-1693(03)00364-5
– volume: 118
  start-page: 24705
  year: 2014
  ident: ref_4
  article-title: Structural Properties of Nickel Dimethylglyoxime at High Pressure: Single-Crystal X-ray Diffraction and DFT Studies
  publication-title: J. Phys. Chem. C
  doi: 10.1021/jp508939g
– volume: 6
  start-page: 487
  year: 1953
  ident: ref_24
  article-title: The structure of nickel dimethylglyoxime
  publication-title: Acta Crystallogr.
  doi: 10.1107/S0365110X5300137X
– ident: ref_23
  doi: 10.1039/jr9570000281
– volume: 84
  start-page: 2413
  year: 2014
  ident: ref_39
  article-title: Formation and properties of Ziegler systems based on nickel bis(dimethylglyoximate) in catalysis of hydrogenation reactions
  publication-title: Russ. J. Gen. Chem.
  doi: 10.1134/S1070363214120111
– volume: 45
  start-page: 142
  year: 1989
  ident: ref_12
  article-title: Structure changes and proton transfer between O...O in bis(dimethylglyoximato)platinum(II) at low temperature (150 K) and at high pressures (2.39 and 3.14 GPa)
  publication-title: Acta Crystallogr. Sect. B Struct. Sci.
  doi: 10.1107/S0108768188012285
– volume: 71
  start-page: 1725
  year: 1995
  ident: ref_51
  article-title: Third-order nonlinear optical properties of bis(dimethylglyoximato)metal(II)
  publication-title: Synth. Met.
  doi: 10.1016/0379-6779(94)03023-Y
– volume: 28
  start-page: 925
  year: 2006
  ident: ref_46
  article-title: Structural and optical studies of evaporated bis(dimethylglyoximato)nickel(II) thin films
  publication-title: Opt. Mater.
  doi: 10.1016/j.optmat.2005.05.001
– volume: 22
  start-page: 4510
  year: 2004
  ident: ref_80
  article-title: Structural Varieties in 1-Dimethylaminopropyl-2-chalcogenolate and 2-Dimethylaminopropyl-1-chalcogenolate (S, Se, Te) Complexes of Palladium(II) and Platinum(II): Synthesis, Spectroscopy and Structures
  publication-title: Eur. J. Inorg. Chem.
  doi: 10.1002/ejic.200400524
– volume: 1114
  start-page: 118
  year: 2017
  ident: ref_2
  article-title: On bonding in bis(dimethylglyoximato)nickel(II)
  publication-title: Comput. Theor. Chem.
  doi: 10.1016/j.comptc.2017.05.022
– ident: ref_65
  doi: 10.1021/acs.inorgchem.1c00680
– volume: 45
  start-page: 14080
  year: 2016
  ident: ref_78
  article-title: Colour tuning by the stepwise synthesis of mononuclear and homo- and hetero-dinuclear platinum(II) complexes using a zwitterionic quinonoid ligand
  publication-title: Dalton Trans.
  doi: 10.1039/C6DT02328B
– volume: 12
  start-page: 1027
  year: 1959
  ident: ref_20
  article-title: X-ray studies on the metal complexes with the glyoximes. II. Structure of the Pt-dimethylglyoxime
  publication-title: Acta Crystallogr.
  doi: 10.1107/S0365110X59002870
– volume: 27
  start-page: 179
  year: 1965
  ident: ref_17
  article-title: Some theoretical and practical problems in the use of organic reagents in chemical analysis—IV: Infra-red and ultra-violet spectrophotometric study of the dimethylglyoxime complexes of transition metals
  publication-title: J. Inorg. Nucl. Chem.
  doi: 10.1016/0022-1902(65)80208-1
– volume: 545
  start-page: 148
  year: 2017
  ident: ref_38
  article-title: Effective vacuum residue upgrading using sacrificial nickel(II) dimethylglyoxime complex in supercritical methanol
  publication-title: Appl. Catal A Gen.
