Matrix effects on the magnetic properties of a molecular spin triangle embedded in a polymeric film

Molecular triangles with competing Heisenberg interactions and significant Dzyaloshinskii-Moriya interactions (DMI) exhibit high environmental sensitivity, making them potential candidates for active elements for quantum sensing. Additionally, these triangles exhibit magnetoelectric coupling, allowi...

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Published in:Physical chemistry chemical physics : PCCP Vol. 26; no. 10; p. 8043
Main Authors: Tesi, Lorenzo, Boudalis, Athanassios K, Drerup, Katja, Ruben, Mario, van Slageren, Joris
Format: Journal Article
Language:English
Published: England 06.03.2024
ISSN:1463-9084, 1463-9084
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Abstract Molecular triangles with competing Heisenberg interactions and significant Dzyaloshinskii-Moriya interactions (DMI) exhibit high environmental sensitivity, making them potential candidates for active elements for quantum sensing. Additionally, these triangles exhibit magnetoelectric coupling, allowing their properties to be controlled using electric fields. However, the manipulation and deposition of such complexes pose significant challenges. This work explores a solution by embedding iron-based molecular triangles in a polymer matrix, a strategy that offers various deposition methods. We investigate how the host matrix alters the magnetic properties of the molecular triangle, with specific focus on the magnetic anisotropy, aiming to advance its practical applications as quantum sensors.
AbstractList Molecular triangles with competing Heisenberg interactions and significant Dzyaloshinskii-Moriya interactions (DMI) exhibit high environmental sensitivity, making them potential candidates for active elements for quantum sensing. Additionally, these triangles exhibit magnetoelectric coupling, allowing their properties to be controlled using electric fields. However, the manipulation and deposition of such complexes pose significant challenges. This work explores a solution by embedding iron-based molecular triangles in a polymer matrix, a strategy that offers various deposition methods. We investigate how the host matrix alters the magnetic properties of the molecular triangle, with specific focus on the magnetic anisotropy, aiming to advance its practical applications as quantum sensors.
Molecular triangles with competing Heisenberg interactions and significant Dzyaloshinskii-Moriya interactions (DMI) exhibit high environmental sensitivity, making them potential candidates for active elements for quantum sensing. Additionally, these triangles exhibit magnetoelectric coupling, allowing their properties to be controlled using electric fields. However, the manipulation and deposition of such complexes pose significant challenges. This work explores a solution by embedding iron-based molecular triangles in a polymer matrix, a strategy that offers various deposition methods. We investigate how the host matrix alters the magnetic properties of the molecular triangle, with specific focus on the magnetic anisotropy, aiming to advance its practical applications as quantum sensors.Molecular triangles with competing Heisenberg interactions and significant Dzyaloshinskii-Moriya interactions (DMI) exhibit high environmental sensitivity, making them potential candidates for active elements for quantum sensing. Additionally, these triangles exhibit magnetoelectric coupling, allowing their properties to be controlled using electric fields. However, the manipulation and deposition of such complexes pose significant challenges. This work explores a solution by embedding iron-based molecular triangles in a polymer matrix, a strategy that offers various deposition methods. We investigate how the host matrix alters the magnetic properties of the molecular triangle, with specific focus on the magnetic anisotropy, aiming to advance its practical applications as quantum sensors.
Author Tesi, Lorenzo
van Slageren, Joris
Ruben, Mario
Boudalis, Athanassios K
Drerup, Katja
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  givenname: Lorenzo
  orcidid: 0000-0003-4001-8363
  surname: Tesi
  fullname: Tesi, Lorenzo
  email: lorenzo.tesi@ipc.uni-stuttgart.de
  organization: Institute of Physical Chemistry and Center for Integrated Quantum Science and Technology, University of Stuttgart, Pfaffenwaldring 55, Stuttgart 70569, Germany. lorenzo.tesi@ipc.uni-stuttgart.de
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  givenname: Athanassios K
  orcidid: 0000-0002-8797-1170
  surname: Boudalis
  fullname: Boudalis, Athanassios K
  email: bountalis@unistra.fr
  organization: Institut de Chimie de Strasbourg (UMR 7177, CNRS-Unistra), Université de Strasbourg, 4 rue Blaise Pascal, CS 90032, Strasbourg F-67081, France. bountalis@unistra.fr
– sequence: 3
  givenname: Katja
  surname: Drerup
  fullname: Drerup, Katja
  email: lorenzo.tesi@ipc.uni-stuttgart.de
  organization: Institute of Physical Chemistry and Center for Integrated Quantum Science and Technology, University of Stuttgart, Pfaffenwaldring 55, Stuttgart 70569, Germany. lorenzo.tesi@ipc.uni-stuttgart.de
– sequence: 4
  givenname: Mario
  surname: Ruben
  fullname: Ruben, Mario
  organization: Institute of Nanotechnology (INT), and Institute for Quantum Materials and Technology (IQMT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Plats 1, D-76344, Eggenstein-Leopoldshafen, Germany
– sequence: 5
  givenname: Joris
  orcidid: 0000-0002-0855-8960
  surname: van Slageren
  fullname: van Slageren, Joris
  email: lorenzo.tesi@ipc.uni-stuttgart.de
  organization: Institute of Physical Chemistry and Center for Integrated Quantum Science and Technology, University of Stuttgart, Pfaffenwaldring 55, Stuttgart 70569, Germany. lorenzo.tesi@ipc.uni-stuttgart.de
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Title Matrix effects on the magnetic properties of a molecular spin triangle embedded in a polymeric film
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