Iron‐Catalyzed Allylic C(sp3)−H Silylation: Spin‐Crossover‐Efficiency‐Determined Chemoselectivity

The nuanced role of spin effects remains a critical gap in designing proficient open‐shell catalysts. This study elucidates an iron‐catalyzed allylic C(sp3)−H silylation/alkyne hydrosilylation reaction, in which the spin state of the open‐shell iron catalyst dictates the reaction kinetics and pathwa...

Full description

Saved in:

Bibliographic Details
Published in:	Angewandte Chemie International Edition Vol. 63; no. 21; pp. e202402044 - n/a
Main Authors:	He, Peng, Guan, Mu‐Han, Hu, Meng‐Yang, Zhou, Yuan‐Jun, Huang, Ming‐Yao, Zhu, Shou‐Fei
Format:	Journal Article
Language:	English
Published:	Germany Wiley Subscription Services, Inc 21.05.2024
Edition:	International ed. in English
Subjects:	Alkenes Alkynes Catalysts C−H bond silylation Hydrosilylation Iron iron catalysis Reaction kinetics spin spin crossover spin effects Substrates iron catalysis spin crossover spin effects spin C−H bond silylation
ISSN:	1433-7851, 1521-3773, 1521-3773
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!

Be the first to leave a comment!