  doi: 10.1016/j.apcata.2017.07.033
– volume: 123
  start-page: 9166
  year: 2019
  ident: ref_1
  article-title: Structural, Electronic, and Spectral Properties of Metal Dimethylglyoximato [M(DMG)2; M = Ni2+, Cu2+] Complexes: A Comparative Theoretical Study
  publication-title: J. Phys. Chem. A
  doi: 10.1021/acs.jpca.9b06762
– volume: 518
  start-page: 120093
  year: 2021
  ident: ref_66
  article-title: Platinum and palladium complexes of tridentate −C^N^N (phen-ide)-pyridine-thiazol ligands—A case study involving spectroelectrochemistry, photoluminescence spectroscopy and TD-DFT calculations
  publication-title: Inorg. Chim. Acta
  doi: 10.1016/j.ica.2020.120093
– volume: 10
  start-page: 2525
  year: 1998
  ident: ref_15
  article-title: Variations on Nickel Complexes of the vic-Dioximes: An Understanding of Factors Affecting Volatility toward Improved Precursors for Metal-Organic Chemical Vapor Deposition of Nickel
  publication-title: Chem. Mater.
  doi: 10.1021/cm980286v
– volume: 30
  start-page: 2000534
  year: 2020
  ident: ref_42
  article-title: Porous Pd‒PdO Nanotubes for Methanol Electrooxidation
  publication-title: Adv. Funct. Mater.
  doi: 10.1002/adfm.202000534
– volume: 41
  start-page: 48
  year: 2002
  ident: ref_83
  article-title: The Hydrogen Bond in the Solid State
  publication-title: Angew. Chem. Int. Ed.
  doi: 10.1002/1521-3773(20020104)41:1<48::AID-ANIE48>3.0.CO;2-U
– volume: 27
  start-page: 3993
  year: 1988
  ident: ref_6
  article-title: Electronic Structure of Tetracoordinate Transition-Metal Complexes. 2. Comparative Theoretical ab Initio/Hartree-Fock-Slater and UV-Photoelectron Spectroscopic Studies of Building Blocks for Low-Dimensional Conductors: Glyoximate Complexes of Palladium(II) and Platinum(II)
  publication-title: Inorg. Chem.
  doi: 10.1021/ic00295a020
– volume: 54
  start-page: 2466
  year: 2009
  ident: ref_44
  article-title: Synthesis of carbon nanotubes by pyrolysis of solid Ni(dmg)2
  publication-title: Electrochim. Acta
  doi: 10.1016/j.electacta.2008.07.080
– volume: 84
  start-page: 3067
  year: 2012
  ident: ref_22
  article-title: Unraveling the Mysterious Role of Palladium in Feigl bis(dimethylglyoximate)nickel(II) Spot Tests by Means of Confocal Raman Microscopy
  publication-title: Anal. Chem.
  doi: 10.1021/ac3003352
– volume: 272
  start-page: 337
  year: 1984
  ident: ref_90
  article-title: Bis(dimethylmetall(III)glyoximato)metallate(II) (metall(III) = Al, Ga, In, metall(II) = Ni, Pd, Pt, Cu)
  publication-title: J. Organomet. Chem.
  doi: 10.1016/0022-328X(84)80478-7
– volume: 13
  start-page: 967
  year: 1966
  ident: ref_16
  article-title: Studies of the spectra of copper dimethyl-glyoxime, nickel dimethylglyoxime and nickel ethylmethylglyoxime in various solvents
  publication-title: Talanta
  doi: 10.1016/0039-9140(66)80195-9
– volume: 460
  start-page: 131
  year: 2006
  ident: ref_28
  article-title: Structural, Optical, and Electrical Properties of One-Dimensional Bis(Dimethylglyoximato)nickel(II), Ni(dmg)2 at High Pressure
  publication-title: Mol. Cryst. Liq. Cryst.
  doi: 10.1080/15421400600598412
– volume: 304
  start-page: 123
  year: 2015
  ident: ref_35
  article-title: Rapid separation and determination of 107Pd in radioactive waste produced during NPP A-1 decommissioning
  publication-title: J. Radioanal. Nucl. Chem.
  doi: 10.1007/s10967-014-3707-8
– volume: 87
  start-page: 141
  year: 2015
  ident: ref_3
  article-title: Theoretical investigation of the pressure-induced insulator-to-metal-to-insulator transitions in one-dimensional bis(dimethylglyoximato) platinum(II), Pt(dmg)2
  publication-title: Polyhedron
  doi: 10.1016/j.poly.2014.11.013
– volume: 7
  start-page: 3297
  year: 2005
  ident: ref_72
  article-title: Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy
  publication-title: Phys. Chem. Chem. Phys.
