A linear cobalt(II) complex with maximal orbital angular momentum from a non-Aufbau ground state

Orbital angular momentum is a prerequisite for magnetic anisotropy, although in transition metal complexes it is typically quenched by the ligand field. By reducing the basicity of the carbon donor atoms in a pair of alkyl ligands, we synthesized a cobalt(II) dialkyl complex, Co(C(SiMe ONaph) ) (whe...

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Bibliographic Details
Published in:	Science (American Association for the Advancement of Science) Vol. 362; no. 6421
Main Authors:	Bunting, Philip C, Atanasov, Mihail, Damgaard-Møller, Emil, Perfetti, Mauro, Crassee, Iris, Orlita, Milan, Overgaard, Jacob, van Slageren, Joris, Neese, Frank, Long, Jeffrey R
Format:	Journal Article
Language:	English
Published:	United States 21.12.2018
ISSN:	1095-9203, 1095-9203
Online Access:	Get more information
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