Photoinduced alkyl group exchange of ethylzinc alkoxides: X-ray crystal structure of an iodomethylzinc methoxide

Irradiation of a solution of ethyl zinc alkoxides and CH2I2 leads to clean formation of iodomethylzinc alkoxides; these intermediates are important species generated in stereoselective cyclopropanation processes; no alkyl group exchange is observed in the absence of irradiation; the solid-state stru...

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Vydané v:	Chemical communications (Cambridge, England) číslo 5; s. 466 - 467
Hlavní autori:	Charette, A, Beauchemin, A, Francoeur, S, Belanger-Gariepy, F, Enright, GD
Médium:	Journal Article
Jazyk:	English
Vydavateľské údaje:	CAMBRIDGE Royal Soc Chemistry 01.01.2002
Predmet:	Chemistry Chemistry, Multidisciplinary Physical Sciences Science & Technology DISULFONAMIDE CHIRAL ALLYLIC ALCOHOLS SIMMONS-SMITH CYCLOPROPANATION REAGENTS STEREOCONTROL SOLID-STATE STRUCTURE SYNTHETIC APPLICATIONS ENANTIOSELECTIVE CYCLOPROPANATION CYCLOPROPYLMETHANOL DERIVATIVES LIGAND
ISSN:	1359-7345
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