Feasibility of electro-reduction of U(VI) in oxalic acid using an electrolytic CEM-separated cell

The feasibility of electrolytic stripping of U(VI) using an electrolytic separation cell with anode and cathode compartments, separated by a cation exchange membrane (CEM), was investigated as a possible final step in a traditional solvent extraction process to recover uranium. The reduction mechani...

Full description

Saved in:

Bibliographic Details
Published in:	Journal of radioanalytical and nuclear chemistry Vol. 326; no. 2; pp. 1505 - 1510
Main Authors:	Potgieter, M., van der Spoel Badenhorst, W. D., Barry, J. C., van der Westhuizen, D. J., Krieg, H. M.
Format:	Journal Article
Language:	English
Published:	Cham Springer International Publishing 01.11.2020 Springer Springer Nature B.V
Subjects:	Cation exchanging Chemistry Chemistry and Materials Science Comparative analysis Diagnostic Radiology Disproportionation Electrolytes Feasibility Hadrons Heavy Ions Hydrazines Inorganic Chemistry Nitric acid Nuclear Chemistry Nuclear Physics Oxalates Oxalic acid Physical Chemistry Solvent extraction Uranium Electrolytic stripping Oxalic acid electrolyte Uranium reduction Cation exchange membrane
ISSN:	0236-5731, 1588-2780
Online Access:	Get full text
Tags:	Add Tag No Tags, Be the first to tag this record!

Abstract	The feasibility of electrolytic stripping of U(VI) using an electrolytic separation cell with anode and cathode compartments, separated by a cation exchange membrane (CEM), was investigated as a possible final step in a traditional solvent extraction process to recover uranium. The reduction mechanism of U(VI)–U(IV) in oxalic acid was compared with the well-known nitric acid and hydrazine mechanism. It was shown that a similar mechanism was followed in both electrolytes, forming a U(V) intermediate followed by disproportionation to U(IV) and U(VI). Measurable amounts of U(IV) were produced and the transfer of U(VI) through the CEM with simultaneous electro-reduction to U(IV) was confirmed.
AbstractList	The feasibility of electrolytic stripping of U(VI) using an electrolytic separation cell with anode and cathode compartments, separated by a cation exchange membrane (CEM), was investigated as a possible final step in a traditional solvent extraction process to recover uranium. The reduction mechanism of U(VI)-U(IV) in oxalic acid was compared with the well-known nitric acid and hydrazine mechanism. It was shown that a similar mechanism was followed in both electrolytes, forming a U(V) intermediate followed by disproportionation to U(IV) and U(VI). Measurable amounts of U(IV) were produced and the transfer of U(VI) through the CEM with simultaneous electro-reduction to U(IV) was confirmed.
Audience	Academic
Author	Barry, J. C. van der Westhuizen, D. J. Potgieter, M. van der Spoel Badenhorst, W. D. Krieg, H. M.
Author_xml	– sequence: 1 givenname: M. surname: Potgieter fullname: Potgieter, M. organization: Uranium Chemistry Group, South African Nuclear Energy Corporation SOC Ltd (Necsa), Membrane Technology Group, Chemical Resource Beneficiation, North-West University – sequence: 2 givenname: W. D. surname: van der Spoel Badenhorst fullname: van der Spoel Badenhorst, W. D. organization: Membrane Technology Group, Chemical Resource Beneficiation, North-West University – sequence: 3 givenname: J. C. surname: Barry fullname: Barry, J. C. organization: Uranium Chemistry Group, South African Nuclear Energy Corporation SOC Ltd (Necsa) – sequence: 4 givenname: D. J. surname: van der Westhuizen fullname: van der Westhuizen, D. J. organization: Membrane Technology Group, Chemical Resource Beneficiation, North-West University – sequence: 5 givenname: H. M. orcidid: 0000-0002-4268-133X surname: Krieg fullname: Krieg, H. M. email: henning.krieg@nwu.ac.za organization: Membrane Technology Group, Chemical Resource Beneficiation, North-West University
