Dithiolene complexes containing N coordinating groups and corresponding tetrathiafulvalene donors

The chemistry of transition metal dithiolene complexes containing N coordinating groups and the corresponding TTF donors, is reviewed starting from the ligand synthesis to the coordination structures where these dithiolene complexes are used as bridging units. The dithiolene ligands containing N coo...

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Veröffentlicht in:	Coordination chemistry reviews Jg. 254; H. 13; S. 1493 - 1508
Hauptverfasser:	Rabaça, Sandra, Almeida, Manuel
Format:	Journal Article
Sprache:	Englisch
Veröffentlicht:	Elsevier B.V 01.07.2010
Schlagworte:	Coordination polymers Dithiolenes Metal complexes N coordinating groups Tetrathiafulvalenes B15C5 cbdt MnTPP AcOH DMSO hmp Tetrathiafulvalenes hfac fendt H 2 pds H 2 pdt Coordination polymers bpmdmit cdc 18C6 DazfDTs adt SMM bpedmit dpesdt nBu 4N DPEphos dcbdt dmio Cyclam TTF LDA VDT-TTF Pd(PPh 3) 4 Cyclem DC18C6-B DC18C6-A Me 4cyclam Hg(OAc) 2 i-mnt THF BEDT-TTF dmit Na 2 dcdmp Pd 2(dba) 3 DMF dpddt Metal complexes 15C5 Me 2Benz 218C6 H 2 dcbdt H 2 cbdt N18C6 N coordinating groups tfadt pedt PPh 4 Dithiolenes mnt BVDT-TTF
ISSN:	0010-8545, 1873-3840
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Zusammenfassung:	The chemistry of transition metal dithiolene complexes containing N coordinating groups and the corresponding TTF donors, is reviewed starting from the ligand synthesis to the coordination structures where these dithiolene complexes are used as bridging units. The dithiolene ligands containing N coordinating atoms present two coordination poles which can selectively bind different metals and act as bridging units in a variety of coordination architectures. The transition metal dithiolene complexes based on these N containing ligands and the corresponding TTF donors can be themselves regarded as ligands. These can be used to coordinate other metals, potentially leading to a diversity of hetero metallic coordination architectures. With the use of appropriate auxiliary ligands they can lead to discrete metal complexes. In addition they can lead to more extended polymeric structures of different dimensionality such as 1D chains, 2D layers or even 3D polymers can also be obtained.
ISSN:	0010-8545 1873-3840
DOI:	10.1016/j.ccr.2009.12.006