Synthesis and electrochemical study of iron, chromium and tungsten aminocarbenes: Role of ligand structure and central metal nature

Several series of Fischer-type aminocarbene complexes with central Fe, Cr or W atoms and with various carbene substitution were synthesized and electrochemically investigated by dc-polarography and cyclic voltammetry. The shifts and changes of reduction and oxidation potentials were evaluated using...

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Veröffentlicht in:	Electrochimica acta Jg. 55; H. 27; S. 8341 - 8351
Hauptverfasser:	Hoskovcová, Irena, Roháčová, Jana, Dvořák, Dalimil, Tobrman, Tomáš, Záliš, Stanislav, Zvěřinová, Radka, Ludvík, Jiří
Format:	Journal Article Tagungsbericht
Sprache:	Englisch
Veröffentlicht:	Kidlington Elsevier Ltd 30.11.2010 Elsevier
Schlagworte:	Carbenes Chemistry Chromium Electronics Exact sciences and technology Fischer aminocarbene complexes HOMO–LUMO displacement Iron LFER Ligands Molecular structure Orbitals Organic chemistry Organometalloidal and organometallic compounds Preparations and properties Reduction Structurally dependent redox properties Transition metals derivatives Voltammetry–polarography Voltammetry–polarography Fischer aminocarbene complexes LFER Structurally dependent redox properties HOMO–LUMO displacement Chromium Organic compounds Frontier orbital Chromium Carbonyl Complexes Orbital interaction Organic ligand Theoretical study Voltammetry Transition metal Carbonyl Complexes Tungsten Organic compounds Ylidene complex Iron Organic compounds Iron Carbonyl Complexes Electrochemical properties Polarography Aminocarbene Density functional method Property structure relationship HOMO-LUMO displacement Voltammetry-polarography Chemical synthesis Tungsten Carbonyl Complexes
ISSN:	0013-4686, 1873-3859
Online-Zugang:	Volltext
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