Spin- and Energy-Dependent Tunneling through a Single Molecule with Intramolecular Spatial Resolution
We investigate the spin- and energy-dependent tunneling through a single organic molecule (CoPc) adsorbed on a ferromagnetic Fe thin film, spatially resolved by low-temperature spin-polarized scanning tunneling microscopy. Interestingly, the metal ion as well as the organic ligand show a significant...
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| Veröffentlicht in: | Physical review letters Jg. 105; H. 4; S. 047204 |
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| Sprache: | Englisch |
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23.07.2010
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| ISSN: | 0031-9007, 1079-7114, 1079-7114 |
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| Abstract | We investigate the spin- and energy-dependent tunneling through a single organic molecule (CoPc) adsorbed on a ferromagnetic Fe thin film, spatially resolved by low-temperature spin-polarized scanning tunneling microscopy. Interestingly, the metal ion as well as the organic ligand show a significant spin dependence of tunneling current flow. State-of-the-art ab initio calculations including also van der Waals interactions reveal a strong hybridization of molecular orbitals and substrate 3d states. The molecule is anionic due to a transfer of one electron, resulting in a nonmagnetic (S=0) state. Nevertheless, tunneling through the molecule exhibits a pronounced spin dependence due to spin-split molecule-surface hybrid states. |
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| AbstractList | We investigate the spin- and energy-dependent tunneling through a single organic molecule (CoPc) adsorbed on a ferromagnetic Fe thin film, spatially resolved by low-temperature spin-polarized scanning tunneling microscopy. Interestingly, the metal ion as well as the organic ligand show a significant spin dependence of tunneling current flow. State-of-the-art ab initio calculations including also van der Waals interactions reveal a strong hybridization of molecular orbitals and substrate 3d states. The molecule is anionic due to a transfer of one electron, resulting in a nonmagnetic (S=0) state. Nevertheless, tunneling through the molecule exhibits a pronounced spin dependence due to spin-split molecule-surface hybrid states.We investigate the spin- and energy-dependent tunneling through a single organic molecule (CoPc) adsorbed on a ferromagnetic Fe thin film, spatially resolved by low-temperature spin-polarized scanning tunneling microscopy. Interestingly, the metal ion as well as the organic ligand show a significant spin dependence of tunneling current flow. State-of-the-art ab initio calculations including also van der Waals interactions reveal a strong hybridization of molecular orbitals and substrate 3d states. The molecule is anionic due to a transfer of one electron, resulting in a nonmagnetic (S=0) state. Nevertheless, tunneling through the molecule exhibits a pronounced spin dependence due to spin-split molecule-surface hybrid states. We investigate the spin- and energy-dependent tunneling through a single organic molecule (CoPc) adsorbed on a ferromagnetic Fe thin film, spatially resolved by low-temperature spin-polarized scanning tunneling microscopy. Interestingly, the metal ion as well as the organic ligand show a significant spin dependence of tunneling current flow. State-of-the-art ab initio calculations including also van der Waals interactions reveal a strong hybridization of molecular orbitals and substrate 3d states. The molecule is anionic due to a transfer of one electron, resulting in a nonmagnetic (S=0) state. Nevertheless, tunneling through the molecule exhibits a pronounced spin dependence due to spin-split molecule-surface hybrid states. |
| ArticleNumber | 047204 |
| Author | Blügel, Stefan Caciuc, Vasile Kuck, Stefan Wiesendanger, Roland Morikawa, Yoshitada Lazić, Predrag Brede, Jens Hoffmann, Germar Atodiresei, Nicolae |
| Author_xml | – sequence: 1 givenname: Jens surname: Brede fullname: Brede, Jens – sequence: 2 givenname: Nicolae surname: Atodiresei fullname: Atodiresei, Nicolae – sequence: 3 givenname: Stefan surname: Kuck fullname: Kuck, Stefan – sequence: 4 givenname: Predrag surname: Lazić fullname: Lazić, Predrag – sequence: 5 givenname: Vasile surname: Caciuc fullname: Caciuc, Vasile – sequence: 6 givenname: Yoshitada surname: Morikawa fullname: Morikawa, Yoshitada – sequence: 7 givenname: Germar surname: Hoffmann fullname: Hoffmann, Germar – sequence: 8 givenname: Stefan surname: Blügel fullname: Blügel, Stefan – sequence: 9 givenname: Roland surname: Wiesendanger fullname: Wiesendanger, Roland |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/20867880$$D View this record in MEDLINE/PubMed |
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| Title | Spin- and Energy-Dependent Tunneling through a Single Molecule with Intramolecular Spatial Resolution |
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