Mixed salts of amino acids with different anions

Mixed salts of amino acids with different anions are of considerable interest from chemical and structural points of view and also as a source of new materials the properties of which can be controlled by appropriate choice of anions. Four such crystals, L-His2+·Cl−·HSO4− (P212121, Z=4), L-Arg2+·NO3...

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Veröffentlicht in:Journal of crystal growth Jg. 362; S. 182 - 188
Hauptverfasser: Ghazaryan, V.V., Fleck, M., Petrosyan, A.M.
Format: Journal Article Tagungsbericht
Sprache:Englisch
Veröffentlicht: Amsterdam Elsevier B.V 01.01.2013
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ISSN:0022-0248, 1873-5002
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Abstract Mixed salts of amino acids with different anions are of considerable interest from chemical and structural points of view and also as a source of new materials the properties of which can be controlled by appropriate choice of anions. Four such crystals, L-His2+·Cl−·HSO4− (P212121, Z=4), L-Arg2+·NO3−·ClO4− (δ-form, P21, Z=4), L-Arg2+·F−·NO3− (P1, Z=2), 2L-Arg2+·(F−⋯HF)·3NO3− (P212121, Z=4), have been characterized structurally and by IR and Raman spectra. The hydrogen bond between the carboxyl group and the fluoride ion (2.371(3)Å) in the structure of L-Arg2+·F−·NO3− is among the shortest known O–H⋯F type hydrogen bonds. The O–H⋯F hydrogen bond in the structure of 2L-Arg2+·(F−⋯HF)·3NO3− is even shorter (2.341(2)Å) and thus belongs to the shortest contacts among both Ο–Η⋯F and F–H⋯O types hydrogen bonds. ► Four crystalline amino acid salts with different anions have been obtained. ► Molecular and crystal structures were determined by XRD and vibrational spectroscopy. ► Very short O⋯F type H-bonds were found, two shorter than any previously known.
AbstractList Mixed salts of amino acids with different anions are of considerable interest from chemical and structural points of view and also as a source of new materials the properties of which can be controlled by appropriate choice of anions. Four such crystals, L-His2+ADTCl-ADTHSO4- (P212121, Z=4), L-Arg2+ADTNO3-ADTClO4- ([d]-form, P21, Z=4), L-Arg2+ADTF-ADTNO3- (P1, Z=2), 2L-Arg2+ADT(F-a=HF)ADT3NO3- (P212121, Z=4), have been characterized structurally and by IR and Raman spectra. The hydrogen bond between the carboxyl group and the fluoride ion (2.371(3) Aa) in the structure of L-Arg2+ADTF-ADTNO3- is among the shortest known OaHa=F type hydrogen bonds. The OaHa=F hydrogen bond in the structure of 2L-Arg2+ADT(F-a=HF)ADT3NO3- is even shorter (2.341(2) Aa) and thus belongs to the shortest contacts among both IaIa=F and FaHa=O types hydrogen bonds.
Mixed salts of amino acids with different anions are of considerable interest from chemical and structural points of view and also as a source of new materials the properties of which can be controlled by appropriate choice of anions. Four such crystals, L-His2+·Cl−·HSO4− (P212121, Z=4), L-Arg2+·NO3−·ClO4− (δ-form, P21, Z=4), L-Arg2+·F−·NO3− (P1, Z=2), 2L-Arg2+·(F−⋯HF)·3NO3− (P212121, Z=4), have been characterized structurally and by IR and Raman spectra. The hydrogen bond between the carboxyl group and the fluoride ion (2.371(3)Å) in the structure of L-Arg2+·F−·NO3− is among the shortest known O–H⋯F type hydrogen bonds. The O–H⋯F hydrogen bond in the structure of 2L-Arg2+·(F−⋯HF)·3NO3− is even shorter (2.341(2)Å) and thus belongs to the shortest contacts among both Ο–Η⋯F and F–H⋯O types hydrogen bonds. ► Four crystalline amino acid salts with different anions have been obtained. ► Molecular and crystal structures were determined by XRD and vibrational spectroscopy. ► Very short O⋯F type H-bonds were found, two shorter than any previously known.
Author Ghazaryan, V.V.
Fleck, M.
Petrosyan, A.M.
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Keywords B1. Amino acids' mixed salts
A2. Growth from solutions
Crystal growth
Hydrogen bonds
Hafnium
Amino acids
Fluorides
Infrared spectra
Raman spectroscopy
Growth from solution
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Snippet Mixed salts of amino acids with different anions are of considerable interest from chemical and structural points of view and also as a source of new materials...
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SubjectTerms A2. Growth from solutions
Amino acids
Anions
B1. Amino acids' mixed salts
Carboxyl group
Condensed matter: structure, mechanical and thermal properties
Cross-disciplinary physics: materials science; rheology
Crystal growth
Crystal structure
Exact sciences and technology
Fluorides
Growth from solutions
Hydrogen bonds
Infrared radiation
Materials science
Methods of crystal growth; physics of crystal growth
Organic compounds
Physics
Structure of solids and liquids; crystallography
Structure of specific crystalline solids
Title Mixed salts of amino acids with different anions
URI https://dx.doi.org/10.1016/j.jcrysgro.2011.09.059
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