BookMark	eNp9kctqHDEQRUVwIOPHD2TVkE2ykFOSRo9emsFODA7Z2NkKtbo0yMjdE0kDmb-PJm1jyMJooeLqnipU95ScTPOEhHxkcMkA9NfCoFeaAgcKWrRKvCMrJo2hXBs4ISvgQlGpBftATkt5BIDeGLEi7gZdiUNMsR66OXSY0Nc804zj3tc4T0fx4fOv2y9dbPUfl6LvnI9jty9x2nZuekHSobanzfUPWnDnsqs4dh5TOifvg0sFL57vM_Jwc32_-U7vfn673VzdUS-kqdRAP2gl2YBBrZVHZfjo9Hpkg9KKBROkRubl4BV41xsnBEMmUPFRB9mDF2fk09J3l-ffeyzVPs77PLWRlq-1MCB7yZvrcnFtXUIbpzDX7Hw7Iz5F35YaYtOvlOh7wRRnDTAL4PNcSsZgfazuuJkGxmQZ2GMCdknAtgTsvwSsaCj_D93l-OTy4W1ILFBp5mmL-fUbb1B_Ad73mc0
CitedBy_id	crossref_primary_10_1016_j_seppur_2023_123615 crossref_primary_10_1007_s11356_022_21351_2 crossref_primary_10_1002_slct_202201140 crossref_primary_10_1080_01932691_2021_1956322 crossref_primary_10_1016_j_cej_2024_152383
Cites_doi	10.1016/j.ces.2012.03.019 10.1016/j.jelechem.2016.07.002 10.1023/A:1012819416084 10.1016/j.memsci.2007.05.018 10.1021/ja01211a011 10.1021/ja01225a023 10.1081/SS-100100795 10.1007/s10967-012-1940-6 10.1007/s10967-012-2267-z 10.1023/B:JRNC.0000046770.86000.d6 10.2172/4165457 10.1021/cr60211a001 10.1080/18811248.1994.9735158 10.1021/j150563a017 10.1080/18811248.2007.9711366 10.1016/j.mineng.2005.09.035 10.1524/ract.2013.2061 10.1016/j.jssc.2008.04.010 10.1016/S0016-7037(02)00953-5 10.1023/b:jach.0000021925.61151.95 10.1007/s10967-013-2463-5 10.2172/5650046 10.1021/es980010o
ContentType	Journal Article
Copyright	Akadémiai Kiadó, Budapest, Hungary 2020 COPYRIGHT 2020 Springer Akadémiai Kiadó, Budapest, Hungary 2020.
Copyright_xml	– notice: Akadémiai Kiadó, Budapest, Hungary 2020 – notice: COPYRIGHT 2020 Springer – notice: Akadémiai Kiadó, Budapest, Hungary 2020.
DBID	AAYXX CITATION
DOI	10.1007/s10967-020-07367-3
DatabaseName	CrossRef
DatabaseTitle	CrossRef
DatabaseTitleList
DeliveryMethod	fulltext_linktorsrc
Discipline	Chemistry
EISSN	1588-2780
EndPage	1510
ExternalDocumentID	A639931621 10_1007_s10967_020_07367_3
GroupedDBID	--- --K -4Y -58 -5G -BR -EM -Y2 -~C .86 .GJ .VR 06C 06D 0R~ 0VY 1B1 1N0 1SB 2.D 203 28- 29L 2J2 2JN 2JY 2KG 2KM 2LR 2P1 2VQ 2~H 30V 4.4 406 408 409 40D 40E 53G 5QI 5VS 67Z 6NX 78A 8TC 8UJ 8WZ 95- 95. 95~ 96X A6W A8Z AAAVM AABHQ AACDK AAHNG AAIAL AAIKT AAJBT AANZL AARHV AARTL AASML AATNV AATVU AAUYE AAWCG AAYIU AAYQN AAYTO AAYZH ABAKF ABBBX ABBXA ABDBF ABDZT ABECU ABEFU ABFTV ABHLI ABHQN ABJNI ABJOX ABKCH ABKTR ABMNI ABMQK ABNWP ABQBU ABQSL ABSXP ABTEG ABTHY ABTKH ABTMW ABULA ABWNU ABXPI ACAOD ACBXY ACDTI ACGFS ACHSB ACHXU ACIWK ACKNC ACMDZ ACMLO ACOKC ACOMO ACPIV ACSNA ACUHS ACZOJ ADHHG ADHIR ADINQ ADKNI ADKPE ADMLS ADRFC ADTPH ADURQ ADYFF ADZKW AEBTG AEFIE AEFQL AEGAL AEGNC AEJHL AEJRE AEKMD AEMSY AENEX AEOHA AEPYU AESKC AETLH AEVLU AEXYK AFBBN AFEXP AFGCZ AFLOW AFQWF AFWTZ AFZKB AGAYW AGDGC AGGDS AGJBK AGMZJ AGQEE AGQMX AGRTI AGWIL AGWZB AGYKE AHAVH AHBYD AHKAY AHSBF AHYZX AIAKS AIGIU AIIXL AILAN AITGF AJBLW AJRNO AJZVZ ALMA_UNASSIGNED_HOLDINGS ALWAN AMKLP AMXSW AMYLF AMYQR AOCGG ARMRJ ASPBG AVWKF AXYYD AYJHY AZFZN B-. BA0 BBWZM BDATZ BGNMA BSONS CAG COF CS3 CSCUP DDRTE DL5 DNIVK DPUIP DU5 EBD EBLON EBS EIOEI EJD ESBYG ESX FEDTE FERAY FFXSO FIGPU FINBP FNLPD FRRFC FSGXE FWDCC G-Y G-Z GGCAI GGRSB GJIRD