Catalytic valorization of glycerol to hydrogen and syngas
Glycerol, a byproduct derived from the production of biodiesel, is currently in an oversupply crisis worldwide. One approach to alleviate this problem is to transform glycerol into valuable chemicals such as hydrogen and syngas. Pyrolysis, steam reforming, partial oxidation, autothermal reforming, a...
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| Published in: | International journal of hydrogen energy Vol. 38; no. 6; pp. 2678 - 2700 |
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| Main Author: | |
| Format: | Journal Article |
| Language: | English |
| Published: |
Kidlington
Elsevier Ltd
27.02.2013
Elsevier |
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| ISSN: | 0360-3199, 1879-3487 |
| Online Access: | Get full text |
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| Abstract | Glycerol, a byproduct derived from the production of biodiesel, is currently in an oversupply crisis worldwide. One approach to alleviate this problem is to transform glycerol into valuable chemicals such as hydrogen and syngas. Pyrolysis, steam reforming, partial oxidation, autothermal reforming, and aqueous-phase reforming are promising routes for the catalytic conversion of glycerol. However, certain challenges are still limiting their development. Recent advances in catalyst design, reactor engineering, and theoretical chemistry have enabled us to understand glycerol valorization on macro- and microscopic scales, and may help overcome existing thresholds. With the synergistic efforts of these tools, glycerol may no longer be a burden, but a valuable resource of hydrogen and syngas in the near future.
► A review of glycerol conversion to hydrogen and syngas. ► Pyrolysis, steam reforming, partial oxidation, and aqueous-phase reforming. ► Computational studies provide in-depth understandings of glycerol valorization. |
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| AbstractList | Glycerol, a byproduct derived from the production of biodiesel, is currently in an oversupply crisis worldwide. One approach to alleviate this problem is to transform glycerol into valuable chemicals such as hydrogen and syngas. Pyrolysis, steam reforming, partial oxidation, autothermal reforming, and aqueous-phase reforming are promising routes for the catalytic conversion of glycerol. However, certain challenges are still limiting their development. Recent advances in catalyst design, reactor engineering, and theoretical chemistry have enabled us to understand glycerol valorization on macro- and microscopic scales, and may help overcome existing thresholds. With the synergistic efforts of these tools, glycerol may no longer be a burden, but a valuable resource of hydrogen and syngas in the near future.
► A review of glycerol conversion to hydrogen and syngas. ► Pyrolysis, steam reforming, partial oxidation, and aqueous-phase reforming. ► Computational studies provide in-depth understandings of glycerol valorization. Glycerol, a byproduct derived from the production of biodiesel, is currently in an oversupply crisis worldwide. One approach to alleviate this problem is to transform glycerol into valuable chemicals such as hydrogen and syngas. Pyrolysis, steam reforming, partial oxidation, autothermal reforming, and aqueous-phase reforming are promising routes for the catalytic conversion of glycerol. However, certain challenges are still limiting their development. Recent advances in catalyst design, reactor engineering, and theoretical chemistry have enabled us to understand glycerol valorization on macro- and microscopic scales, and may help overcome existing thresholds. With the synergistic efforts of these tools, glycerol may no longer be a burden, but a valuable resource of hydrogen and syngas in the near future. |
| Author | Lin, Yu-Chuan |
| Author_xml | – sequence: 1 givenname: Yu-Chuan surname: Lin fullname: Lin, Yu-Chuan email: yclin@saturn.yzu.edu.tw, yclin768@gmail.com organization: Department of Chemical Engineering and Materials Science, Yuan Ze University, 135 Yuan-Tung Rd., Chungli, Taoyuan 32003, Taiwan |
| BackLink | http://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=27125427$$DView record in Pascal Francis |
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| Snippet | Glycerol, a byproduct derived from the production of biodiesel, is currently in an oversupply crisis worldwide. One approach to alleviate this problem is to... |
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| SubjectTerms | Alternative fuels. Production and utilization Applied sciences Biodiesel Energy Exact sciences and technology Fuels Glycerol Hydrogen Miscellaneous Partial oxidation Reforming Syngas |
| Title | Catalytic valorization of glycerol to hydrogen and syngas |
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