  doi: 10.1039/b508541a
– volume: 65
  start-page: 1343
  year: 1994
  ident: ref_49
  article-title: Reversible control of the nonlinear optical activity of one-dimensional metal complexes
  publication-title: Appl. Phys. Lett.
  doi: 10.1063/1.112046
– volume: 107
  start-page: 3210
  year: 1997
  ident: ref_69
  article-title: A new definition of cavities for the computation of solvation free energies by the polarizable continuum model
  publication-title: J. Chem. Phys.
  doi: 10.1063/1.474671
– volume: 23
  start-page: 667
  year: 1967
  ident: ref_14
  article-title: On the crystal structure of bis(glyoximato)nickel(II)
  publication-title: Acta Crystallogr.
  doi: 10.1107/S0365110X67003391
– volume: 479
  start-page: 273
  year: 2019
  ident: ref_43
  article-title: Pd(II)/Ni(II)-dimethylglyoxime derived Pd‒Ni‒P@N-doped carbon hybrid nanocatalysts for oxygen reduction reaction
  publication-title: Appl. Surf. Sci.
  doi: 10.1016/j.apsusc.2019.02.071
– volume: 59
  start-page: m1094
  year: 2003
  ident: ref_11
  article-title: Redetermination of bis(dimethylglyoximato-[κ]2-N,N’)nickel(II)
  publication-title: Acta Crystallogr. Sect. E Struct. Rep. Online
  doi: 10.1107/S1600536803024656
– volume: 42
  start-page: 17453
  year: 2018
  ident: ref_54
  article-title: α-Diimine homologues of cisplatin: Synthesis, speciation in DMSO/water and cytotoxicity
  publication-title: New J. Chem.
  doi: 10.1039/C8NJ04195D
– volume: 20
  start-page: 7271
  year: 2020
  ident: ref_7
  article-title: Epitaxial Growth of Bis(dimethylglyoximato)platinum(II) Accompanied by Hole Formation
  publication-title: Cryst. Growth Des.
  doi: 10.1021/acs.cgd.0c00913
– ident: ref_21
  doi: 10.1039/JR9580004536
– volume: 146
  start-page: 2229
  year: 2021
  ident: ref_32
  article-title: Highly selective simultaneous determination of Cu(II), Co(II), Ni(II), Hg(II), and Mn(II) in water samples using microfluidic paper-based analytical de-vices
  publication-title: Analyst
  doi: 10.1039/D0AN02200D
– volume: 358
  start-page: 2609
  year: 2005
  ident: ref_79
  article-title: Synthesis, spectroscopy, structure and photophysical properties of dinaphthylmethylarsine complexes of palladium(II) and platinum(II)
  publication-title: Inorg. Chim. Acta
  doi: 10.1016/j.ica.2005.03.026
– volume: 5
  start-page: 3
  year: 2015
  ident: ref_25
  article-title: Editorial (Thematic Issue: Recent Advances in Chemistry and Applications of Oximes and their Metal Complexes: Part I)
  publication-title: Curr. Inorg. Chem.
  doi: 10.2174/187794410501150630184338
– volume: 141
  start-page: 5822
  year: 2016
  ident: ref_52
  article-title: A molecularly imprinted electrochemiluminescence sensor based on the mimetic enzyme catalytic effect for ultra-trace Ni2+ determination
  publication-title: Analyst
  doi: 10.1039/C6AN00926C
SSID ssj0000913838
Score 2.208727
Snippet Important applications of the NiII, PdII and PtII complexes [M(Hdmg)2] (H2dmg = dimethylglyoxime) stem from their metal...metal stacked virtually insoluble...
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Aggregation Database
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StartPage 47
SubjectTerms Biological effects
Charge transfer
Density functional theory
DFT
Dimethyl sulfoxide
dimethylglyoxime
Hydrogen bonds
Ligands
Metals
Molecular properties
NiII
Oligomers
Palladium
PdII
Platinum
PtII
Rare species
Solvents
Spectra
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Title DFT Investigation of the Molecular Properties of the Dimethylglyoximato Complexes [M(Hdmg)2] (M = Ni, Pd, Pt)
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https://doaj.org/article/1f5f0e5304614fcb9fec378992103abc
Volume 9
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