GNWQR GQ6 GQ7 GQ8 GXS H13 HF~ HG5 HG6 HMJXF HQYDN HRMNR HVGLF HZ~ I-F IAO IHE IJ- IKXTQ ITC IWAJR IXC IXD IXE IZIGR IZQ I~X I~Z J-C J0Z JBSCW JCJTX JZLTJ KDC KOV KOW L8X LLZTM M4Y MA- MET MKB ML- N2Q NB0 NDZJH NPVJJ NQ- NQJWS NU0 O9- O93 O9G O9I O9J OAM OVD P19 P9N PF0 PT4 PT5 QOK QOR QOS R4E R89 R9I RHV RIG RKA RNI RNS ROL RPX RPZ RSV RZC RZE RZK S16 S1Z S26 S27 S28 S3B SAP SCG SCLPG SCM SDH SDM SHX SISQX SJYHP SNE SNPRN SNX SOHCF SOJ SPISZ SRMVM SSLCW STPWE SZN T13 T16 TEORI TSG TSK TSV TUC TUS U2A UG4 UOJIU UTJUX UZXMN VC2 VFIZW W23 W48 W4F WH7 WJK WK8 YLTOR Z45 Z5O Z7R Z7V Z7W Z7X Z7Y Z7Z Z83 Z86 Z87 Z8M Z8O Z8P Z8Q Z8T Z91 ZMTXR ZXP ~02 ~8M ~EX AAPKM AAYXX ABBRH ABDBE ABFSG ABJCF ABRTQ ACSTC ADHKG AEZWR AFDZB AFFHD AFHIU AFKRA AFOHR AGQPQ AHPBZ AHWEU AIXLP ARAPS ATHPR AYFIA BENPR BGLVJ CCPQU CITATION ESTFP HCIFZ KB. M7S PDBOC PHGZM PHGZT PQGLB PTHSS
ID	FETCH-LOGICAL-c358t-809b7651bef646ce682da74d1b6761f8f57e1c5bc60ca98a331e13e62d7f590c3
IEDL.DBID	RSV
ISICitedReferencesCount	5
ISICitedReferencesURI	http://www.webofscience.com/api/gateway?GWVersion=2&SrcApp=Summon&SrcAuth=ProQuest&DestLinkType=CitingArticles&DestApp=WOS_CPL&KeyUT=000571694800003&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D
ISSN	0236-5731
IngestDate	Wed Sep 17 23:57:52 EDT 2025 Sat Nov 29 10:25:26 EST 2025 Tue Nov 18 21:30:36 EST 2025 Sat Nov 29 04:08:27 EST 2025 Fri Feb 21 02:32:16 EST 2025
IsPeerReviewed	true
IsScholarly	true
Issue	2
Keywords	Electrolytic stripping Oxalic acid electrolyte Uranium reduction Cation exchange membrane
Language	English
LinkModel	DirectLink
MergedId	FETCHMERGED-LOGICAL-c358t-809b7651bef646ce682da74d1b6761f8f57e1c5bc60ca98a331e13e62d7f590c3
Notes	ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 14
ORCID	0000-0002-4268-133X
PQID	2473805952
PQPubID	2043824
PageCount	6
ParticipantIDs	proquest_journals_2473805952 gale_infotracacademiconefile_A639931621 crossref_citationtrail_10_1007_s10967_020_07367_3 crossref_primary_10_1007_s10967_020_07367_3 springer_journals_10_1007_s10967_020_07367_3
PublicationCentury	2000
PublicationDate	2020-11-01
PublicationDateYYYYMMDD	2020-11-01
PublicationDate_xml	– month: 11 year: 2020 text: 2020-11-01 day: 01
PublicationDecade	2020
PublicationPlace	Cham
PublicationPlace_xml	– name: Cham – name: Heidelberg
PublicationSubtitle	An International Journal Dealing with All Aspects and Applications of Nuclear Chemistry
PublicationTitle	Journal of radioanalytical and nuclear chemistry
PublicationTitleAbbrev	J Radioanal Nucl Chem
PublicationYear	2020
Publisher	Springer International Publishing Springer Springer Nature B.V
Publisher_xml	– name: Springer International Publishing – name: Springer – name: Springer Nature B.V
References	GuBLiangLDickeyMYinXDaiSReductive precipitation of uranium (VI) by zero-valent ironEnviron Sci Technol19983221336633731:CAS:528:DyaK1cXls1Cls78%3D RamanujamAAn introduction to the PUREX processIANCAS19981421120 MishraSRaoCJMallikaCMudaliUKElectrochemical studies on the reduction of uranyl ions in nitric acid-hydrazine mediaJ Electroanal Chem20167761271331:CAS:528:DC%2BC28XhtFKlsL3J10.1016/j.jelechem.2016.07.002 BurgerLUranium and plutonium extraction by organophosphorus compoundsJ Phys Chem19586255905931:CAS:528:DyaG1cXnsFClsA%3D%3D KurogiTCorrosion behavior of titanium in formic acid, oxalic acid, and formaldehydeInt Chin J Dent20066171:CAS:528:DC%2BD2sXhsVSrt7%2FK KrishnamurtyKVHarrisGMThe chemistry of the metal oxalato complexesChem Rev19616132132461:CAS:528:DyaF3MXos1agtw%3D%3D10.1021/cr60211a001 