Towards a Cradle‐to‐Cradle Polyolefin Lifecycle
Achieving efficient chemical depolymerization of waste polyolefins to monomers remains an unsolved challenge, while it could be an effective means to avoid further waste accumulation in the environment and generate economic benefits. In a recent publication by Conk et al., polyethylene (PE) is conve...
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| Vydané v: | Angewandte Chemie International Edition Ročník 62; číslo 3; s. e202216163 - n/a |
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| Hlavní autori: | , |
| Médium: | Journal Article |
| Jazyk: | English |
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Germany
Wiley Subscription Services, Inc
16.01.2023
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| Vydanie: | International ed. in English |
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| ISSN: | 1433-7851, 1521-3773, 1521-3773 |
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| Abstract | Achieving efficient chemical depolymerization of waste polyolefins to monomers remains an unsolved challenge, while it could be an effective means to avoid further waste accumulation in the environment and generate economic benefits. In a recent publication by Conk et al., polyethylene (PE) is converted to propylene, the second most used monomer in the polymer industry. The conversion is achieved via a tandem catalysis approach in which partially unsaturated PE chains react with ethylene to generate propylene with yields as high as 87 %. The study is a first proof of concept showcasing a selective chemical depolymerization of PE to a monomer. Future research is expected to focus on the catalyst optimization, process design, and compatibility with contaminated and multi‐polymer waste streams.
Selective depolymerization of polyethylene to propylene was achieved by two independent studies using a tandem catalysis approach. By combining a dehydrogenation, an isomerization and an ethenolysis catalyst under an ethylene atmosphere, propylene was the favoured product which could be further used as precursor for polypropylene production. |
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| AbstractList | Achieving efficient chemical depolymerization of waste polyolefins to monomers remains an unsolved challenge, while it could be an effective means to avoid further waste accumulation in the environment and generate economic benefits. In a recent publication by Conk et al., polyethylene (PE) is converted to propylene, the second most used monomer in the polymer industry. The conversion is achieved via a tandem catalysis approach in which partially unsaturated PE chains react with ethylene to generate propylene with yields as high as 87 %. The study is a first proof of concept showcasing a selective chemical depolymerization of PE to a monomer. Future research is expected to focus on the catalyst optimization, process design, and compatibility with contaminated and multi-polymer waste streams.Achieving efficient chemical depolymerization of waste polyolefins to monomers remains an unsolved challenge, while it could be an effective means to avoid further waste accumulation in the environment and generate economic benefits. In a recent publication by Conk et al., polyethylene (PE) is converted to propylene, the second most used monomer in the polymer industry. The conversion is achieved via a tandem catalysis approach in which partially unsaturated PE chains react with ethylene to generate propylene with yields as high as 87 %. The study is a first proof of concept showcasing a selective chemical depolymerization of PE to a monomer. Future research is expected to focus on the catalyst optimization, process design, and compatibility with contaminated and multi-polymer waste streams. Achieving efficient chemical depolymerization of waste polyolefins to monomers remains an unsolved challenge, while it could be an effective means to avoid further waste accumulation in the environment and generate economic benefits. In a recent publication by Conk et al., polyethylene (PE) is converted to propylene, the second most used monomer in the polymer industry. The conversion is achieved via a tandem catalysis approach in which partially unsaturated PE chains react with ethylene to generate propylene with yields as high as 87 %. The study is a first proof of concept showcasing a selective chemical depolymerization of PE to a monomer. Future research is expected to focus on the catalyst optimization, process design, and compatibility with contaminated and multi-polymer waste streams. Achieving efficient chemical depolymerization of waste polyolefins to monomers remains an unsolved challenge, while it could be an effective means to avoid further waste accumulation in the environment and generate economic benefits. In a recent publication by Conk et al., polyethylene (PE) is converted to propylene, the second most used monomer in the polymer industry. The conversion is achieved via a tandem catalysis approach in which partially unsaturated PE chains react with ethylene to generate propylene with yields as high as 87 %. The study is a first proof of concept showcasing a selective chemical depolymerization of PE to a monomer. Future research is expected to focus on the catalyst optimization, process design, and compatibility with contaminated and multi‐polymer waste streams. Selective depolymerization of polyethylene to propylene was achieved by two independent studies using a tandem catalysis approach. By combining a dehydrogenation, an isomerization and an ethenolysis catalyst under an ethylene atmosphere, propylene was the favoured product which could be further used as precursor for polypropylene production. |
| Author | Thevenon, Arnaud Vollmer, Ina |
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| Cites_doi | 10.1038/s41578-020-0190-4 10.1126/science.add1088 10.1038/532435a 10.1021/jacs.2c07781 10.1016/j.wasman.2017.07.044 10.1126/sciadv.1501591 10.1126/sciadv.1700782 10.1021/acssuschemeng.0c07612 10.1016/j.jaap.2010.01.003 10.1021/acs.jpca.0c01363 10.1016/j.fuel.2014.09.034 10.1016/j.wasman.2020.12.020 |
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| Keywords | Depolymerization Propylene Polyethylene Recycling Tandem Catalysis |
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| SubjectTerms | Catalysis Catalysts Depolymerization Design optimization Monomers Polyethylene Polyethylenes Polymers Polyolefins Propylene Recycling Tandem Catalysis Waste management Waste streams |
| Title | Towards a Cradle‐to‐Cradle Polyolefin Lifecycle |
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