GeierRPUREX process solvent: literature review1979RichlandRockwell International Corp YuanZYanTZhengWShuangHXianLBianXZuoCLiCCaoZEfficient uranous nitrate production using membrane electrolysisJ Radioanal Nucl Chem20132981791851:CAS:528:DC%2BC3sXhsVOrsrzJ KolthoffIMHarrisWEThe polarography of uranium. II. Polarography in strongly acid solutionJ Am Chem Soc194668117511791:CAS:528:DyaH28XjtVymsQ%3D%3D DuffMCCoughlinJUHunterDBUranium co-precipitation with iron oxide mineralsGeochim Cosmochim Acta20026620353335471:CAS:528:DC%2BD38XnsFOkurc%3D BertrandMPlasariELebaigueOBaronPLamarqueNDucrosFHybrid LES—multizonal modelling of the uranium oxalate precipitationChem Eng Sci201277951041:CAS:528:DC%2BC38XpsV2msb8%3D YuanZZhengYWZuoCLiHBianXZhangBLiCCaoZXianLDiYLiuFElectrolytic partitioning of uranium and plutonium based on a new type of electrolytic mixer-settlerRadiochim Acta20131015475521:CAS:528:DC%2BC2cXmt1Srt7s%3D KimK-WLeeE-HYooJ-HA study on in situ electrolytic stripping of uranyl ion by using a closely packed glassy carbon fiber column electrode systemSep Sci Technol19993413262726421:CAS:528:DyaK1MXmt1Gmtbg%3D SuzukiYNankawaTOzakiTOhnukiTFrancisAJEnokidaYYamamotoIElectrochemical studies on uranium in the presence of organic acidsJ Nucl Sci Technol2007449122712321:CAS:528:DC%2BD2sXhtlWms73K10.1080/18811248.2007.9711366 Duvieubourg-GarelaLVigierNAbrahamFGrandjeanSAdaptable coordination of U(IV) in the 2D-(4,4) uranium oxalate network: from 8 to 10 coordinations in the uranium (IV) oxalate hydratesJ Solid State Chem20081818189919081:CAS:528:DC%2BD1cXpvFGlt74%3D10.1016/j.jssc.2008.04.010 PaikSBiswasSBhattacharyaSRoySBStripping study of U(VI) from loaded TBP/n-paraffin using ammonium nitrate bearing waste as strippantJ Radioanal Nucl Chem2013295214121461:CAS:528:DC%2BC3sXisF2isb0%3D Lanham WB, Runion TC (1949) PUREX process for plutonium and uranium recovery (trans: energy Do). Washington, DC HarrisWEKolthoffIMThe polarography of Uranium. I. Reduction in moderately acid solutions. Polarographic determination of UraniumJ Am Chem Soc194567148414901:CAS:528:DyaH2MXjtFOqtA%3D%3D GopinathNMirashiNNChanderKAggarwalSKRapid reduction of U(VI) on activated platinum wire gauze electrode for the primary coulometric determination of uraniumJ Appl Electrochem20043466176221:CAS:528:DC%2BD2cXisV2jsr4%3D10.1023/b:jach.0000021925.61151.95 SiniKMishraSMallikaCPandeyNKLawrenceFKamachi MudaliUNatarajanRReduction of uranyl nitrate ions in a continuous flow electrochemical reactorJ Radioanal Nucl Chem2013295150515101:CAS:528:DC%2BC3sXhtVOqs7w%3D Goldacker H, Hausberger H, Schmieder H (1975) Countercurrent extraction column for liquid–liquid extraction and simultaneous electrolysis. Patent: US 3869374 8p Rahman NA, Daoud JA, Aly HF (2000) Stripping of U(VI) from loaded TBP-Kerosene solutions. In: Paper presented at the seventh conference of nuclear sciences & applications, Cairo, Egypt GuptaSRathoreNSonawaneJPabbyAJanardanPChangraniRDeyPDispersion-free solvent extraction of U(VI) in macro amount from nitric acid solutions using hollow fiber contactorJ Membr Sci200730011311361:CAS:528:DC%2BD2sXptlyns7Y%3D KimK-WKimJ-DAoyagiHYoshidaZKinetics of reduction of uranium(VI) to uranium(IV) at titanium electrode in nitric acid and hydrazine mediaJ Nucl Sci Technol19943143293341:CAS:528:DyaK2cXjtV2ks78%3D10.1080/18811248.1994.9735158 MoraisCAGomieroLAFilhoWSRangelHUranium stripping from tertiary amine by sulfuric acid solution and its precipitation as uranium peroxideMiner Eng20051813–14133113331:CAS:528:DC%2BD2MXhtF2qs7%2FP10.1016/j.mineng.2005.09.035 WeiY-ZFangBAraiTKumagaiMElectrochemical reduction of uranium(VI) in nitric acid-hydrazine solution on glassy carbon electrodeJ Radioanal Nucl Chem200426224094151:CAS:528:DC%2BD2cXpt1Wqur8%3D ZilbermanBYFedorovYSKopyrinAArkhipovSBlazhevaIGlekovRExtraction of U(IV) and U(VI) with 30% tributyl phosphate under conditions of formation of the second organic phaseRadiochemistry20014321721761:CAS:528:DC%2BD3MXlslOhs78%3D T Kurogi (7367_CR25) 2006; 6 MC Duff (7367_CR10) 2002; 66 BY Zilberman (7367_CR26) 2001; 43 B Gu (7367_CR8) 1998; 32 KV Krishnamurty (7367_CR24) 1961; 61 L Burger (7367_CR4) 1958; 62 7367_CR6 A Ramanujam (7367_CR3) 1998; 14 7367_CR1 R Geier (7367_CR2) 1979 M Bertrand (7367_CR9) 2012; 77 S Paik (7367_CR7) 2013; 295 K-W Kim (7367_CR12) 1994; 31 CA Morais (7367_CR11) 2005; 18 WE Harris (7367_CR19) 1945; 67 S Gupta (7367_CR5) 2007; 300 Z Yuan (7367_CR16) 2013; 298 Y-Z Wei (7367_CR20) 2004; 262 K Sini (7367_CR15) 2013; 295 Y Suzuki (7367_CR23) 2007; 44 7367_CR18 IM Kolthoff (7367_CR21) 1946; 68 K-W Kim (7367_CR22) 1999; 34 Z Yuan (7367_CR17) 2013; 101 N Gopinath (7367_CR14) 2004; 34 L Duvieubourg-Garela (7367_CR27) 2008; 181 S Mishra (7367_CR13) 2016; 776
References_xml	– reference: Duvieubourg-GarelaLVigierNAbrahamFGrandjeanSAdaptable coordination of U(IV) in the 2D-(4,4) uranium oxalate network: from 8 to 10 coordinations in the uranium (IV) oxalate hydratesJ Solid State Chem20081818189919081:CAS:528:DC%2BD1cXpvFGlt74%3D10.1016/j.jssc.2008.04.010 – reference: KimK-WKimJ-DAoyagiHYoshidaZKinetics of reduction of uranium(VI) to uranium(IV) at titanium electrode in nitric acid and hydrazine mediaJ Nucl Sci Technol19943143293341:CAS:528:DyaK2cXjtV2ks78%3D10.1080/18811248.1994.9735158 – reference: YuanZZhengYWZuoCLiHBianXZhangBLiCCaoZXianLDiYLiuFElectrolytic partitioning of uranium and plutonium based on a new type of electrolytic mixer-settlerRadiochim Acta20131015475521:CAS:528:DC%2BC2cXmt1Srt7s%3D – reference: GopinathNMirashiNNChanderKAggarwalSKRapid reduction of U(VI) on activated platinum wire gauze electrode for the primary coulometric determination of uraniumJ Appl Electrochem20043466176221:CAS:528:DC%2BD2cXisV2jsr4%3D10.1023/b:jach.0000021925.61151.95 – reference: SiniKMishraSMallikaCPandeyNKLawrenceFKamachi MudaliUNatarajanRReduction of uranyl nitrate ions in a continuous flow electrochemical reactorJ Radioanal Nucl Chem2013295150515101:CAS:528:DC%2BC3sXhtVOqs7w%3D – reference: GuBLiangLDickeyMYinXDaiSReductive precipitation of uranium (VI) by zero-valent ironEnviron Sci Technol19983221336633731:CAS:528:DyaK1cXls1Cls78%3D – reference: KimK-WLeeE-HYooJ-HA study on in situ electrolytic stripping of uranyl ion by using a closely packed glassy carbon fiber column electrode systemSep Sci Technol19993413262726421:CAS:528:DyaK1MXmt1Gmtbg%3D – reference: KrishnamurtyKVHarrisGMThe chemistry of the metal oxalato complexesChem Rev19616132132461:CAS:528:DyaF3MXos1agtw%3D%3D10.1021/cr60211a001 – reference: BertrandMPlasariELebaigueOBaronPLamarqueNDucrosFHybrid LES—multizonal modelling of the uranium oxalate precipitationChem Eng Sci201277951041:CAS:528:DC%2BC38XpsV2msb8%3D – reference: DuffMCCoughlinJUHunterDBUranium co-precipitation with iron oxide mineralsGeochim Cosmochim Acta20026620353335471:CAS:528:DC%2BD38XnsFOkurc%3D – reference: KurogiTCorrosion behavior of titanium in formic acid, oxalic acid, and formaldehydeInt Chin J Dent20066171:CAS:528:DC%2BD2sXhsVSrt7%2FK – reference: GeierRPUREX process solvent: literature review1979RichlandRockwell International Corp – reference: MishraSRaoCJMallikaCMudaliUKElectrochemical studies on the reduction of uranyl ions in nitric acid-hydrazine mediaJ Electroanal Chem20167761271331:CAS:528:DC%2BC28XhtFKlsL3J10.1016/j.jelechem.2016.07.002 – reference: HarrisWEKolthoffIMThe polarography of Uranium. I. Reduction in moderately acid solutions. Polarographic determination of UraniumJ Am Chem Soc194567148414901:CAS:528:DyaH2MXjtFOqtA%3D%3D – reference: KolthoffIMHarrisWEThe polarography of uranium. II. Polarography in strongly acid solutionJ Am Chem Soc194668117511791:CAS:528:DyaH28XjtVymsQ%3D%3D – reference: Lanham WB, Runion TC (1949) PUREX process for plutonium and uranium recovery (trans: energy Do). Washington, DC – reference: MoraisCAGomieroLAFilhoWSRangelHUranium stripping from tertiary amine by sulfuric acid solution and its precipitation as uranium peroxideMiner Eng20051813–14133113331:CAS:528:DC%2BD2MXhtF2qs7%2FP10.1016/j.mineng.2005.09.035 – reference: PaikSBiswasSBhattacharyaSRoySBStripping study of U(VI) from loaded TBP/n-paraffin using ammonium nitrate bearing waste as strippantJ Radioanal Nucl Chem2013295214121461:CAS:528:DC%2BC3sXisF2isb0%3D – reference: ZilbermanBYFedorovYSKopyrinAArkhipovSBlazhevaIGlekovRExtraction of U(IV) and U(VI) with 30% tributyl phosphate under conditions of formation of the second organic phaseRadiochemistry20014321721761:CAS:528:DC%2BD3MXlslOhs78%3D – reference: WeiY-ZFangBAraiTKumagaiMElectrochemical reduction of uranium(VI) in nitric acid-hydrazine solution on glassy carbon electrodeJ Radioanal Nucl Chem200426224094151:CAS:528:DC%2BD2cXpt1Wqur8%3D – reference: Rahman NA, Daoud JA, Aly HF (2000) Stripping of U(VI) from loaded TBP-Kerosene solutions. In: Paper presented at the seventh conference of nuclear sciences & applications, Cairo, Egypt – reference: GuptaSRathoreNSonawaneJPabbyAJanardanPChangraniRDeyPDispersion-free solvent extraction of U(VI) in macro amount from nitric acid solutions using hollow fiber contactorJ Membr Sci200730011311361:CAS:528:DC%2BD2sXptlyns7Y%3D – reference: RamanujamAAn introduction to the PUREX processIANCAS19981421120 – reference: YuanZYanTZhengWShuangHXianLBianXZuoCLiCCaoZEfficient uranous nitrate production using membrane electrolysisJ Radioanal Nucl Chem20132981791851:CAS:528:DC%2BC3sXhsVOrsrzJ – reference: SuzukiYNankawaTOzakiTOhnukiTFrancisAJEnokidaYYamamotoIElectrochemical studies on uranium in the presence of organic acidsJ Nucl Sci Technol2007449122712321:CAS:528:DC%2BD2sXhtlWms73K10.1080/18811248.2007.9711366 – reference: Goldacker H, Hausberger H, Schmieder H (1975) Countercurrent extraction column for liquid–liquid extraction and simultaneous electrolysis. Patent: US 3869374 8p – reference: BurgerLUranium and plutonium extraction by organophosphorus compoundsJ Phys Chem19586255905931:CAS:528:DyaG1cXnsFClsA%3D%3D – volume: 77 start-page: 95 year: 2012 ident: 7367_CR9 publication-title: Chem Eng Sci doi: 10.1016/j.ces.2012.03.019 – volume: 776 start-page: 127 year: 2016 ident: 7367_CR13 publication-title: J Electroanal Chem doi: 10.1016/j.jelechem.2016.07.002 – volume: 43 start-page: 172 issue: 2 year: 2001 ident: 7367_CR26 publication-title: Radiochemistry doi: 10.1023/A:1012819416084 – volume: 300 start-page: 131 issue: 1 year: 2007 ident: 7367_CR5 publication-title: J Membr Sci doi: 10.1016/j.memsci.2007.05.018 – ident: 7367_CR18 – volume: 68 start-page: 1175 year: 1946 ident: 7367_CR21 publication-title: J Am Chem Soc doi: 10.1021/ja01211a011 – volume: 67 start-page: 1484 year: 1945 ident: 7367_CR19 publication-title: J Am Chem Soc doi: 10.1021/ja01225a023 – volume: 34 start-page: 2627 issue: 13 year: 1999 ident: 7367_CR22 publication-title: Sep Sci Technol doi: 10.1081/SS-100100795 – volume: 295 start-page: 1505 year: 2013 ident: 7367_CR15 publication-title: J Radioanal Nucl Chem doi: 10.1007/s10967-012-1940-6 – volume: 14 start-page: 11 issue: 2 year: 1998 ident: 7367_CR3 publication-title: IANCAS – volume: 6 start-page: 1 year: 2006 ident: 7367_CR25 publication-title: Int Chin J Dent – volume: 295 start-page: 2141 year: 2013 ident: 7367_CR7 publication-title: J Radioanal Nucl Chem doi: 10.1007/s10967-012-2267-z – volume: 262 start-page: 409 issue: 2 year: 2004 ident: 7367_CR20 publication-title: J Radioanal Nucl Chem doi: 10.1023/B:JRNC.0000046770.86000.d6 – ident: 7367_CR1 doi: 10.2172/4165457 – volume: 61 start-page: 213 issue: 3 year: 1961 ident: 7367_CR24 publication-title: Chem Rev doi: 10.1021/cr60211a001 – volume: 31 start-page: 329 issue: 4 year: 1994 ident: 7367_CR12 publication-title: J Nucl Sci Technol doi: 10.1080/18811248.1994.9735158 – volume: 62 start-page: 590 issue: 5 year: 1958 ident: 7367_CR4 publication-title: J Phys Chem doi: 10.1021/j150563a017 – volume: 44 start-page: 1227 issue: 9 year: 2007 ident: 7367_CR23 publication-title: J Nucl Sci Technol doi: 10.1080/18811248.2007.9711366 – volume: 18 start-page: 1331 issue: 13–14 year: 2005 ident: 7367_CR11 publication-title: Miner Eng doi: 10.1016/j.mineng.2005.09.035 – volume: 101 start-page: 547 year: 2013 ident: 7367_CR17 publication-title: Radiochim Acta doi: 10.1524/ract.2013.2061 – volume: 181 start-page: 1899 issue: 8 year: 2008 ident: 7367_CR27 publication-title: J Solid State Chem doi: 10.1016/j.jssc.2008.04.010 – volume: 66 start-page: 3533 issue: 20 year: 2002 ident: 7367_CR10 publication-title: Geochim Cosmochim Acta doi: 10.1016/S0016-7037(02)00953-5 – ident: 7367_CR6 – volume: 34 start-page: 617 issue: 6 year: 2004 ident: 7367_CR14 publication-title: J Appl Electrochem doi: 10.1023/b:jach.0000021925.61151.95 – volume: 298 start-page: 179 year: 2013 ident: 7367_CR16 publication-title: J Radioanal Nucl Chem doi: 10.1007/s10967-013-2463-5 – volume-title: PUREX process solvent: literature review year: 1979 ident: 7367_CR2 doi: 10.2172/5650046 – volume: 32 start-page: 3366 issue: 21 year: 1998 ident: 7367_CR8 publication-title: Environ Sci Technol doi: 10.1021/es980010o
SSID	ssj0009883
Score	2.2939305
Snippet	The feasibility of electrolytic stripping of U(VI) using an electrolytic separation cell with anode and cathode compartments, separated by a cation exchange...
SourceID	proquest gale crossref springer
SourceType	Aggregation Database Enrichment Source Index Database Publisher
StartPage	1505
SubjectTerms	Cation exchanging Chemistry Chemistry and Materials Science Comparative analysis Diagnostic Radiology Disproportionation Electrolytes Feasibility Hadrons Heavy Ions Hydrazines Inorganic Chemistry Nitric acid Nuclear Chemistry Nuclear Physics Oxalates Oxalic acid Physical Chemistry Solvent extraction Uranium
Title	Feasibility of electro-reduction of U(VI) in oxalic acid using an electrolytic CEM-separated cell
URI	https://link.springer.com/article/10.1007/s10967-020-07367-3 https://www.proquest.com/docview/2473805952
Volume	326
WOSCitedRecordID	wos000571694800003&url=https%3A%2F%2Fcvtisr.summon.serialssolutions.com%2F%23%21%2Fsearch%3Fho%3Df%26include.ft.matches%3Dt%26l%3Dnull%26q%3D
hasFullText	1
inHoldings	1
isFullTextHit
isPrint
journalDatabaseRights	– providerCode: PRVAVX databaseName: SpringerLINK Contemporary 1997-Present customDbUrl: eissn: 1588-2780 dateEnd: 99991231 omitProxy: false ssIdentifier: ssj0009883 issn: 0236-5731 databaseCode: RSV dateStart: 19970101 isFulltext: true titleUrlDefault: https://link.springer.com/search?facet-content-type=%22Journal%22 providerName: Springer Nature
link	http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV1ZS8QwEA5eoC_e4nqRB0FFC03SHH2URVFQES98C2mSysKyyu4q-u-ddFPXG_QttLmYIzNDMt8gtJmDS2sk8wnYeppkHgIU44xIaOkk9yR1wlaQ-Sfy7Ezd3ubnMSmsV792r68kq5P6XbJbDkodwh0QS2ixUTQO5k4Fdby4vBlC7aoB-CZlIuGSkZgq8_0cH8zR50P5y-1oZXQOZ_633Vk0HZ1MvD-Qijk04jvzaLJZ13ZbQAY8v_gu9gXflzgWw0m6Acg1sCp8vN6-Od7BLWg_g7NusbEth8M7-TtsOvWQ9gusgZsHp0nPVzDi3uFwGbCIrg8PrppHSSy2kFjGVR8sVV5IwUnhS5EJ64WizsjMkUJIQUpVcumJ5YUVqTW5MowRT5gX1MmS56llS2isc9_xywgXhnDlhOPS-CzNIHYveMm9UamyxuWkgUhNc20jEnkoiNHWQwzlQDwNxNMV8TRroN23MQ8DHI5fe28FVuqgpDCzNTHXAPYX4K70fuWXEUFhL2s1t3XU3p6mmWQK_E5OG2iv5u7w98_rrvyt-yqaokFAqtTGNTTW7z76dTRhn_qtXnejkupXdqju9g
linkProvider	Springer Nature
linkToHtml	http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwnV3daxQxEB-0FuqL2qp4Wm0eCm3RhU2y-djHcvRo8XoUey19C9kkWw7Kndxdi_ffO9nLemqtoG9hN1_MTDIzZOY3ALslmrRW8ZChrmdZEdBBsd7KjNVeiUBzL10Dmd9Xg4G-uirPUlLYrI12b58km5v6p2S3Eg91dHdQLLHFH8OTAjVWDOT7cn65gtrVS_BNxmUmFKcpVebPc_yijn6_lO-9jjZKp_f8_7b7Ap4lI5McLqViEx6F8RZsdNvabi_BouWX4mIXZFKTVAwnm0Yg18iq-PFi__LkgIyw_Q2NdUesG3kS4-SviR23Q24WuAbpHp1ms9DAiAdP4mPAK7joHQ27x1kqtpA5LvQcNVVZKSloFWpZSBekZt6qwtNKKklrXQsVqBOVk7mzpbac00B5kMyrWpS5469hbTwZhzdAKkuF9tILZUORF-i7V6IWwepcO-tL2gHa0ty4hEQeC2LcmBWGciSeQeKZhniGd-DjjzFflzgcf-29F1lp4iHFmZ1NuQa4vwh3ZQ4bu4xKhnvZbrlt0umdGVYortHuFKwDn1rurn4_vO7bf-u-AxvHw9O-6Z8MPr-DpywKS5PmuA1r8-lteA_r7m4-mk0_NBL-HbHy8do
linkToPdf	http://cvtisr.summon.serialssolutions.com/2.0.0/link/0/eLvHCXMwpV3dSxwxEB-qLeqL1bbitbbmQailLrdJNh_7KKdHpfYQquJbyCbZciCr3J2i_72TvV3Pqi2UvoVsvpiZ7Mwwmd8AbOVo0lrFQ4K6niVZQAfFeisTVnolAk29dDVk_qEaDPTZWX70IIu_fu3ehiSnOQ0RpamadC992X2Q-JbjBY-uD4ootvgcvMxi0aDor_88ncHu6ikQJ-MyEYrTJm3m-TV-U02Pf9BPIqW1Auq__v-jr8ByY3yS3am0rMKLUL2BxV5b8-0tWLQIm_eyt-SiJE2RnGQUAV4jC2PnyfbpwRcyxPYNGvGOWDf0JL6f_0Vs1U45v8U9SG__RzIONbx48CQGCd7BSX__uPctaYowJI4LPUENlhdKClqEUmbSBamZtyrztJBK0lKXQgXqROFk6myuLec0UB4k86oUeer4GsxXF1VYB1JYKrSXXigbsjRDn74QpQhWp9pZn9MO0Jb-xjUI5bFQxrmZYStH4hkknqmJZ3gHvt7PuZzic_x19OfIVhMvL67sbJODgOeLMFhmt7bXqGR4lo2W86a51WPDMsU12qOCdWCn5fTs85_3ff9vwzdh4Wivbw4PBt8_wBKLslJnP27A_GR0FT7CK3c9GY5Hn2phvwMbPvq-
openUrl	ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Feasibility+of+electro-reduction+of+U%28VI%29+in+oxalic+acid+using+an+electrolytic+CEM-separated+cell&rft.jtitle=Journal+of+radioanalytical+and+nuclear+chemistry&rft.au=Potgieter%2C+M.&rft.au=van+der+Spoel+Badenhorst%2C+W.+D.&rft.au=Barry%2C+J.+C.&rft.au=van+der+Westhuizen%2C+D.+J.&rft.date=2020-11-01&rft.pub=Springer+International+Publishing&rft.issn=0236-5731&rft.eissn=1588-2780&rft.volume=326&rft.issue=2&rft.spage=1505&rft.epage=1510&rft_id=info:doi/10.1007%2Fs10967-020-07367-3&rft.externalDocID=10_1007_s10967_020_07367_3
thumbnail_l	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/lc.gif&issn=0236-5731&client=summon
thumbnail_m	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/mc.gif&issn=0236-5731&client=summon
thumbnail_s	http://covers-cdn.summon.serialssolutions.com/index.aspx?isbn=/sc.gif&issn=0236-5731&client=summon